苄基二甲基乙氧基硅烷 | 17151-27-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苄基二甲基乙氧基硅烷
• 英文名称: benzyl(ethoxy)dimethylsilane
• 英文别名: benzyldimethylethoxysilane；BnMe2SiOEt；Aethoxy-dimethyl-benzyl-silan；Benzyldimethyl-ethoxy-silan；Benzyldimethylaethoxysilan；benzyl-ethoxy-dimethylsilane
• CAS: 17151-27-8
• 化学式: C₁₁H₁₈OSi
• 分子量: 194.349
• InChiKey: RFXODRCAZTVEOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.01
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  苄基二甲基乙氧基硅烷 在 硫酸 作用下， 生成 1,3-二苄基四甲基二硅烷
  参考文献：
  名称：

  Pola,J. et al., Collection of Czechoslovak Chemical Communications, 1973, vol. 38, p. 1522 - 1527

  摘要：

  DOI：
• 作为产物：
  描述：

  乙醇 、 苄基二甲基氯硅烷 在 吡啶 作用下， 以 乙醚 为溶剂， 生成 苄基二甲基乙氧基硅烷
  参考文献：
  名称：

  Pola,J.; Chvalovsky,V., Collection of Czechoslovak Chemical Communications, 1978, vol. 43, p. 746 - 751

  摘要：

  DOI：

文献信息

• Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene
  作者：Songchen Xu、Jeffery S. Boschen、Abhranil Biswas、Takeshi Kobayashi、Marek Pruski、Theresa L. Windus、Aaron D. Sadow

  DOI：10.1039/c5dt02844b

  日期：——

  of organic carbonyl compounds with silanes to give hydrosilylation products or deoxygenation products. The pathway to these reactions is primarily influenced by the degree of substitution of the organosilane. Reactions with primary silanes give deoxygenation of esters to ethers, amides to amines, and ketones and aldehydes to hydrocarbons, whereas tertiary silanes react to give 1,2-hydrosilylation of

  亲电，配位不饱和的铑配合物的硼酸联恶唑啉，恶唑啉配位亚甲硅烷基，和N-杂环卡宾供体支持[κ 3 -N，硅，C-值PhB（OX ME2）（OX ME2 SiHPh）进出口的Mes }铑（H）CO] [HB（C 6 F 5）3 ]（2，Ox ME2 = 4,4-二甲基-2-恶唑啉; Im Mes = 1-mesitylimidazole）由中性铑甲硅烷基PhB（Ox ME2）2 Im Mes } RhH（SiH 2 Ph）CO（1）和B（C 6 F 5）3。在这种不寻常的恶唑啉配位亚甲硅烷基结构2是由一个未观察异构体的阳离子铑亚甲硅基物种的重排提议形式[值PhB（OX ME2）2林的Mes } RhH的（SiHPh）CO] [HB（C 6 ˚F 5）3 ]由H抽象生成。复杂2催化有机羰基化合物与硅烷的还原反应，生成氢化硅烷化产物或脱氧产物。这些反应的途径主要受有机硅烷取代度的影响。与伯硅
• Synthesis of alkoxybenzylmethylsilanes and polybenzylmethylsiloxane polymers on their basis
  作者：S. A. Milenin、A. A. Kalinina、V. V. Gorodov、N. G. Vasilenko、M. I. Buzin、A. M. Muzafarov

  DOI：10.1007/s11172-015-1183-0

  日期：2015.10

  procedure for the preparation of alkoxybenzylmethylsilanes by organomagnesium synthesis was developed. The reaction conditions gave the high yields of the target products. A number of benzylmethylsiloxane polymers was synthesized by polycondensation of alkoxybenzylmethylsilanes in anhydrous acetic acid. The products obtained can become a good alternative to phenylsiloxanes in some practical applications

  开发了一种通过有机镁合成制备烷氧基苄基甲基硅烷的有效无溶剂方法。反应条件使目标产物的收率高。许多苄基甲基硅氧烷聚合物是通过烷氧基苄基甲基硅烷在无水乙酸中的缩聚反应合成的。所得产品在一些实际应用中可以成为苯基硅氧烷的良好替代品。
• Single-Walled Cluster Nanotubes for Single-Atom Catalysts with Precise Structures
  作者：Zhong Li、Yunwei Huang、Haoyang Li、Fenghua Zhang、Yazhou Ren、Wenxiong Shi、Qingda Liu、Xun Wang

  DOI：10.1021/jacs.3c09752

  日期：2024.1.10

  low-dimensional nanostructures is a promising strategy for preparing high-performance single-atom catalysts (SACs). Herein, fascinating polyoxometalate cluster-based single-walled nanotubes (POM-SWNTs) with atomically precise structures, uniform diameter, and single-cluster wall thickness are constructed by lacunary POM clusters (PW11 and P2W17 clusters). Isolated metal centers are accurately incorporated into

  在低维纳米结构中空间限制孤立的原子位点是制备高性能单原子催化剂（SAC）的一种有前景的策略。在此，令人着迷的基于多金属氧酸盐簇的单壁纳米管（POM-SWNT）由空位POM簇（PW 11和P 2 W 17簇）构造而成，具有原子精确的结构、均匀的直径和单簇壁厚度。孤立的金属中心准确地融入到 PW 11 -SWNT 和 P 2 W 17 -SWNT 支架中。所得 MPW 11 -SWNT 和 MP 2 W 17 -SWNT 的结构已得到很好的确定（M = Cu、Pt）。分子动力学模拟证明了 POM-SWNT 的稳定性。此外，在二甲基苯基硅烷醇解过程中，PtP 2 W 17 -SWNTs的周转频率比PtP 2 W 17团簇单元高20倍，比Pt纳米粒子高140倍。理论研究表明，将Pt原子掺入P 2 W 17载体中会诱导它们之间直接的电子转移，结合纳米限制环境来增强PtP 2 W 17 -SWNT的催化活性。这项工作展示了使用亚纳米
• Remarkably Robust Monomeric Alkylperoxyzinc Compounds from Tris(oxazolinyl)boratozinc Alkyls and O₂
  作者：Debabrata Mukherjee、Arkady Ellern、Aaron D. Sadow

  DOI：10.1021/ja303440n

  日期：2012.8.8

  Metal alkylperoxides are remarkable, highly effective, yet often thermally unstable, oxidants that may react through a number of possible pathways including O-O homolytic cleavage, M-O homolytic cleavage, nucleophilic O-atom transfer, and electrophilic O-atom transfer. Here we describe a series of zinc alkyl compounds of the type To(M)ZnR (To(M) = tris(4,4-dimethyl-2-oxazolinyl)phenylborate; R = Et, n-C3H7, i-C3H7, t-Bu) that react with O-2 at 25 degrees C to form isolable monomeric alkylperoxides To(M)ZnOOR in quantitative yield. The series of zinc alkylperoxides is crystallographically characterized, and the structures show systematic variations in the Zn-O-O angle and O-O distances. The observed rate law for the reaction of To(M)ZnEt (2) and O-2 is consistent with a radical chain mechanism, where the rate-limiting S(H)2 step involves the interaction of (OOR)-O-center dot and To(M)ZnR. In contrast, To(M)ZnH and To(M)ZnMe are unchanged even to 120 degrees C under 100 psi of O-2 and in the presence of active radical chains (e.g., (OOEt)-O-center dot). This class of zinc alkylperoxides is unusually thermally robust, in that the compounds are unchanged after heating at 120 degrees C in solution for several days. Yet, these compounds are reactive as oxidants with phosphines. Additionally, an unusual alkylperoxy group transfer to organosilanes affords To(M)ZnH and ROOSiR3'.
• Thermal reactions of benzosilacyclobutenes with alcohols
  作者：Kang Kyung-Tae、Seo Hee-Chan、Kim Kwang-Nam

  DOI：10.1016/s0040-4039(00)94944-x

  日期：1985.1