3-(tert-butylammonio)propyl sulfate | 1198271-85-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 英文名称: 3-(tert-butylammonio)propyl sulfate
• 英文别名: 3-(Tert-butylazaniumyl)propyl sulfate；3-(tert-butylazaniumyl)propyl sulfate
• CAS: 1198271-85-0
• 化学式: C₇H₁₇NO₄S
• 分子量: 211.282
• InChiKey: OUYBZOJBPKPGOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.2
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  84
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-(tert-butylammonio)propyl sulfate 在 potassium hydroxide 作用下， 以 水 为溶剂， 反应 0.25h， 以57%的产率得到N-tert-butylazetidine
  参考文献：
  名称：

  Microwave-assisted synthesis of azetidines in aqueous media

  摘要：

  Simple azetidines are synthesized in good to excellent yields and high purity via cyclization of 3-(ammonio nio)propyl sulfates derived from primary amines and the cyclic sulfate of 1,3-propanediol. A feature of this methodology includes the accelerated synthesis of azetidines in water under the influence of microwave-assisted heating. (C) 2009 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.tetlet.2009.09.063
• 作为产物：
  描述：

  叔丁胺 、 1,3-丙二醇环硫酸酯 以 乙腈 为溶剂， 以89%的产率得到3-(tert-butylammonio)propyl sulfate
  参考文献：
  名称：

  Microwave-assisted synthesis of azetidines in aqueous media

  摘要：

  Simple azetidines are synthesized in good to excellent yields and high purity via cyclization of 3-(ammonio nio)propyl sulfates derived from primary amines and the cyclic sulfate of 1,3-propanediol. A feature of this methodology includes the accelerated synthesis of azetidines in water under the influence of microwave-assisted heating. (C) 2009 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.tetlet.2009.09.063

文献信息

• HYDROPHILIZING AGENT FOR PRODUCTION OF SELF-EMULSIFYING POLYISOCYANATE COMPOSITION, SELF-EMULSIFYING POLYISOCYANATE COMPOSITION, COATING MATERIAL COMPOSITION, AND COATING FILM
  申请人：Tosoh Corporation

  公开号：EP3760657A1

  公开（公告）日：2021-01-06

  The present invention relates to a hydrophilizing agent for producing a self-emulsifying polyisocyanate composition, the hydrophilizing agent comprising an anionic compound represented by the following formula (1): wherein X represents a sulfo group or a hydroxysulfonyloxy group, R1 represents a straight-chain or branched alkylene group, and R2 represents a straight-chain or branched alkyl group; the total number of carbon atoms included in R1 and R2 is 6 or more and less than 14, and one or two or more carbon atoms in the groups R1 and R2 are optionally replaced with an oxygen atom(s).

  本发明涉及一种用于生产自乳化聚异氰酸酯组合物的亲水剂，该亲水剂包括由下式（1）表示的阴离子化合物： 其中 X 代表磺基或羟基磺酰氧基，R1 代表直链或支链亚烷基，R2 代表直链或支链烷基；R1 和 R2 中包含的碳原子总数为 6 个或 6 个以上且小于 14 个，R1 和 R2 中的一个或两个或两个以上碳原子可选择被氧原子取代。
• Microwave-assisted synthesis of azetidines in aqueous media
  作者：Brendan A. Burkett、Samuel Z. Ting、Gwendolyn C.S. Gan、Christina L.L. Chai

  DOI：10.1016/j.tetlet.2009.09.063

  日期：2009.11

  Simple azetidines are synthesized in good to excellent yields and high purity via cyclization of 3-(ammonio nio)propyl sulfates derived from primary amines and the cyclic sulfate of 1,3-propanediol. A feature of this methodology includes the accelerated synthesis of azetidines in water under the influence of microwave-assisted heating. (C) 2009 Elsevier Ltd. All rights reserved