3-(2,3-dibromo-propionyl)-2,2,5-trimethyl-oxazolidine | 52836-52-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 3-(2,3-dibromo-propionyl)-2,2,5-trimethyl-oxazolidine
• 英文别名: 2,2,5-trimethyl-3(2',3'-dibromopropionyl)oxazolidine；2,3-dibromo-1-(2,2,5-trimethyl-1,3-oxazolidin-3-yl)propan-1-one
• CAS: 52836-52-9
• 化学式: C₉H₁₅Br₂NO₂
• 分子量: 329.032
• InChiKey: BDTPKASUAIUTNZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,3-二溴丙酰氯 、 2,2,5-三甲基恶唑烷 在 三乙胺 作用下， 以 苯 为溶剂， 生成 3-(2,3-dibromo-propionyl)-2,2,5-trimethyl-oxazolidine
  参考文献：
  名称：

  Herbicidal antidote compositions with substituted oxazolidines and

  摘要：

  除草剂组合物包括一种活性除草剂化合物和其解毒剂，以及使用方法；解毒剂化合物对应于具有以下式子的取代噁唑烷和噻唑烷：##SPC1## 其中X是氧或硫；R是卤代烷基，烷基或烷基硫代基；R.sub.1、R.sub.2、R.sub.3、R.sub.4、R.sub.5和R.sub.6分别独立地选自氢、低烷基、烷氧基烷基和低烷基醇基的群。

  公开号：

  US03989503A1

文献信息

• Herbicidal antidote compositions with substituted oxazolidines and
  申请人：Stauffer Chemical Company

  公开号：US03989503A1

  公开（公告）日：1976-11-02

  Herbicidal compositions comprising an active herbicidal compound and antidote therefor and the methods of use; the antidote compound corresponds to substituted oxazolidines and thiazolidines having the formula ##SPC1## In which X is oxygen or sulfur; R is haloalkyl, alkyl or alkylthio; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower alkyl, alkoxyalkyl and lower alkylol.

  除草剂组合物包括一种活性除草剂化合物和其解毒剂，以及使用方法；解毒剂化合物对应于具有以下式子的取代噁唑烷和噻唑烷：##SPC1## 其中X是氧或硫；R是卤代烷基，烷基或烷基硫代基；R.sub.1、R.sub.2、R.sub.3、R.sub.4、R.sub.5和R.sub.6分别独立地选自氢、低烷基、烷氧基烷基和低烷基醇基的群。
• N-(haloalkanoyl) oxazolidines
  申请人：Stauffer Chemical Company

  公开号：US04186130A1

  公开（公告）日：1980-01-29

  Substituted oxazolidines and thiazolidines having the formula ##STR1## in which X is oxygen or sulfur; R is haloalkyl, alkyl or alkylthio; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower alkyl, alkoxyalkyl and lower alkylol; provided that when X is oxygen and R is alkyl, then at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 or R.sub.6 is other than hydrogen. The compounds are active as an antidote against crop injury, when used with various herbicides.

  具有以下式子的替代氧唑啉和噻唑啉：##STR1## 其中X为氧或硫；R为卤代烷基，烷基或烷基硫；R.sub.1，R.sub.2，R.sub.3，R.sub.4，R.sub.5和R.sub.6独立地选自氢，低烷基，烷氧基烷基和低烷基醇；但是当X为氧且R为烷基时，至少有一个R.sub.1，R.sub.2，R.sub.3，R.sub.4，R.sub.5或R.sub.6不是氢。这些化合物与各种除草剂一起使用时，可作为防治作物受损的解毒剂。
• 2,2,4-Trimethyl-4-hydroxymethyl-3-dichloroacetyl oxazolidine
  申请人：Stauffer Chemical Company

  公开号：US04243811A1

  公开（公告）日：1981-01-06

  Substituted oxazolidines and thiazolidines having the formula ##STR1## in which X is oxygen or sulfur; R is haloalkyl, alkyl or alkylthio; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower alkyl, alkoxyalkyl and lower alkylol; provided that when X is oxygen and R is alkyl, then at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 or R.sub.6 is other than hydrogen. The compounds are active as an antidote against crop injury, when used with various herbicides.

  具有以下公式的替代氧氮杂环和硫氮杂环：##STR1## 其中X为氧或硫；R为卤代烷基，烷基或烷基硫代基；R.sub.1，R.sub.2，R.sub.3，R.sub.4，R.sub.5和R.sub.6独立地选自氢，较低的烷基，烷氧基烷基和较低的烷基醇；前提是当X为氧且R为烷基时，至少有一个R.sub.1，R.sub.2，R.sub.3，R.sub.4，R.sub.5或R.sub.6不是氢。当与各种除草剂一起使用时，这些化合物可作为防治作物损伤的解毒剂。
• N-Acyl oxazolidines and thiazolidines as herbicides
  申请人：Stauffer Chemical Company

  公开号：US04236011A1

  公开（公告）日：1980-11-25

  Substituted oxazolidines and thiazolidines having the formula ##STR1## in which X is oxygen or sulfur; R is haloalkyl, alkyl or alkylthio; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower alkyl, alkoxyalkyl and lower alkylol; provided that when X is oxygen and R is alkyl, then at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 is other than hydrogen. The compounds are active as an antidote against crop injury, when used with various herbicides.

  具有以下式子##STR1##的替代氧唑啉和硫唑啉，其中X为氧或硫; R为卤代烷基，烷基或烷基硫; 而R.sub.1、R.sub.2、R.sub.3、R.sub.4、R.sub.5和R.sub.6分别独立地选自氢、低烷基、烷氧基烷基和低烷基醇; 前提是当X为氧且R为烷基时，至少有一个R.sub.1、R.sub.2、R.sub.3、R.sub.4、R.sub.5和R.sub.6不是氢。当与各种除草剂一起使用时，这些化合物可作为对作物损伤的解毒剂。
• Substituted oxazolidines and thiazolidines
  申请人：Stauffer Chemical Company

  公开号：US04268677A1

  公开（公告）日：1981-05-19

  Substituted oxazolidines and thiazolidines having the formula ##STR1## in which X is oxygen or sulfur; R is haloalkyl, alkyl or alkylthio; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower alkyl, alkoxyalkyl and lower alkylol; provided that when X is oxygen and R is alkyl, then at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 or R.sub.6 is other than hydrogen. The compounds are active as an antidote against crop injury, when used with various herbicides.

  具有以下式子的替代氧唑啉和硫唑啉：##STR1## 其中X为氧或硫；R为卤代烷基，烷基或烷基硫；R.sub.1、R.sub.2、R.sub.3、R.sub.4、R.sub.5和R.sub.6分别独立地选择自氢、低烷基、烷氧基烷基和低烷基醇的组，但当X为氧且R为烷基时，至少有一个R.sub.1、R.sub.2、R.sub.3、R.sub.4、R.sub.5或R.sub.6不是氢。这些化合物在与各种除草剂一起使用时，可作为一种抗作物损伤的解毒剂。