1,3-Difluoro-5-(3-fluorophenyl)benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-Difluoro-5-(3-fluorophenyl)benzene
• 英文别名: 1,3-difluoro-5-(3-fluorophenyl)benzene
• 化学式: C₁₂H₇F₃
• 分子量: 208.18
• InChiKey: ZHYWWGGAAMXUAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• DIFLUOROMETHOXY-BRIDGE LIQUID CRYSTAL COMPOUND CONTAINING METHYL-SUBSTITUTED 2,3-DIFLUOROPHENYL AND CRYSTAL COMPOSITION
  申请人：Shijiazhuang Chengzhi Yonghua Display Material Co., Ltd

  公开号：US20190345388A1

  公开（公告）日：2019-11-14

  Provided are a difluoromethoxy-bridge liquid crystal compound containing methyl-substituted 2,3-difluorophenyl, a liquid crystal composition containing the compound, and a liquid crystal display element and a liquid crystal display, wherein said liquid crystal composition is represented by the following formula I: wherein the difluoromethoxy-bridge liquid crystal compound containing methyl-substituted 2,3-difluorophenyl not only has a high clearing point (CP) and a prominent low-temperature miscibility with other liquid crystals, but also has a good stability to ultraviolet light, stability to high temperatures, and particularly also a high vertical dielectric constant (ε ⊥ ), and may be applied to the formulation of various types of liquid crystal compositions, and it is particularly prominent that the compound has the advantages of both a good low-temperature miscibility and a high vertical dielectric constant (ε ⊥ ).

  提供的是一种含有甲基取代的2,3-二氟苯基的二氟甲氧基桥液晶化合物，一种含有该化合物的液晶组合物，以及液晶显示元件和液晶显示器。其中，该液晶组合物由下式I表示：其中，含有甲基取代的2,3-二氟苯基的二氟甲氧基桥液晶化合物不仅具有高的清晰点(CP)和与其他液晶的低温混溶性，还具有良好的紫外光稳定性，高温稳定性，特别是高的垂直介电常数(ε⊥)，可用于各种类型的液晶组合物的配方，尤其突出的是该化合物具有良好的低温混溶性和高的垂直介电常数(ε⊥)的优点。
• COMPOSITION FOR CHARGE-TRANSPORT FILM AND IONIC COMPOUND, CHARGE-TRANSPORT FILM AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME, AND PRODUCTION METHOD OF THE ORGANIC ELECTROLUMINESCENCE DEVICE AND PRODUCTION METHOD OF THE CHARGE-TRANSPORT FILM
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2918590A1

  公开（公告）日：2015-09-16

  An composition for a charge-transport film having excellent heat-resistant property, high hole injection/transport capacity and being able to function at a low voltage. Said composition can be used to produce an organic electroluminescence device.

  一种具有优异耐热性、高空穴注入/传输能力并能在低电压下运作的电荷传输膜的组合物。该组合物可用于制备有机电致发光器件。
• Halogenated S-(perfluoroalkyl)dibenzothiophenium salt and its production methods
  申请人：Zhejiang Jiuzhou Pharmaceutical Co., Ltd.

  公开号：US10155739B2

  公开（公告）日：2018-12-18

  Halogenated S-(perfluoroalkyl)dibenzothiophenium salt represented by the following general formula (I): This compound is a new, reactive, and industrially useful reagent for perfluoroalkylating organic compounds. The reagent can be prepared by a one-pot process or a two-step reaction process from a halogenated biphenyl and easily isolated by a filtration method. In addition, the halogenated biphenyl can be recovered by desulfurization from a halogenated dibenzothiophene obtained as a side-product by the usage of the reagent.

  由以下通式 (I) 代表的卤代 S-(全氟烷基)二苯并噻吩盐： 该化合物是一种新型、活性和工业上有用的全氟烷基化有机化合物试剂。该试剂可通过一锅法或两步反应法从卤化联苯中制备，并可通过过滤法轻松分离。此外，卤化联苯还可以通过脱硫从使用该试剂得到的副产品卤化二苯并噻吩中回收。
• Liquid crystal compound containing 2,3,4-trisubstituted benzene and composition thereof
  申请人：SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO.,LTD.

  公开号：US10767113B2

  公开（公告）日：2020-09-08

  Provided is a liquid crystal compound containing 2,3,4-trisubstituted benzene, a liquid crystal composition thereof, and a liquid crystal display element or a liquid crystal display comprising the liquid crystal compound or the liquid crystal composition, wherein the liquid crystal composition has a lower viscosity, can achieve a quick response, and further has a moderate dielectric anisotropy Δε, a moderate optical anisotropy Δn, and high stability to heat and light. The liquid crystal display element or liquid crystal display comprising the liquid crystal composition has the properties of a wider nematic phase temperature range, an appropriate birefringence anisotropy, a very high electrical resistivity, a good ultraviolet resistant property, a high charge retention rate, a low vapor pressure etc., and particularly, the liquid crystal compound or the liquid crystal composition has the advantage of a high light transmittance.

  本发明提供了一种含有 2,3,4-三取代苯的液晶化合物、其液晶组合物以及包含该液晶化合物或该液晶组合物的液晶显示元件或液晶显示器，其中该液晶组合物具有较低的粘度，可实现快速响应，并进一步具有适度的介电各向异性Δε、适度的光学各向异性Δn以及较高的热稳定性和光稳定性。由液晶组合物组成的液晶显示元件或液晶显示器具有更宽的向列相温度范围、适当的双折射各向异性、极高的电阻率、良好的抗紫外线性能、高电荷保持率、低蒸气压等特性，特别是液晶化合物或液晶组合物具有高透光率的优点。
• Liquid crystal composition
  申请人：Shijiazhuang Chengzhi Yonghua Display Material Co., Ltd

  公开号：US10954445B2

  公开（公告）日：2021-03-23

  Disclosed is a liquid crystal composition comprising one or more compounds represented by formula I and/or formula II and one or more compounds represented by formula III: wherein the definition of each substituent is given. The composition involved in the present invention has a low viscosity γ1, a high clearing point Tni and a large optical anisotropy Δn, and can realize a rapid response of liquid crystal display.

  本发明公开了一种液晶组合物，它包含一种或多种由式 I 和/或式 II 代表的化合物和一种或多种由式 III 代表的化合物： 其中给出了各取代基的定义。本发明所涉及的组合物具有低粘度 γ1、高清澈点 Tni 和大光学各向异性 Δn，可实现液晶显示器的快速响应。