2,4,6,8-Tetrachlor-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-cyclotetraphosphazatetraen | 751-68-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6,8-Tetrachlor-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-cyclotetraphosphazatetraen
• 英文别名: 2,4,6,8-Tetrachlor-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-tetrazatetraphosphozin；Tetrameres Phenylphosphornitrilchlorid；2,4,6,8-Tetrachlor-2,4,6,8-tetraphenyltetraphosphonitril；Phenylchlor-tetraphosphonitril；2,4,6,8-Tetrachlor-2,4,6,8-tetraphenyl-cyclotetraphosphazatetraen；2,4,6,8-Tetrachloro-2,4,6,8-tetraphenyl-1,3,5,7,2lambda~5~,4lambda~5~,6lambda~5~,8lambda~5~-tetrazatetraphosphocine；2,4,6,8-tetrachloro-2,4,6,8-tetraphenyl-1,3,5,7-tetraza-2λ5,4λ5,6λ5,8λ5-tetraphosphacycloocta-1,3,5,7-tetraene
• CAS: 751-68-8
• 化学式: C₂₄H₂₀Cl₄N₄P₄
• 分子量: 630.157
• InChiKey: CFPGAEXNMOVEBI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.1
• 重原子数：
  36
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4,6,8-Tetrachlor-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-cyclotetraphosphazatetraen 在 氨 作用下， 以50%的产率得到2,4,6,8-Tetraamino-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-tetrazatetraphosphocin
  参考文献：
  名称：

  Inorganic-Organic Hybrids Basedon Cyclotetraphosphazenes

  摘要：

  Organic cyclic and oligoaminoacid derivatives of cyclotetraphosphazenes were synthesized and characterized. WAXS and DSC methods were applied to the bull? and LB-films study, being different crystalline structures are shown both for initial cyclotetraphosphazenes and for their organic hybrids.

  DOI：

  10.1080/15421400390193459

文献信息

• β-trans-[N4{P(Ph)(C6H 11N)}4]4−; a tetraanionic ligand system exhibiting two separated tetradentate coordination sites of concave-shaped cavities
  作者：Alexander Steiner、Dominic S. Wright

  DOI：10.1039/a607055h

  日期：——

  β-trans-[N 4 P(Ph)(C 6 H 11 NH)} 4 ] can be deprotonated at all four N–H functions with BuLi in toluene yielding Li 4 β-trans-[N 4 P(Ph)(C 6 H 11 NH)} 4 ]}, using an excess of BuLi in the presence of thf, the lithium enolate co-complex Li 6 β-trans-[N 4 P(Ph)(C 6 H 11 N)} 4 ](CH 2 CHO ) 2 }·4thf is formed,in which the tetraanionic ligand β-trans-[N 4 P(Ph)(C 6 H 11 N)} 4 ] 4- exhibits two separated coordination sites; both act in a tetradentate way and form concave-shaped cavities.

  δ-反式-[N 4 P(Ph)(C 6 H 11 NH)} 4 ]可以用 BuLi 在甲苯中对所有四个 NâH 功能进行去质子化，得到 Li 4 δ-反式-[N 4 P(Ph)(C 6 H 11 NH)} 4 ]}，在有 thf 的情况下使用过量的 BuLi、形成锂烯醇共络合物 Li 6 β-trans-[N 4 P(Ph)(C 6 H 11 N)} 4 ](CH 2 CHO ) 2 }Â-4thf，其中四阴离子配体 β-trans-[N 4 P(Ph)(C 6 H 11 N)} 4 ]4 显示出两个分离的配位位点；这两个配位以四价方式作用，并形成凹形空腔。
• ALAPISHVILI M. G.; POPOVA G. V.; VORONTSOV E. D.; KIREEV V. V.; CYBOPOB N+, SAKARTVELOS CCP METSNIEREBATA AKADEMIIS MOAMBE, SOOBSHCH. AN GRUZSSR, 198+
  作者：ALAPISHVILI M. G.、 POPOVA G. V.、 VORONTSOV E. D.、 KIREEV V. V.、 CYBOPOB N+

  DOI：——

  日期：——
• Inorganic-Organic Hybrids Basedon Cyclotetraphosphazenes
  作者：Galina Popova、Vjacheslav Kireev、Alexander Spitsyn、Hirotaka Ihara、Maxim Scherbina、Sergei Chvalun

  DOI：10.1080/15421400390193459

  日期：2003.1.1

  Organic cyclic and oligoaminoacid derivatives of cyclotetraphosphazenes were synthesized and characterized. WAXS and DSC methods were applied to the bull? and LB-films study, being different crystalline structures are shown both for initial cyclotetraphosphazenes and for their organic hybrids.