Tri-p-toluamid | 23825-29-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Tri-p-toluamid
• 英文别名: tri-p-toluoyl-amine；4-Methyl-n,n-bis(4-methylbenzoyl)benzamide
• CAS: 23825-29-8
• 化学式: C₂₄H₂₁NO₃
• 分子量: 371.436
• InChiKey: IQGDNAGWWWCENP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  54.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  对氯甲苯 在 吡啶 、 氯仿 作用下， 生成 Tri-p-toluamid
  参考文献：
  名称：

  The Diacylation of Amides by Acyl Chloride—Pyridine Compounds

  摘要：

  DOI：

  10.1021/ja01156a115

文献信息

• A photochemical generation of nitrosocarbonyl intermediates
  作者：P. Quadrelli、M. Mella、P. Caramella

  DOI：10.1016/s0040-4039(98)02416-2

  日期：1999.1

  Nitroscarbonyl intermediates are photochemically generated from 1,2,4-oxadiazole-4-oxides and efficiently trapped with enes and dienes.

  亚硝基羰基中间体是由1,2,4-恶二唑-4-氧化物光化学生成的，并有效地被烯和二烯捕获。
• Process for producing cyanobenzoic acid derivatives
  申请人：Showa Denko Kabushiki Kaisha

  公开号：EP0989115A2

  公开（公告）日：2000-03-29

  A process for producing a cyanobenzoic acid compound, a cyanobenzamide compound, an alkyl cyanobenzoate compound, and a cyanobenzoyl chloride compound, which are useful intermediates for a variety of chemicals such as pharmaceuticals, agrochemicals, liquid crystals, and monomers for functional polymers. One nitrile group of an easily available phthalonitrile compound is selectively hydrolyzed to thereby produce a cyanobenzamide compound with high selectivity and yield. The cyanobenzamide compound thus-produced is transformed under acidic conditions into a cyanobenzoic acid compound and a cyanobenzoate ester compound without the cyano group of the benzene ring being damaged.

  一种生产氰基苯甲酸化合物、氰基苯甲酰胺化合物、氰基苯甲酸烷基酯化合物和氰基苯甲酰氯化合物的工艺，这些化合物是多种化学品（如医药、农用化学品、液晶和功能聚合物单体）的有用中间体。一种易于获得的邻苯二腈化合物的一个腈基被选择性水解，从而以高选择性和高产率生成一种氰基苯甲酰胺化合物。由此生成的氰基苯甲酰胺化合物在酸性条件下可转化为氰苯甲酸化合物和氰苯甲酸酯化合物，而苯环上的氰基不会受到破坏。
• AROMATIC AMINE DERIVATIVES, SOLUBLE CONDUCTIVE COMPOUND, AND ELECTROLUMINESCENT ELEMENT
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1156072A1

  公开（公告）日：2001-11-21

  An aromatic amine derivative of the following general formula (1) is useful to form an auxiliary carrier transporting layer in an electroluminescent device. R1 is a monovalent hydrocarbon group or organooxy group, and A and B have the following general formula (2) or (3).

  以下通式（1）的芳香胺衍生物可用于在电致发光器件中形成辅助载流子传输层。 R1 是一价烃基或有机氧基，A 和 B 具有以下通式（2）或（3）。
• ELECTROLUMINESCENCE ELEMENT
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1248497A1

  公开（公告）日：2002-10-09

  An electroluminescent device comprising an anode, a cathode, and at least one electroluminescent organic layer interposed therebetween, wherein a luminescent material in the organic layer emits light upon application of a voltage between the anode and the cathode, is characterized in that a salt of an electron accepting dopant with a polyimide precursor and/or polyimide having oligo-aniline units on side chains is formed as an auxiliary carrier transporting layer between the anode and the organic layer, the polyimide precursor and/or polyimide being obtained from a diamine component containing at least 1 mol% of an oligo-aniline unit-bearing diaminobenzene derivative and a tetracarboxylic dianhydride or derivative thereof.

  一种电致发光装置，包括阳极、阴极和至少一个夹在其间的电致发光有机层，其中有机层中的发光材料在阳极和阴极之间施加电压时发光、其特征在于，作为阳极和有机层之间的辅助载流子传输层，电子接受掺杂剂与聚酰亚胺前体和/或侧链上具有低聚苯胺单元的聚酰亚胺形成盐，聚酰亚胺前体和/或聚酰亚胺由含有至少 1 摩尔%低聚苯胺单元的二氨基苯衍生物和四羧酸二酐或其衍生物的二胺组分获得。
• Electroluminescent element
  申请人：——

  公开号：US20020197494A1

  公开（公告）日：2002-12-26

  An electroluminescent device comprising an anode, a cathode, and at least one electroluminescent organic layer interposed therebetween, wherein a luminescent material in the organic layer emits light upon application of a voltage between the anode and the cathode, is characterized in that a salt of an electron accepting dopant with a polyimide precursor and/or polyimide having oligo-aniline units on side chains is formed as an auxiliary carrier transporting layer between the anode and the organic layer, the polyimide precursor and/or polyimide being obtained from a diamine component containing at least 1 mol % of an oligo-aniline unit-bearing diaminobenzene derivative and a tetracarboxylic dianhydride or derivative thereof.

  一种电致发光装置，包括阳极、阴极和至少一个夹在其间的电致发光有机层，其中有机层中的发光材料在阳极和阴极之间施加电压时发光、其特征在于，作为阳极和有机层之间的辅助载流子传输层，电子接受掺杂剂与聚酰亚胺前体和/或侧链上具有低聚苯胺单元的聚酰亚胺形成盐，聚酰亚胺前体和/或聚酰亚胺由含有至少 1 摩尔%低聚苯胺单元的二氨基苯衍生物和四羧酸二酐或其衍生物的二胺组分获得。