3,3'-(perfluorocyclopent-1-ene-1,2-diyl)bis(2-(4-(tert-butyl)phenyl)-6-(2-(2-(2-ethoxyethoxy)ethoxy)ethoxy)benzofuran) | 1429208-29-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 2-芳基苯并呋喃类黄酮
• 英文名称: 3,3'-(perfluorocyclopent-1-ene-1,2-diyl)bis(2-(4-(tert-butyl)phenyl)-6-(2-(2-(2-ethoxyethoxy)ethoxy)ethoxy)benzofuran)
• 英文别名: 3,3'-(Hexafluorocyclopentene-1,2-diyl)bis[2-(4-tert-butylphenyl)-6-(3,6,9-trioxaundecane-1-yloxy)benzofuran]；2-(4-tert-butylphenyl)-3-[2-[2-(4-tert-butylphenyl)-6-[2-[2-(2-ethoxyethoxy)ethoxy]ethoxy]-1-benzofuran-3-yl]-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-6-[2-[2-(2-ethoxyethoxy)ethoxy]ethoxy]-1-benzofuran
• CAS: 1429208-29-6
• 化学式: C₅₇H₆₆F₆O₁₀
• 分子量: 1025.14
• InChiKey: IKYGGYWCRZNYCO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  73
• 可旋转键数：
  28
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  100
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  3,3'-(perfluorocyclopent-1-ene-1,2-diyl)bis(2-(4-(tert-butyl)phenyl)-6-(2-(2-(2-ethoxyethoxy)ethoxy)ethoxy)benzofuran) 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  A “Plug-and-Play” Method to Prepare Water-Soluble Photoresponsive Encapsulated Upconverting Nanoparticles Containing Hydrophobic Molecular Switches

  摘要：

  A convenient and versatile protocol to encapsulate lanthanide doped upconverting nanoparticles by an amphiphilic polymer shell containing photoresponsive diarylethene chromophores was developed. The assemblies are all water-soluble and fluoresce in the visible region of the spectrum when excited with 980 nm near-infrared light. The fluorescent emission can be selectively and reversibly modulated by alternatively irradiating the photoresponsive nanoparticles with UV light and visible light, which triggers ring-closing and ring-opening reactions of the chromophores, respectively. Fluorescence lifetime experiments suggest that the quenching mechanism is a combination of energy transfer and emission-reabsorption processes. These photoresponsive upconverting nanoparticles have the potential to advance bioimaging and other applications in nanophotonics.

  DOI：

  10.1021/cm400802d
• 作为产物：
  描述：

  以 乙腈 为溶剂， 生成 3,3'-(perfluorocyclopent-1-ene-1,2-diyl)bis(2-(4-(tert-butyl)phenyl)-6-(2-(2-(2-ethoxyethoxy)ethoxy)ethoxy)benzofuran)
  参考文献：
  名称：

  A “Plug-and-Play” Method to Prepare Water-Soluble Photoresponsive Encapsulated Upconverting Nanoparticles Containing Hydrophobic Molecular Switches

  摘要：

  A convenient and versatile protocol to encapsulate lanthanide doped upconverting nanoparticles by an amphiphilic polymer shell containing photoresponsive diarylethene chromophores was developed. The assemblies are all water-soluble and fluoresce in the visible region of the spectrum when excited with 980 nm near-infrared light. The fluorescent emission can be selectively and reversibly modulated by alternatively irradiating the photoresponsive nanoparticles with UV light and visible light, which triggers ring-closing and ring-opening reactions of the chromophores, respectively. Fluorescence lifetime experiments suggest that the quenching mechanism is a combination of energy transfer and emission-reabsorption processes. These photoresponsive upconverting nanoparticles have the potential to advance bioimaging and other applications in nanophotonics.

  DOI：

  10.1021/cm400802d

文献信息

• DIARYLETHENE COMPOUNDS AND USES THEREOF
  申请人：SWITCH MATERIALS, INC.

  公开号：US20160083398A1

  公开（公告）日：2016-03-24

  A compound according to Formula IA and IB, reversibly convertible under photochromic and electrochromic conditions between a ring-open isomer A and a ring-closed isomer B is provided. For substitutent groups, Z is N, O or S; each R 1 is independently selected from the group consisting of H, or halo; each R 2 is independently selected from the group consisting of H, halo, a polymer backbone, alkyl or aryl; or, when both R 2 together form —CH═CH— and form part of a polymer backbone; each R 3 is independently selected from the group consisting of H, halo, alkyl, alkoxy, thioalkyl or aryl; each R 4 is aryl; and each R 5 is independently selected from the group consisting of H, halo, alkyl, alkoxy, thioalkyl or aryl.

  本发明提供了一种按照式IA和IB的化合物，在光致变色和电致变色条件下，可在环开放异构体A和环闭合异构体B之间可逆地转化。对于取代基，Z为N、O或S；每个R1独立地选自H或卤素；每个R2独立地选自H、卤素、聚合物骨架、烷基或芳基；或者，当两个R2一起形成-CH═CH-并形成聚合物骨架的一部分时；每个R3独立地选自H、卤素、烷基、烷氧基、硫代烷基或芳基；每个R4为芳基；每个R5独立地选自H、卤素、烷基、烷氧基、硫代烷基或芳基。
• Diarylethene compounds and uses thereof
  申请人：SWITCH MATERIALS, INC.

  公开号：US10072023B2

  公开（公告）日：2018-09-11

  A compound according to Formula IA and IB, reversibly convertible under photochromic and electrochromic conditions between a ring-open isomer A and a ring-closed isomer B is provided. For substitutent groups, Z is N, O or S; each R1 is independently selected from the group consisting of H, or halo; each R2 is independently selected from the group consisting of H, halo, a polymer backbone, alkyl or aryl; or, when both R2 together form —CH═CH— and form part of a polymer backbone; each R3 is independently selected from the group consisting of H, halo, alkyl, alkoxy, thioalkyl or aryl; each R4 is aryl; and each R5 is independently selected from the group consisting of H, halo, alkyl, alkoxy, thioalkyl or aryl.

  提供了一种根据式 IA 和 IB 的化合物，该化合物在光致变色和电致变色条件下可在开环异构体 A 和闭环异构体 B 之间进行可逆转换。对于取代基，Z 是 N、O 或 S；每个 R1 独立地选自 H 或卤代；每个 R2 独立地选自 H、卤代、聚合物骨架、烷基或芳基；或者，当两个 R2 一起形成 -CH═CH- 并构成聚合物骨架的一部分时；每个 R3 独立地选自由 H、卤素、烷基、烷氧基、硫代烷基或芳基组成的组；每个 R4 是芳基；每个 R5 独立地选自由 H、卤素、烷基、烷氧基、硫代烷基或芳基组成的组。
• US2014/256936
  申请人：——

  公开号：——

  公开（公告）日：——
• PHOTOCHROMIC AND ELECTROCHROMIC DIARYLCYCLOPENTENE DERIVATIVES AS OPTICAL FILTERS
  申请人：Switch Materials, Inc.

  公开号：EP2760969A1

  公开（公告）日：2014-08-06
• US20140256936A1
  申请人：——

  公开号：US20140256936A1

  公开（公告）日：2014-09-11