1,2-Dimethyl-4-(trifluoromethyl)cyclohexane

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 1,2-Dimethyl-4-(trifluoromethyl)cyclohexane
• 英文别名: 1,2-dimethyl-4-(trifluoromethyl)cyclohexane
• 化学式: C₉H₁₅F₃
• 分子量: 180.21
• InChiKey: LUHQHWAHOYBHRQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：EP3098229B1

  公开（公告）日：2021-08-11
• [EN] METHODS FOR FORMING ARYL CARBON-NITROGEN BONDS USING LIGHT AND PHOTOREACTORS USEFUL FOR CONDUCTING SUCH REACTIONS<br/>[FR] PROCÉDÉS DE FORMATION DE LIAISONS ARYLE CARBONE-AZOTE À L'AIDE DE LUMIÈRE ET PHOTORÉACTEURS UTILES POUR LA MISE EN ŒUVRE DE TELLES RÉACTIONS
  申请人：UNIV COLORADO STATE RES FOUND

  公开号：WO2021096496A1

  公开（公告）日：2021-05-20

  The disclosure relates to a dual catalytic method for forming aryl carbon-nitrogen bonds. The method comprises contacting an aryl halide with an amine in the presence of a dual catalytic solution comprising a Ni(II) salt catalyst, a photocatalyst, and an optional base, thereby forming a reaction mixture; exposing the reaction mixture to light under reaction condition sufficient to produce the aryl carbon-nitrogen bonds. In certain embodiments, the amine may be present in a molar excess to the aryl halide. In certain embodiment, the photocatalyst may be [Ru(bpy)3]Cl2 or an organic phenoxazine. In certain embodiments, the Ni salt catalyst solution includes a Ni(II) salt and a polar solvent, wherein the Ni(II) salt is dissolved in the polar solvent.