bis(trifluoromethyl)-1-butene | 115413-08-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: bis(trifluoromethyl)-1-butene
• 英文别名: 2-Trifluoromethyl-1,1,1-trifluoro-2-pentene；1,1,1-trifluoro-2-(trifluoromethyl)pent-2-ene
• CAS: 115413-08-6
• 化学式: C₆H₆F₆
• 分子量: 192.104
• InChiKey: CKHBTIUPYSNZTR-UHFFFAOYSA-N

物化性质

• 沸点：
  76.2±8.0 °C(predicted)
• 密度：
  1.249±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  bis(trifluoromethyl)-1-butene 、 水 以to form 2-trifluoromethyl-1,1,1-trifluoro-2-pentanol的产率得到1,1,1-Trifluor-2-trifluormethyl-2-pentanol
  参考文献：
  名称：

  Partially fluorinated alkanols having a tertiary structure

  摘要：

  具有以下式子的部分氟化烷类小说：##STR1## 其中每个R相同或不同，且选自CF.sub.3，CHF.sub.2，CH.sub.2 F和CH.sub.3 CF.sub.2的群组，而R'是具有1到6个碳原子的烷基或氟烷基。它们在各种工业清洗应用中具有溶剂的实用性，包括冷清洗、干洗和印刷电路板的去焊剂。

  公开号：

  US05254755A1
• 作为产物：
  描述：

  2,2-二氯-1,1,1,3,3,3-六氟丙烷 、 丙醛 在 三苯基膦 作用下， 以 various solvent(s) 为溶剂， 反应 72.0h， 以31%的产率得到bis(trifluoromethyl)-1-butene
  参考文献：
  名称：

  A New Synthesis of 1,1-Bis(trifluoromethyl)-Substituted Alkenes

  摘要：

  1,1-双（三氟甲基）取代烯烃6是通过醛5与三苯基膦（4）及2,2-二氯六氟丙烷（3）反应获得的，产率中等到良好。这些烯烃6通过其他途径不易获得。

  DOI：

  10.1055/s-1987-28135

文献信息

• Solvent compositions comprising unsaturated fluorinated hydrocarbons
  申请人：Nappa Joseph Mario

  公开号：US20070105738A1

  公开（公告）日：2007-05-10

  This invention relates to cleaning compositions comprising unsaturated fluorinated hydrocarbons. The invention further relates to use of said cleaning compositions in methods to clean, degrease, deflux, dewater, and deposit fluorolubricant. The invention further relates to novel unsaturated fluorinated hydrocarbons and their use as cleaning compositions and in the methods listed above.

  本发明涉及包含不饱和氟化碳化合物的清洁组合物。本发明进一步涉及使用该清洁组合物在清洗、去脂、去通量、脱水和沉积氟润滑剂的方法中。本发明还涉及新型不饱和氟化碳化合物及其作为清洁组合物和上述方法中的使用。
• Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foams stabilizers
  申请人：Boggs Janet

  公开号：US20070149437A1

  公开（公告）日：2007-06-28

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. RF compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F- monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F urethanes, and/or R F -foam stabilizers. The R F portion can include at least two —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.

  提供生产过程和系统，包括反应卤代化合物，脱卤化合物，反应醇，反应烯烃和饱和化合物，将至少含有两个—CF3基团的反应物与具有环状基团的反应物反应。提供RF组分，例如RF中间体，RF表面活性剂，RF单体，RF单体单元，RF金属络合物，RF磷酸酯，RF乙二醇，RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个— 基团，至少三个— 基团，和/或至少两个— 基团和至少两个—CH2—基团。提供包括RF表面活性剂组分的清洁剂，乳化剂，油漆，粘合剂，油墨，润湿剂，发泡剂和消泡剂。提供包括RF单体单元的丙烯酸，树脂和聚合物。提供包括具有RF组分的基底的组合物。提供包括RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。
• Production Processes and Systems, Compositions, Surfactants, Monomer Units, Metal Complexes, Phosphate Esters, Glycols, Aqueous Film Forming Foams, and Foam Stabilizers
  申请人：Boggs Janet

  公开号：US20080009655A1

  公开（公告）日：2008-01-10

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohol's, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. R F -compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F -monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F -urethanes, and/or R F -foam stabilizers. The R F portion can include at least two —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit. Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.

  提供了生产过程和系统，其中包括反应卤代化合物，去卤化化合物，反应醇，反应烯烃和饱和化合物，反应至少具有两个-CF3基团的反应物与具有环状基团的反应物。提供了RF组分，例如RF中间体，RF表面活性剂，RF单体，RF单体单元，RF金属配合物，RF磷酸酯，RF乙二醇，RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个- 基团，至少三个- 基团，以及至少两个- 基团和至少两个-CH2-基团。提供了包括RF表面活性剂组分的洗涤剂，乳化剂，油漆，粘合剂，油墨，润湿剂，泡沫剂和消泡剂。提供了包括RF单体单元的丙烯酸，树脂和聚合物。提供了包括具有RF组分的基板的组合物。提供了含有RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。
• SOLVENT COMPOSITIONS COMPRISING UNSATURATED FLUORINATED HYDROCARBONS
  申请人：NAPPA MARIO JOSEPH

  公开号：US20100189885A1

  公开（公告）日：2010-07-29

  Disclosed is a method for removing residue from a surface comprising: contacting the surface with a composition comprising at least one unsaturated fluorinated hydrocarbon selected from the group consisting of compounds having the formula E- or Z—R 1 CH═CHR 2 , wherein R 1 and R 2 are, independently, C 1 to C 6 perfluoroalkyl groups, or C 1 to C 6 hydrofluoroalkyl groups, and recovering the surface from the composition.

  本发明公开了一种从表面去除残留物的方法，包括：将表面与包含至少一种不饱和氟化碳化合物的组合物接触，所述不饱和氟化碳化合物选择自具有E-或Z- R1CH═CHR2公式的化合物组，其中R1和R2分别是C1到C6的全氟烷基或C1到C6的氢氟烷基，然后从组合物中回收表面。
• PRODUCTION PROCESSES AND SYSTEMS, COMPOSITIONS, SURFACTANTS, MONOMER UNITS, METAL COMPLEXES, PHOSPHATE ESTERS, GLYCOLS, AQUEOUS FILM FORMING FOAMS, AND FOAM STABILIZERS
  申请人：Boggs Janet

  公开号：US20120071689A1

  公开（公告）日：2012-03-22

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohol's, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups, R F -compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F -monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F -urethanes, and or R F -foam stabilizers. The R F portion can include at least two groups —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit. Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.

  提供生产过程和系统，包括反应卤代化合物、去卤化化合物、反应醇、反应烯烃和饱和化合物、将至少具有两个—CF3基团的反应物与具有环状基团的反应物反应，RF组分，如RF中间体、RF表面活性剂、RF单体、RF单体单元、RF金属配合物、RF磷酸酯、RF乙二醇、RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个— 基团、至少三个— 基团和/或至少两个— 基团和至少两个—CH2基团。提供了包括RF表面活性剂组分的洗涤剂、乳化剂、油漆、粘合剂、油墨、润湿剂、起泡剂和消泡剂。提供了包括RF单体单元的丙烯酸、树脂和聚合物。提供了包括RF组分的基底上的组合物。提供了可以包括RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。