imide of methylnorbornenedicarboxylic acid | 91950-04-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: imide of methylnorbornenedicarboxylic acid
• 英文别名: 5-methyl-3a,4,7,7a-tetrahydro-4,7-methano-isoindole-1,3-dione；8-Methyl-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
• CAS: 91950-04-8
• 化学式: C₁₀H₁₁NO₂
• mdl: MFCD03968052
• 分子量: 177.203
• InChiKey: QYLALJLLMRXOAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  46.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  anhydride of 3-methyl-Δ²-norbornene-8,9-dicarboxylic acid 在 氯化胆碱 、 尿素 作用下， 反应 1.0h， 以72%的产率得到imide of methylnorbornenedicarboxylic acid
  参考文献：
  名称：

  在低共熔溶剂（DES）氯化胆碱/脲中由酸酐和尿素合成N-未取代的环酰亚胺

  摘要：

  N-未取代的环状酰亚胺很容易在深共熔溶剂（DES）胆碱氯化物（ChCl）/脲中由具有尿素的酸酐合成。尿素既是DES组分又是氮源，这使该方案具有反应平稳，产物易于分离，ChCl /脲易于回收和再循环的优点。

  DOI：

  10.1007/s11696-019-00969-6

文献信息

• Study of the products of the reaction of succinic anhydride derivatives with urea
  作者：A. V. Fokin、M. V. Pospelov、A. V. Ignatov、M. V. Galakhov、N. S. Ovchinnikova、L. T. Zhuravlev

  DOI：10.1007/bf00961127

  日期：1988.8
• FOKIN, A. V.;POSPELOV, M. V.;IGNATOV, A. V.;GALAXOV, M. V.;OVCHINNIKOVA, +, IZV. AN CCCP. CEP. XIM.,(1988) N 8, 1900-1902
  作者：FOKIN, A. V.、POSPELOV, M. V.、IGNATOV, A. V.、GALAXOV, M. V.、OVCHINNIKOVA, +

  DOI：——

  日期：——
• OXYGEN-ABSORBING RESIN COMPOSITION
  申请人：TOYO SEIKAN GROUP HOLDINGS, LTD.

  公开号：US20140335297A1

  公开（公告）日：2014-11-13

  An oxygen-absorbing resin composition containing a base resin having a thermoplastic resin; and an oxygen-absorbing component having at least the one selected from the group consisting of an ester, an amide, an imide or a dicarboxylic acid derived from an acid anhydride represented by the following formula (1), wherein, a ring X is an aliphatic ring having an unsaturated bond, n is a number of the substituents Y bonded to the ring X and is an integer of 0 or 1, and Y is an alkyl group, and a polymer having a constituent unit stemming from the acid anhydride. An oxygen-absorbing polyester resin composition exhibits excellent oxygen-absorbing property even in the absence of transition metal catalyst without accompanied by the deterioration of the polyester resin used as a the base resin, the oxygen-absorbing property being strong enough for maintaining gas-barrier properties.
• Synthesis of N-unsubstituted cyclic imides from anhydride with urea in deep eutectic solvent (DES) choline chloride/urea
  作者：Luxiao Liu、Hong-Yu Zhang、Guohui Yin、Yuecheng Zhang、Jiquan Zhao

  DOI：10.1007/s11696-019-00969-6

  日期：2020.4

  N-Unsubstituted cyclic imides were readily synthesized in deep eutectic solvent (DES) choline chloride (ChCl)/urea from anhydrides with urea. Urea serves as both a DES component and a nitrogen source, which endows the protocol with advantages of smooth reaction, easy separation of products, simple recovery and recycling of ChCl/urea.

  N-未取代的环状酰亚胺很容易在深共熔溶剂（DES）胆碱氯化物（ChCl）/脲中由具有尿素的酸酐合成。尿素既是DES组分又是氮源，这使该方案具有反应平稳，产物易于分离，ChCl /脲易于回收和再循环的优点。