[Benzyl(fluorooxy)phosphoryl] hypofluorite

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Benzyl(fluorooxy)phosphoryl] hypofluorite
• 英文别名: [benzyl(fluorooxy)phosphoryl] hypofluorite
• 化学式: C₇H₇F₂O₃P
• 分子量: 208.1
• InChiKey: VFYYRNGHNCXBJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• PENTAFLUOROPHOSPHATE DERIVATIVE, ITS USES AND AN APPROPRIATE MANUFACTURING METHOD
  申请人：Freie Universität Berlin

  公开号：EP3456725A1

  公开（公告）日：2019-03-20

  The invention relates to a pentafluorophosphate derivative according to general formula (I): or a pharmaceutically acceptable salt or solvate thereof. Thereby, R1 and R2 denote independently from each other H or F; R3 denotes H, an optionally substituted C1-C10 alkyl, an optionally substituted C3-C10 cycloalkyl, or an optionally substituted C6-C20 aryl, wherein a hydrocarbon chain of the alkyl, the cycloalkyl or the aryl can be interrupted by one or more oxygen, sulfur and/or nitrogen atoms; and M denotes any cation; with the proviso that at least one of R1 and R2 denotes F, if R3 denotes H. The invention further relates to uses of such a pentafluorophosphate derivative and to an appropriate manufacturing method.

  该发明涉及一种五氟磷酸盐衍生物，其通式为(I)：或其药用可接受的盐或溶剂。在此，R1和R2分别独立表示H或F；R3表示H，可选择性取代的C1-C10烷基，可选择性取代的C3-C10环烷基，或可选择性取代的C6-C20芳基，其中烷基、环烷基或芳基的烃链可被一个或多个氧、硫和/或氮原子中断；M表示任何阳离子；但要求至少R1和R2中的一个表示F，如果R3表示H。该发明还涉及该五氟磷酸盐衍生物的用途和适当的制造方法。
• Physically reconfigurable structurally embedded vascular antenna
  申请人：Government of the United States, as represented by the Secretary of the Air Force

  公开号：US10944178B1

  公开（公告）日：2021-03-09

  A reconfigurable antenna comprises a panel having a liquid metal pump coupled to a power supply; a liquid metal reservoir in fluid communication with the pump; one or more channels for transporting the liquid metal, each of the one or more channels having a proximal end in fluid communication with the pump, each of the one or more channels having a vent at a distal end, wherein application of power to the pump moves the liquid metal into or out of the channels thereby reconfiguring the antenna. The pump may be a pneumatic pump or a magnetohydrodynamic pump, and a layer of a phosphonic acid may be included on the liquid metal-bearing surfaces of the channels. The phosphonic acid may be decylphosphonic acid (DPA), fluorobenzylphosphonic acid (FPA), or difluorobenzylphosphonic acid (DFPA), and one or more sensors may be coupled to the panel for determining the position of the liquid metal in the channels.

  一种可重新配置的天线包括一个面板，面板上有一个与电源相连的液态金属泵；一个与泵流体相通的液态金属贮槽；一个或多个用于输送液态金属的通道，一个或多个通道中的每个通道都有一个与泵流体相通的近端，一个或多个通道中的每个通道的远端都有一个通风口，其中向泵供电可使液态金属进入或流出通道，从而重新配置天线。泵可以是气动泵或磁流体泵，通道的液态金属承载表面可以包括一层膦酸。膦酸可以是癸基膦酸 (DPA)、氟苄基膦酸 (FPA) 或二氟苄基膦酸 (DFPA)，一个或多个传感器可以连接到面板上，用于确定通道中液态金属的位置。
• Physically reconfigurable structurally embedded vascular antenna and method of making
  申请人：Government of the United States, as represented by the Secretary of the Air Force

  公开号：US10985446B1

  公开（公告）日：2021-04-20

  A method of making a reconfigurable antenna comprises the steps of applying one or more first layers of a prepreg laminate fabric to a form having a desired contour; applying a pattern corresponding to an antenna shape to the first layers of prepreg fabric; applying one or more second layers of the prepreg laminate fabric atop the pattern to form a laminate stack; curing the laminate stack; and removing the pattern to form channels in the antenna shape. The desired contour may be an aircraft skin panel or an airfoil panel. The pattern may be a polymer sheet with an applied cPLA antenna design. The curing step may be performed in a vacuum bag under the application of vacuum and heat. The removing step may be performed by heating the cured laminate stack to remove the pattern.

  一种制造可重新配置天线的方法包括以下步骤：将一层或多层预浸料层压织物涂抹在具有所需轮廓的形状上；将与天线形状相对应的图案涂抹在第一层预浸料织物上；在图案上涂抹一层或多层第二层预浸料层压织物以形成层压叠层；固化层压叠层；以及去除图案以在天线形状中形成通道。所需的轮廓可以是飞机蒙皮面板或机翼面板。图案可以是带有应用 cPLA 天线设计的聚合物薄片。固化步骤可在真空袋中通过真空和加热进行。移除步骤可通过加热固化的层压板来移除图案。
• Ultraviolet- and infrared-absorbing composition and ultraviolet- and infrared-absorbing filter
  申请人：Nippon Sheet Glass Company, Limited

  公开号：US11535726B2

  公开（公告）日：2022-12-27

  A UV-IR-absorbing composition according to the present invention includes: an absorber formed by a phosphonic acid represented by the following formula (a) and copper ion, the absorber being dispersed in the UV-IR-absorbing composition; a phosphoric acid ester allowing the absorber to be dispersed; a matrix resin; and an alkoxysilane monomer.

  根据本发明的紫外线-红外线吸收组合物包括：由下式（a）代表的膦酸和铜离子形成的吸收剂，吸收剂分散在紫外线-红外线吸收组合物中；允许吸收剂分散的磷酸酯；基质树脂；以及烷氧基硅烷单体。
• ULTRAVIOLET AND INFRARED ABSORBING COMPOSITION AND ULTRAVIOLET AND INFRARED ABSORBING FILTER
  申请人：Nippon Sheet Glass Company, Limited

  公开号：EP3605163B1

  公开（公告）日：2022-01-12