1,1,1,2,2,3,3-heptafluoro-4,4-bis-trifluoromethyl-heptane | 67728-31-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 1,1,1,2,2,3,3-heptafluoro-4,4-bis-trifluoromethyl-heptane
• 英文别名: 1,1,1,2,2,3,3-Heptafluoro-4,4-bis(trifluoromethyl)heptane
• CAS: 67728-31-8
• 化学式: C₉H₇F₁₃
• 分子量: 362.134
• InChiKey: CVZIMSFXDJCVHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为产物：
  描述：

  (E)-全氟代(4-甲基-2-戊烯) 、 1-碘代丙烷 、 氟化铯 以43%的产率得到
  参考文献：
  名称：

  DMOWSKI, W.;WOZNIACKI, R., J. FLUOR. CHEM., 36,(1987) N 4, 385-394

  摘要：

  DOI：

文献信息

• Alkylation of perfluoro-2-methyl-2-pentylcarbanion with alkyl and allyl halides
  作者：Wojciech Dmowski、Ryszard Wozniacki

  DOI：10.1016/s0022-1139(00)81980-6

  日期：1987.9
• Methods for Making Functionalized Fluorinated Monomers, Fluorinated Monomers, and Compositions for Making the Same
  申请人：ETNA-Tec, Ltd.

  公开号：US20220213016A1

  公开（公告）日：2022-07-07

  A method of making a functionalized fluorinated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a functionalized fluorinated monomer includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon.
• DISPERSION LIQUID, COMPOSITION, CURED FILM, COLOR FILTER, SOLID-STATE IMAGING ELEMENT, AND IMAGE DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20220213296A1

  公开（公告）日：2022-07-07

  A dispersion liquid contains an inorganic oxide particle surface-treated with at least one of a compound represented by Formula Si(R A1 )(X A1 ) 3 or a compound represented by Formula Si(R A2 )(R A20 )(X A2 ) 2 , polysiloxane having at least one of a T unit represented by Formula [R B1 SiO 3/2 ] or a D unit represented by Formula [R B2 R B20 SiO], and an organic solvent, where a content of the polysiloxane is 0.5% to 39% by mass with respect to a total amount of the inorganic oxide particle and the polysiloxane, in which in the formula, R A1 , R A2 , R B1 , and R B2 represent a functional group, X A1 and X A2 represent a hydroxyl group or a hydrolyzable group, and R A20 and R B20 represent an alkyl group or an aryl group.