2-(biphenyl-2-yl)-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(biphenyl-2-yl)-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione
• 英文别名: 4-(2-phenylphenyl)-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
• 化学式: C₂₁H₁₇NO₂
• 分子量: 315.4
• InChiKey: IVDPCBAMVHDKTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• RING-OPENED POLYNORBORNENES
  申请人：JSR Corporation

  公开号：EP1561766A1

  公开（公告）日：2005-08-10

  The invention provides a ring-opened polynorbornene that is relatively low in birefringence, has specific wavelength dependency about birefringence and is excellent in transparency and heat resistance. [Solving means] The polymer of the present invention has a structural unit (I) of the general formula (I): [Chemical formula 1] wherein in the general formula (I), m and n are integers of 0 to 2, X1 is an ethylene or vinylene group, R1 and R2 are individually a hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, and R3 is a group of the general formula (I-1) or (I-2), in which in the general formulae (I-1) and (I-2), R11 to R27 are individually a hydrogen atom; a halogen atom; a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, which may have a linkage containing or not containing oxygen, sulfur, nitrogen and/or silicon atom(s); or a polar group, p and q in the general formula (I-1) are individually 0 or a positive integer, with the proviso that when both p and q are 0, R12 and R15, or R19 and R15 may be bonded to each other to form a carbon ring or heterocyclic ring, and the carbon ring or heterocyclic ring may be either a monocyclic structure or a polycyclic structure, and s in the general formula (I-2) is 0 or a positive integer.

  本发明提供了一种双折射相对较低、对双折射具有特定波长依赖性、透明度和耐热性优异的开环聚降冰片烯。 [解决方法】本发明的聚合物具有通式（I）的结构单元（I）： [化学式 1］ 其中在通式（I）中，m 和 n 是 0 至 2 的整数，X1 是乙烯基或乙烯基，R1 和 R2 分别是氢原子或具有 1 至 30 个碳原子的取代或未取代的烃基，R3 是通式（I-1）或（I-2）的基团，其中在通式（I-1）和（I-2）中，R11 至 R27 分别是氢原子；卤素原子； 具有 1 至 30 个碳原子的取代或未取代的烃基，该烃基可以具有含或不含氧、硫、氮和/或硅原子的连接；或极性基团，通式（I-1）中的 p 和 q 分别为 0 或正整数，但当 p 和 q 均为 0 时，R12 和 R15 或 R19 和 R15 可相互键合形成碳环或杂环，碳环或杂环可为单环结构或多环结构，通式（I-2）中的 s 为 0 或正整数。
• Ring-opened polynorbornenes
  申请人：Miyaki Nobuyuki

  公开号：US20060041092A1

  公开（公告）日：2006-02-23

  The invention provides a ring-opened polynorbornene that is relatively low in birefringence, has specific wavelength dependency about birefringence and is excellent in transparency and heat resistance. [Solving means] The polymer of the present invention has a structural unit (I) of the general formula (I): [Chemical formula 1 ] wherein in the general formula (I), m and n are integers of 0 to 2, X 1 is an ethylene or vinylene group, R 1 and R 2 are individually a hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, and R 3 is a group of the general formula (I-1) or (I-2), in which in the general formulae (I-1) and (I-2), R 11 to R 27 are individually a hydrogen atom; a halogen atom; a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, which may have a linkage containing or not containing oxygen, sulfur, nitrogen and/or silicon atom(s); or a polar group, p and q in the general formula (I-1) are individually 0 or a positive integer, with the proviso that when both p and q are 0, R 12 and R 15 , or R 19 and R 15 may be bonded to each other to form a carbon ring or heterocyclic ring, and the carbon ring or heterocyclic ring may be either a monocyclic structure or a polycyclic structure, and s in the general formula (I-2) is 0 or a positive integer.

  本发明提供了一种双折射相对较低、对双折射具有特定波长依赖性、透明度和耐热性优异的开环聚降冰片烯。[解决方法】本发明的聚合物具有通式（I）的结构单元（I）： [化学式 1 ] 其中，在通式（I）中，m 和 n 是 0 至 2 的整数，X 1 是乙烯基或乙烯基，R 1 和 R 2 分别是氢原子或具有 1 至 30 个碳原子的取代或未取代的烃基，以及 R 3 是通式（I-1）或（I-2）的基团，其中在通式（I-1）和（I-2）中，R 11 至 R 27 通式（I-1）中的 p 和 q 分别为 0 或正整数，但当 p 和 q 均为 0 时，R 12 和 R 15 或 R 19 和 R 15 可相互键合形成碳环或杂环，碳环或杂环可为单环结构或多环结构，通式 (I-2) 中的 s 为 0 或正整数。
• US7157523B2
  申请人：——

  公开号：US7157523B2

  公开（公告）日：2007-01-02
• US7230058B2
  申请人：——

  公开号：US7230058B2

  公开（公告）日：2007-06-12