1,10-Bis(4-hydroxyphenyl)decane | 3682-97-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1,10-Bis(4-hydroxyphenyl)decane
• 英文别名: 4,4'-decanediyl-di-phenol；4,4'-Decandiyl-di-phenol；1,10-Bis-(4-hydroxy-phenyl)-decan；4,4'-Decamethylenediphenol；4-[10-(4-hydroxyphenyl)decyl]phenol
• CAS: 3682-97-1
• 化学式: C₂₂H₃₀O₂
• 分子量: 326.479
• InChiKey: YTGYVXZVFCPXEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  24
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,10-Bis(4-hydroxyphenyl)decane 、 2,6-双(溴甲基)-4-甲基苯酚 在 四氯化钛 作用下， 以 1,4-二氧六环 为溶剂， 反应 52.0h， 以8.6%的产率得到11,23-dimethyl-5,17-decano-25,26,27,28-tetrahydroxycalix<4>arene
  参考文献：
  名称：

  A series of calix[4]arenes, having two opposite para positions connected by an aliphatic chain

  摘要：

  DOI：

  10.1021/ja00228a034
• 作为产物：
  描述：

  1,10-双(4-甲氧基苯基)癸烷 在 碘代三甲硅烷 作用下， 以 氯仿 为溶剂， 反应 48.0h， 以69%的产率得到1,10-Bis(4-hydroxyphenyl)decane
  参考文献：
  名称：

  三重螺纹 [4] 轮烷

  摘要：

  [4]通过活性金属模板合成制备了具有三个轴穿过单个环的轮烷。镍催化的 sp(3)-sp(3) 烷基溴“半线”通过 37 和 38 元 2,2':6',2"-三联吡啶大环的同偶联产生三重线 [4] 轮烷到 11% 的收率。类似的 39 元大环在类似条件下不产生轮烷产物。[4]轮烷的组成通过核磁共振光谱和质谱测定。双螺纹 [3] 轮烷也从反应中获得，但没有分离出 [2] 轮烷，这表明在脱金属后，单螺纹轮烷的轴可以滑过一个大环，该大环足够容纳三个螺纹。

  DOI：

  10.1021/jacs.6b07733

文献信息

• IONICALLY BONDED SALT HAVING REACTIVE GROUP AND THERMOPLASTIC RESIN COMPOSITION CONTAINING SAME
  申请人：NIPPON NYUKAZAI CO., LTD.

  公开号：US20150166474A1

  公开（公告）日：2015-06-18

  [Problem] Provided are an ionically bonded salt having a reactive group which improves the weather resistance of a thermoplastic resin, and a thermoplastic resin composition containing the ionically bonded salt. [Solution] An ionically bonded salt which has a reactive group and is represented by the following Chemical Formula (1) or the following Chemical Formula (2): in Chemical Formulas (1) and (2) above, R 1 and R 2 each independently represent a substituted or unsubstituted linear, branched, or cyclic alkyl group having from 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having from 6 to 30 carbon atoms, or a substituted or unsubstituted arylalkyl group having from 7 to 31 carbon atoms, A is a linear or branched alkylene group having from 2 to 4 carbon atoms, n represents an integer of 0 to 50, and Q1 and Q2 each independently represent at least one kind selected from the group consisting of an ammonium ion having an ethylenically unsaturated bond, an imidazolium ion having an ethylenically unsaturated bond, a pyridinium ion having an ethylenically unsaturated bond, a pyrrolidinium ion having an ethylenically unsaturated bond, a pyrrolinium ion having an ethylenically unsaturated bond, a piperidinium ion having an ethylenically unsaturated bond, a pyrazinium ion having an ethylenically unsaturated bond, a pyrimidinium ion having an ethylenically unsaturated bond, a triazolium ion having an ethylenically unsaturated bond, a triazinium ion having an ethylenically unsaturated bond, a quinolinium ion having an ethylenically unsaturated bond, an isoquinolinium ion having an ethylenically unsaturated bond, an indolinium ion having an ethylenically unsaturated bond, a quinoxalinium ion having an ethylenically unsaturated bond, a piperazinium ion having an ethylenically unsaturated bond, an oxazolinium ion having an ethylenically unsaturated bond, a thiazolinium ion having an ethylenically unsaturated bond, and a morpholinium ion having an ethylenically unsaturated bond.

  提供了一种离子键合盐，具有改善热塑性树脂的耐候性的反应性基团，以及含有该离子键合盐的热塑性树脂组合物。具有以下化学式（1）或以下化学式（2）表示的具有反应性基团的离子键合盐： 在上述化学式（1）和（2）中，R1和R2分别独立表示具有1至30个碳原子的取代或未取代的直链、支链或环烷基基团，具有6至30个碳原子的取代或未取代芳基基团，或具有7至31个碳原子的取代或未取代芳基烷基基团，A表示具有2至4个碳原子的直链或支链烷基基团，n表示0至50的整数，Q1和Q2分别独立表示从具有乙烯不饱和键的氨基离子、具有乙烯不饱和键的咪唑离子、具有乙烯不饱和键的吡啶离子、具有乙烯不饱和键的吡咯烷离子、具有乙烯不饱和键的吡咯离子、具有乙烯不饱和键的哌啶离子、具有乙烯不饱和键的吡嗪离子、具有乙烯不饱和键的嘧啶离子、具有乙烯不饱和键的三唑离子、具有乙烯不饱和键的三唑离子、具有乙烯不饱和键的喹啉离子、具有乙烯不饱和键的异喹啉离子、具有乙烯不饱和键的吲哚啉离子、具有乙烯不饱和键的喹啉啉离子、具有乙烯不饱和键的哌啶啉离子、具有乙烯不饱和键的噁唑啉离子、具有乙烯不饱和键的噻唑啉离子和具有乙烯不饱和键的吗啉啉离子中选择的至少一种的群组。
• POLYCARBONATE RESIN COMPOSITION AND FORMED PRODUCT THEREOF
  申请人：Monden Toshiki

  公开号：US20110245388A1

  公开（公告）日：2011-10-06

  In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

  在含有聚碳酸酯树脂和聚碳硅烷化合物的聚碳酸酯树脂组合物中，使用聚碳硅烷化合物可以改变聚碳酸酯树脂组合物的表面特性，而不会对聚碳酸酯树脂的固有特性产生不利影响，如透明度、耐热性和机械性能（例如冲击强度）。含有100质量部聚碳酸酯树脂、0.001至1质量部金属盐化合物和0.005至5质量部聚碳硅烷化合物的聚碳酸酯树脂组合物具有显著提高的阻燃性和高透明度，显著减少气体排放和模具污染，同时不会损失冲击强度和耐热性。
• HYDROXY-TERMINATED SILOXANE, POLYSILOXANE-POLYCARBONATE COPOLYMER, AND PREPARATION METHOD THEREOF
  申请人：Kim Sun Mi

  公开号：US20120309922A1

  公开（公告）日：2012-12-06

  Provided are a hydroxy-terminated siloxane, a polysiloxane-polycarbonate copolymer including same as a repeating unit, and a preparation method thereof. The hydroxyl-terminated siloxane has the structure of chemical formula 1.

  提供了一种羟基终止的硅氧烷，包括其作为重复单元的聚硅氧烷-聚碳酸酯共聚物以及其制备方法。羟基终止的硅氧烷具有化学式1的结构。
• Process for Producing Polycarbonate
  申请人：Kunishi Noriyuki

  公开号：US20080242828A1

  公开（公告）日：2008-10-02

  Provided a process for producing a polycarbonate which comprises reacting an aqueous alkali solution of a dihydric phenol with phosgene in the presence of an organic solvent to produce a polycarbonate oligomer and subsequently polycondensing the oligomer, wherein an emulsion solution of a polycarbonate oligomer-containing organic solvent obtained in the polycarbonate oligomer production step is introduced into a coalescer to separate the emulsion solution into a polycarbonate oligomer-containing organic solvent phase and an aqueous phase, and the polycarbonate oligomer-containing organic solvent phase is subjected to polycondensation. Thus the emulsion solution of a polycarbonate oligomer-containing organic solvent obtained in the polycarbonate oligomer production step is efficiently separated to reduce the content of impurity-containing water in the oligomer for producing a polycarbonate having excellent quality and to a obtain wastewater having a low content of organic materials.

  提供了一种制备聚碳酸酯的方法，包括在有机溶剂存在下，将二元酚的水性碱溶液与光气反应，生产聚碳酸酯寡聚体，随后进行聚缩反应。在聚碳酸酯寡聚体生产步骤中获得含有聚碳酸酯寡聚体的有机溶剂的乳液溶液，将其引入凝聚器中，将乳液溶液分离成含有聚碳酸酯寡聚体的有机溶剂相和水相，然后对含有聚碳酸酯寡聚体的有机溶剂相进行聚缩反应。因此，有效地分离聚碳酸酯寡聚体的乳液溶液，以减少杂质含水量，生产优质的聚碳酸酯，并获得有机物含量低的废水。
• TRANSPARENT FLAME-RETARDANT AROMATIC POLYCARBONATE RESIN COMPOSITION, AND MOLDED PRODUCT THEREOF
  申请人：Yamada Aki

  公开号：US20110245389A1

  公开（公告）日：2011-10-06

  A polycarbonate resin composition that is enhanced in flame retardancy while maintaining transparency containing (A) a polycarbonate resin component containing from 10 to 90% by mass of (A-1) an aromatic polycarbonate resin containing a dihydroxybiphenyl as a part of a dihydric phenol, from 10 to 90% by mass of (A-2) an aromatic polycarbonate-polyorganosiloxane copolymer, and from 0 to 80% by mass of (A-3) an aromatic polycarbonate resin other than (A-1) and (A-2), and a molded product thereof. In the flame retardant polycarbonate resin composition, the content of the polyorganosiloxane in (A) is preferably from 0.3 to 1.6% by mass, and the composition may contain from 0.01 to 1 part by mass of (B) an organic metal salt per 100 parts by mass of (A).

  一种聚碳酸酯树脂组合物，具有提高的阻燃性能，同时保持透明度，包含（A）聚碳酸酯树脂成分，其中含有10至90质量％的（A-1）芳香族聚碳酸酯树脂，该聚碳酸酯树脂含有二羟基联苯作为二元酚的一部分，含有10至90质量％的（A-2）芳香族聚碳酸酯-聚有机硅氧烷共聚物，以及0至80质量％的（A-3）除（A-1）和（A-2）之外的芳香族聚碳酸酯树脂，以及其模塑制品。在阻燃聚碳酸酯树脂组合物中，（A）中的聚有机硅氧烷含量最好为0.3至1.6质量％，并且该组合物可以包含每100质量部（A）的有机金属盐0.01至1质量部（B）。