2-N-phenylamino-4-N-phenylimino-2-pentene | 23768-99-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-N-phenylamino-4-N-phenylimino-2-pentene
• 英文别名: N-4-(phenylimino)pent-2-en-2-ylbenzenamine；2-phenylamino-4-phenyl-imino-2-pentene
• CAS: 23768-99-2
• 化学式: C₁₇H₁₈N₂
• 分子量: 250.343
• InChiKey: PWYOZUDBDQUBBL-GCYSJDCNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.79
• 重原子数：
  19.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  24.39
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 2-N-phenylamino-4-N-phenylimino-2-pentene 以 乙腈 为溶剂， 反应 2.0h， 以65%的产率得到
  参考文献：
  名称：

  Kalita, Aswini, Journal of the Indian Chemical Society, 2020, vol. 97, # 6, p. 823 - 827

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-戊二炔 、 苯胺 在 Ti(NMe₂)₂(dpma) 作用下， 生成 2-N-phenylamino-4-N-phenylimino-2-pentene
  参考文献：
  名称：

  Pyrrole Syntheses Based on Titanium-Catalyzed Hydroamination of Diynes

  摘要：

  Titanium-catalyzed hydroamination of 1,4- and 1,5-diynes by primary amines leads to imino-alkynes that undergo in situ 5-endo dig and 5-exo dig cyclization reactions, respectively. The products are 1,2,5-trisubsituted pyrroles accessed directly from readily available diyne starting materials.

  DOI：

  10.1021/ol0489088

文献信息

• Metal-organic frameworks containing nitrogen-donor ligands for efficient catalytic organic transformations
  申请人：The University of Chicago

  公开号：US10647733B2

  公开（公告）日：2020-05-12

  Metal-organic framework (MOFs) compositions based on nitrogen donor-based organic bridging ligands, including ligands based on 1,3-diketimine (NacNac), bipyridines and salicylaldimine, were synthesized and then post-synthetically metalated with metal precursors, such as complexes of first row transition metals. Metal complexes of the organic bridging ligands could also be directly incorporated into the MOFs. The MOFs provide a versatile family of recyclable and reusable single-site solid catalysts for catalyzing a variety of asymmetric organic transformations. The solid catalysts can also be integrated into a flow reactor or a supercritical fluid reactor.

  基于以氮为供体的有机桥联配体，包括基于1,3-二酮亚胺（NacNac）、联吡啶和柳酸亚胺的金属-有机框架（MOFs）组成物被合成，然后用金属前驱体如第一行过渡金属的络合物进行后合成金属化。有机桥联配体的金属络合物也可以直接并入MOFs中。MOFs提供了一个多功能的、可回收和可重复使用的单点固体催化剂家族，用于催化各种不对称有机转化。这些固体催化剂也可以集成到流动反应器或超临界流体反应器中。
• MASS POLYMERIZABLE POLYCYCLOOLEFIN COMPOSITIONS CONTAINING SOLUBLE PHOTOACID GENERATORS
  申请人：PROMERUS, LLC

  公开号：US20210380733A1

  公开（公告）日：2021-12-09

  Embodiments in accordance with the present invention encompass compositions comprising a soluble photoacid generator, a organopalladium compound, a photosensitizer and one or more olefinic monomers which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, among others.

  根据本发明的实施例，包括可溶性光酸发生剂、有机钯化合物、光敏剂和一种或多种烯烃单体的组合物被涵盖在内，当该组合物暴露于适当的光辐射下时，这些单体会经历乙烯基加成聚合反应，形成一个基本透明的薄膜。其中使用的单体具有不同的光学和机械性能，因此这些组合物可以定制成具有各种光电性能的薄膜。因此，本发明的组合物在各种应用中都是有用的，包括作为涂料、封装材料、填充剂、平整剂等。
• COMPOUNDS, REACTIONS, AND SCREENING METHODS
  申请人：HARTWIG John F.

  公开号：US20130274144A1

  公开（公告）日：2013-10-17

  The invention provides a method comprising identifying a successful metal-mediated conjugation reaction by analyzing a test mixture for the presence of a conjugation product. The invention provides a two-dimensional approach to reaction discovery in which many catalysts for many catalytic reactions can be tested simultaneously to provide an efficient discovery platform. Reactants and products from the system can be identified using techniques such as gas chromatography, liquid chromatography, mass spectrometry, and combinations thereof.

  本发明提供了一种方法，其中包括通过分析测试混合物中的共轭产物的存在来识别成功的金属介导的共轭反应。本发明提供了一种二维方法来发现反应，其中可以同时测试许多催化剂和催化反应，以提供高效的发现平台。可以使用气相色谱、液相色谱、质谱等技术来识别系统中的反应物和产物。
• Process for the gas-phase (co)-polymerisation of olefins in a fluidised bed reactor
  申请人：BP Chemicals S.N.C.

  公开号：EP1229055A1

  公开（公告）日：2002-08-07

  The present invention relates to a process for the (co-) polymerisation of olefins using a Ziegler-Natta type catalyst, in particular to a process for the gas-phase (co-) polymerisation of olefins in a fluidised bed reactor using a Ziegler-Natta type catalyst.

  本发明涉及一种使用齐格勒-纳塔型催化剂进行烯烃（共）聚合的工艺，特别是涉及一种使用齐格勒-纳塔型催化剂在流化床反应器中进行烯烃气相（共）聚合的工艺。
• BIMETALLIC CATALYST FOR OLEFIN POLYMERIZATION
  申请人：Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

  公开号：EP3037409A1

  公开（公告）日：2016-06-29

  The present invention relates to a bimetallic catalyst for olefin polymerization, a preparation method therefor, and the application thereof in catalysis for olefin polymerization. The catalyst is a transitional bimetallic complex of the VIII group with a type of multidentate ligand, and the structural formula thereof is shown as formula (I), wherein the definition for each radical group is described in the description. The catalyst of the present invention has a high activity and a high catalytic efficiency, suitable for olefin polymerization reactions, particularly suitable for the preparation of an olefin polymer having a bimodal distribution of molecular weights.

  本发明涉及一种用于烯烃聚合的双金属催化剂、其制备方法及其在烯烃聚合催化中的应用。该催化剂为 VIII 基团与一种多叉配位体的过渡双金属配合物，其结构式如式（I）所示，其中各基团的定义见说明。本发明的催化剂具有高活性和高催化效率，适用于烯烃聚合反应，尤其适用于制备分子量呈双峰分布的烯烃聚合物。