1-Butylphospholane 1-sulfide | 20553-96-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 金属杂环化合物
• 英文名称: 1-Butylphospholane 1-sulfide
• 英文别名: 1-Butylphospholan-1-sulfid；1-Butyl-1-sulfanylidene-1lambda5-phospholane；1-butyl-1-sulfanylidene-1λ5-phospholane
• CAS: 20553-96-2
• 化学式: C₈H₁₇PS
• 分子量: 176.263
• InChiKey: HHNUOOJDCFHIKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  32.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5-phosphonia-spiro[4.4]-nonane iodide 在 三氯硅烷 、 sulfur 、 三乙胺 、 silver(l) oxide 作用下， 以 甲醇 、 苯 为溶剂， 反应 5.0h， 生成 1-Butylphospholane 1-sulfide
  参考文献：
  名称：

  Derkach,N.Ya.; Kirsanov,A.V., Journal of general chemistry of the USSR, 1968, vol. 38, p. 332 - 336

  摘要：

  DOI：

文献信息

• Baccolini; Boga; Negri, Synlett, 2000, # 11, p. 1685 - 1687
  作者：Baccolini、Boga、Negri

  DOI：——

  日期：——
• P-CHIRAL PHOSPHOLANES AND PHOSPHOCYCLIC COMPOUNDS AND THEIR USE IN ASYMMETRIC CATALYTIC REACTIONS
  申请人：THE PENN STATE RESEARCH FOUNDATION

  公开号：EP1451133A2

  公开（公告）日：2004-09-01
• EP1451133A4
  申请人：——

  公开号：EP1451133A4

  公开（公告）日：2006-07-19
• [EN] P-CHIRAL PHOSPHOLANES AND PHOSPHOCYCLIC COMPOUNDS AND THEIR USE IN ASYMMETRIC CATALYTIC REACTIONS<br/>[FR] PHOSPHOLANES P CHIRAUX ET COMPOSES PHOSPHOCYCLIQUES ET LEUR UTILISATION DANS DES REACTIONS CATALYTIQUES ASYMETRIQUES
  申请人：PENN STATE RES FOUND

  公开号：WO2003042135A2

  公开（公告）日：2003-05-22

  Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrigenation, hydride transfer, allylic alkylation, hydrosilytation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation. Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and [m+n] cycloaddition. Processes for the preparation of the ligands are also described.
• [EN] P-CHIRAL PHOSPHOLANES AND PHOSPHOCYCLIC COMPOUNDS AND THEIR USE IN ASYMMETRIC CATALYTIC REACTIONS<br/>[FR] PHOSPHOLANES P-CHIRAUX ET COMPOSES PHOSPHOCYCLIQUES, ET LEUR UTILISATION DANS DES REACTIONS CATALYTIQUES ASYMETRIQUES
  申请人：PENN STATE RES FOUND

  公开号：WO2005117907A2

  公开（公告）日：2005-12-15

  Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrogenation, hydride transfer, allylic alkylation, hydrosilylation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation, Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and [m+n] cycloaddition. Processes for the preparation of the ligands are also described.