6-己基-2-萘酚 | 1999-56-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 6-己基-2-萘酚
• 英文名称: 6-hexylnaphthalen-2-ol
• 英文别名: 6-Hexyl-[2]naphthol；6-Hexyl-2-naphthol；2-Naphthol, 6-hexyl-
• CAS: 1999-56-0
• 化学式: C₁₆H₂₀O
• 分子量: 228.334
• InChiKey: YLSRNLBJYQACQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2907199090

反应信息

• 作为反应物：
  描述：

  6-己基-2-萘酚 在 乙醇 、 氨 、 sodium 作用下， 生成 6-hexyl-3,4-dihydro-1H-naphthalen-2-one
  参考文献：
  名称：

  234.高分子量烃的合成。第二部分 一些二和三正烷基萘

  摘要：

  DOI：

  10.1039/jr9510001061
• 作为产物：
  描述：

  (6-己基-[2]萘基)-甲基醚 在 氢溴酸 、 溶剂黄146 作用下， 生成 6-己基-2-萘酚
  参考文献：
  名称：

  Synthesis and Characterization of Liquid Crystalline Semiconducting Materials, Dialkyl-2-phenylnaphthalene Derivatives—Mesomorphic behavior and Charge carrier transport

  摘要：

  For establishment of high electronic charge carrier transport at ambient temperature, dialkyl derivatives of 2-phenylnaphthalene have been synthesized and characterized their liquid crystalline behaviors and photoelectrical properties. These materials exhibited smectic mesophases (Smectic A, B and E phases), at fairly low temperature range extended down below ambient temperature. Fast electronic transport of positive carriers was observed in SmE phase of 2-(4'-octylphenyl)-6-butylnaphthalene at 30degreesC, whose mobility was over 10(-2) cm(2)/Vs.

  DOI：

  10.1080/15421400490435251

文献信息

• CATALYST FOR OLEFIN POLYMERIZATION AND METHOD OF PREPARATION THEREOF
  申请人：Wang Licai

  公开号：US20110301385A1

  公开（公告）日：2011-12-08

  A catalyst for olefin polymerization and method of preparing the same are disclosed.

  揭示了一种烯烃聚合的催化剂及其制备方法。
• Methylation of Arenols through Ni-catalyzed C-O Activation with Methyl Magnesium Bromide
  作者：Wen-Juan Shi、Zhang-Jie Shi

  DOI：10.1002/cjoc.201700664

  日期：2018.3

  Direct alkylation of arenols with alkyl organometallic reagents has never been approached. Herein we reported the first successful example of nickel‐catalyzed methylation of arenols with methyl Grignard reagents to construct C(sp2)‐C(sp3) bond under mild conditions. The transformation was compatible with broad substrate scope of 2‐naphthol derivatives. Benzyl alcohol and biphenols were also suitable

  从未有过使用烷基有机金属试剂将芳烃直接烷基化的方法。在这里，我们报道了第一个成功的例子，该例子是在温和条件下用甲基格氏试剂进行镍催化的芳香烃甲基化，以构建C（sp 2）-C（sp 3）键。该转化与2-萘酚衍生物的广泛底物范围兼容。苄醇和联苯酚也是该甲基化的合适底物。
• Catalyst for Olefin Polymerization and Preparation Thereof and Polymerization Process
  申请人：Wang Licai

  公开号：US20080161513A1

  公开（公告）日：2008-07-03

  The catalyst for olefin polymerization contains three components A, B and C. The component A is a solid catalyst containing titanium, magnesium, chlorine element and an internal electron donor, the internal electron donor consists of 1,4-diether [2,2′-dialkoxy-1,1′-biphenyl, 2,2′-dialkoxy-1,1′-binaphthalene, 10,10′-dialkoxy-9,9-biphenanthrene] and organic acid ester or 1,3-diether [9,9-bis(methoxymethyl)fluorine, 2,2-dialky 1-1,3-dimethoxypropane]; the component B is an organoaluminum compound; the component C is external electron donor-organic silicon compound or the 1,4 aromatic diether. The catalyst has high catalytic activity, and can be adjusted in the range from 40,000 to 150,000 gPP/gCat when used in propylene polymerization. The polymer made therefrom has isotactivity of 80 to 99 percent and the molecular weight distribution can be adjusted in a wide range. The invention provides a novel method for preparing the 1,4 aromatic diether.

  烯烃聚合反应的催化剂包含三个组分A、B和C。组分A是一种固体催化剂，包含钛、镁、氯元素和内部电子给体。内部电子给体由1,4-二醚[2,2'-二烷氧基-1,1'-联苯、2,2'-二烷氧基-1,1'-联萘、10,10'-二烷氧基-9,9-联苯并]和有机酸酯或1,3-二醚[9,9-双(甲氧基甲基)氟、2,2-二烷基-1,3-二甲氧基丙烷]组成；组分B是一种有机铝化合物；组分C是外部电子给体-有机硅化合物或1,4-芳香二醚。该催化剂具有高催化活性，在丙烯聚合中使用时，可以在40,000至150,000 gPP/gCat的范围内调整。由此制成的聚合物具有80至99％的同构活性，分子量分布范围可以广泛调整。本发明提供了一种制备1,4-芳香二醚的新方法。
• RESIN COMPOSITION FOR ENCAPSULATING SEMICONDUCTOR AND SEMICONDUCTOR DEVICE USING THE RESIN COMPOSITION
  申请人：Tanaka Yusuke

  公开号：US20120205822A1

  公开（公告）日：2012-08-16

  Disclosed are a resin composition for encapsulating a semiconductor containing a phenol resin (A), an epoxy resin (B) and an inorganic filler (C), wherein the phenol resin (A) contains a polymer (a1) having a structure represented by the general formula (1), and the epoxy resin (B) contains at least one kind of epoxy resin selected from the group consisting of a triphenol methane type epoxy resin, a naphthol type epoxy resin and a dihydroanthracene type epoxy resin, and a semiconductor device, obtained by encapsulating a semiconductor element with a cured product of the resin composition for encapsulating a semiconductor.
• US7964678B2
  申请人：——

  公开号：US7964678B2

  公开（公告）日：2011-06-21