4'-methyl-N,N-bis(4-methylphenyl)-[1,1'-biphenyl]-4-amine | 124373-59-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4'-methyl-N,N-bis(4-methylphenyl)-[1,1'-biphenyl]-4-amine
• 英文别名: 4'-Methyl-N,N-bis(4-methylphenyl)[1,1'-biphenyl]-4-amine；4-methyl-N-(4-methylphenyl)-N-[4-(4-methylphenyl)phenyl]aniline
• CAS: 124373-59-7
• 化学式: C₂₇H₂₅N
• 分子量: 363.502
• InChiKey: PILONTKKEDAWGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4,4'-二甲基二苯胺 、 4-碘-4’-甲基联苯 在 铜 、 potassium carbonate 作用下， 以 硝基苯 为溶剂， 反应 11.0h， 以49.6%的产率得到4'-methyl-N,N-bis(4-methylphenyl)-[1,1'-biphenyl]-4-amine
  参考文献：
  名称：

  含有偶氮化合物的层状光感受器中的电子转移过程

  摘要：

  光致电子转移（ET）是有机光电器件中载流子光生最重要的过程。在基于偶氮化合物的层状光感受器中，载流子光生通过空穴传输材料 (HTM) 的掺入而敏感。我们研究了这个过程以阐明高度敏化的机制。首先，测量并比较层状光感受器和载流子生成层的光致 ET 效率和整体量子效率。HTM 增强光诱导 ET 的结果意味着 HTM 催化作用以减少活化能。尽管这种外在 ET 独立于电场发生，但随后的成对解离取决于电场。下一个，通过使用 50 多个光感受器在很宽的范围内改变能隙，研究了 ET 的能隙依赖性。测量的效率针对能隙绘制，其中未观察到倒置区域。

  DOI：

  10.1246/bcsj.73.785

文献信息

• Electrophotographic photoconductor, process for forming an image, image forming apparatus and a process cartridge for the same
  申请人：——

  公开号：US20030190540A1

  公开（公告）日：2003-10-09

  Providing an electrophotographic photoconductor comprising a conductive support and a photoconductive layer disposed on the photoconductive support; wherein the photoconductive layer contains an azo compound expressed by a general formula <<1>>. Ar &Parenopenst;N═N—Cp) n general formula <<1>> (in the general formula <<1>>, Ar expresses one of a substituted or non-substituted aromatic carbon hydride group and heterocyclic ring aromatic series group which can be combined by way of a bond group; Cp expresses a coupler residual group; n expresses an integer of one of 1, 2, 3, and 4; at least one of the Cp is a coupler residual group selected from one of the following general formulae <<2>>, <<3>>, and <<4>>.) 1

  提供一种电照相光导体，包括导电支持和设置在光导支承上的光导层；其中，所述光导层含有一种由下式表示的偶氮化合物。
• ELECTROCHROMIC COMPOUND, ELECTROCHROMIC COMPOSITION, AND ELECTROCHROMIC ELEMENT
  申请人：Goto Daisuke

  公开号：US20180208834A1

  公开（公告）日：2018-07-26

  An electrochromic compound represented by the following formula (1) is provided: where each of R 1 to R 9 and Ar 1 to Ar 6 independently represents one of a hydrogen atom, a halogen atom, a monovalent organic group, a group in which two or more aryl and/or heteroaryl groups are bound to each other via a covalent bond, a group in which two or more aryl and/or heteroaryl groups are condensed with each other to form a ring, and a polymerizable functional group; and at least one of Ar 1 to Ar 6 represents an aryl group, a heteroaryl group, a group in which two or more aryl and/or heteroaryl groups are bound to each other via a covalent bond, or a group in which at least two aryl or heteroaryl groups are condensed with each other to form a ring.

  提供以下式（1）所表示的一个电致变色化合物：其中R1至R9和Ar1至Ar6中的每一个独立表示氢原子、卤原子、一价有机基团、通过共价键相互连接的两个或更多芳基和/或杂环芳基组成的基团、通过共价键相互连接的两个或更多芳基和/或杂环芳基组成的环、以及可聚合的功能基团；并且Ar1至Ar6中至少有一个表示芳基、杂环芳基、通过共价键相互连接的两个或更多芳基和/或杂环芳基组成的基团，或者至少有两个芳基或杂环芳基通过共价键相互连接形成环。
• EMISSIVE ARYL-HETEROARYL COMPOUNDS
  申请人：ZHENG SHIJUN

  公开号：US20100326526A1

  公开（公告）日：2010-12-30

  Disclosed herein are compounds represented by Formula 1, wherein R 1 , Ar 1 , X, Ar 2 , Ar a , and Het are described herein. Compositions and light-emitting devices related thereto are also disclosed.

  本文披露了由式子1表示的化合物，其中R1，Ar1，X，Ar2，Ara和Het在此处描述。还披露了相关的组合物和发光装置。
• Electrophotographic photoconductor, process for forming an image, image forming apparatus and process cartridge for the same
  申请人：Shoshi Masayuki

  公开号：US20050112487A1

  公开（公告）日：2005-05-26

  Providing an electrophotographic photoconductor comprising a conductive support and a photoconductive layer disposed on the photoconductive support; wherein the photoconductive layer contains an azo compound expressed by a general formula <<1>>. ArN═N—Cp) n general formula <<1>> (in the general formula <<1>>, Ar expresses one of a substituted or non-substituted aromatic carbon hydride group and heterocyclic ring aromatic series group which can be combined by way of a bond group; Cp expresses a coupler residual group; n expresses an integer of one of 1, 2, 3, and 4; at least one of the Cp is a coupler residual group selected from one of the following general formulae <<2>>, <<3>>, and <<4>>.)

  提供一种电子照相感光鼓，包括一个导电支撑和一个位于导电支撑上的感光层；其中，感光层包含一个由一般式<<1>>表示的偶氮化合物。一般式<<1>>为：ArN═N—Cp)n（在一般式<<1>>中，Ar表示取代或未取代的芳香碳氢基团和杂环芳香系列基团之一，可以通过键基团结合；Cp表示偶合剩余基团；n表示1、2、3和4中的一个整数；Cp中至少有一个是从以下一般式<<2>>、<<3>>和<<4>>中选择的偶合剩余基团之一）。
• Electrophotographic photoreceptor, process for producing the same, and image forming apparatus using same
  申请人：Sharp Kabushiki Kaisha

  公开号：EP0926557A1

  公开（公告）日：1999-06-30

  The invention enables the forming of a highly characteristic image using an electrophotographic photoreceptor the charge-generating layer of which can be produced with better coating properties and which is highly sensitive and electrostatically highly stable in repeated use. The charge-generating layer of a function-separated type photoreceptor contains a τ-type non-metallic phthalocyanine and a vinyl chloride-vinyl acetate copolymer. The weight ratio of τ-type non-metallic phthalocyanine to the vinyl chloride-vinyl acetate copolymer is preferably 1/3 to 3/1 by weight and the copolymer is suitably of vinyl chloride and vinyl acetate, vinyl chloride, vinyl acetate and maleic acid or vinyl chloride, vinyl acetate and vinyl alcohol, especially one containing at least 10% by weight of vinyl alcohol.

  本发明可使用电致发光感光器形成高特征图像，该感光器的电荷发生层具有更好的涂层性能，在重复使用时具有高灵敏度和高静电稳定性。功能分离型感光器的电荷发生层含有τ型非金属酞菁和氯乙烯-醋酸乙烯共聚物。τ型非金属酞菁与氯乙烯-醋酸乙烯共聚物的重量比最好为 1/3 至 3/1（重量比），共聚物最好是氯乙烯和醋酸乙烯、氯乙烯、醋酸乙烯和马来酸或氯乙烯、醋酸乙烯和乙烯醇，特别是含有至少 10%（重量比）乙烯醇的共聚物。