diethyl 6-methyl-2-phenyl-4-(p-tolylamino)benzene-1,3-dicarboxylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diethyl 6-methyl-2-phenyl-4-(p-tolylamino)benzene-1,3-dicarboxylate
• 英文别名: Diethyl 3-methyl-5-[(4-methylphenyl)amino]biphenyl-2,6-dicarboxylate；diethyl 4-methyl-6-(4-methylanilino)-2-phenylbenzene-1,3-dicarboxylate
• 化学式: C₂₆H₂₇NO₄
• 分子量: 417.505
• InChiKey: TUCBQSKGXCMNCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  31
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  64.6
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  N-(4-tolyl)-5-methyl-3-phenyl-2,4-diethoxycarbonyl-1,5-cyclohexadienylamine 在 sulfur 作用下， 以45%的产率得到diethyl 6-methyl-2-phenyl-4-(p-tolylamino)benzene-1,3-dicarboxylate
  参考文献：
  名称：

  摘要：

  Polysubstituted diphenylamines were synthesized by dehydration of cyclohexadienylarylamines or dehydration-dehydrogenation of hydroxycyclohexenylarylamines. Sulfur and a mixture of copper and lithium chlorides in the presence of copper oxide were used as aromatizing agents.

  DOI：

  10.1023/a:1013963306250

文献信息

• ——
  作者：V. V. Sorokin、A. V. Grigor'ev、K. V. Kovalev、A. P. Kriven'ko

  DOI：10.1023/a:1013963306250

  日期：——

  Polysubstituted diphenylamines were synthesized by dehydration of cyclohexadienylarylamines or dehydration-dehydrogenation of hydroxycyclohexenylarylamines. Sulfur and a mixture of copper and lithium chlorides in the presence of copper oxide were used as aromatizing agents.