5-[4-(Bromomethyl)phenyl]-2-[4-[2-[4-[5-[4-(bromomethyl)phenyl]-3-butylfuran-2-yl]phenyl]ethyl]phenyl]-3-butylfuran | 629670-35-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 呋喃
• 英文名称: 5-[4-(Bromomethyl)phenyl]-2-[4-[2-[4-[5-[4-(bromomethyl)phenyl]-3-butylfuran-2-yl]phenyl]ethyl]phenyl]-3-butylfuran
• 英文别名: 5-[4-(bromomethyl)phenyl]-2-[4-[2-[4-[5-[4-(bromomethyl)phenyl]-3-butylfuran-2-yl]phenyl]ethyl]phenyl]-3-butylfuran
• CAS: 629670-35-5
• 化学式: C₄₄H₄₄Br₂O₂
• 分子量: 764.64
• InChiKey: FTCDBWJZLUTPSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.8
• 重原子数：
  48
• 可旋转键数：
  15
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-[4-(Bromomethyl)phenyl]-2-[4-[2-[4-[5-[4-(bromomethyl)phenyl]-3-butylfuran-2-yl]phenyl]ethyl]phenyl]-3-butylfuran 在 苯基锂 作用下， 以 四氢呋喃 、 乙醚 、 环己烷 为溶剂， 反应 2.0h， 以76%的产率得到3,18-Dibutyl-33,38-dioxaheptacyclo[24.2.2.26,9.212,15.220,23.12,5.116,19]octatriaconta-1(28),2,4,6(37),7,9(36),12(35),13,15(34),16,18,20,22,26,29,31-hexadecaene
  参考文献：
  名称：

  Furan-Containing Oligoaryl Cyclophanene

  摘要：

  Furan-containing oligoaryl cyclophanene 1 and the corresponding cyclophane 2 were synthesized from propargylic dithioacetal 3. The electrochemical and photophysical properties and the fluxional behavior of these molecules have been examined. The emission of 1 appeared at 499 nm whereas that of 2 appeared at 389 nm.

  DOI：

  10.1021/ol0356688
• 作为产物：
  描述：

  4-[2-(4-甲酰基苯基)乙基]苯甲醛 在 正丁基锂 、 三溴化磷 、 二异丁基氢化铝 作用下， 以 四氢呋喃 、 正己烷 、 苯 为溶剂， 反应 21.83h， 生成 5-[4-(Bromomethyl)phenyl]-2-[4-[2-[4-[5-[4-(bromomethyl)phenyl]-3-butylfuran-2-yl]phenyl]ethyl]phenyl]-3-butylfuran
  参考文献：
  名称：

  Furan-Containing Oligoaryl Cyclophanene

  摘要：

  Furan-containing oligoaryl cyclophanene 1 and the corresponding cyclophane 2 were synthesized from propargylic dithioacetal 3. The electrochemical and photophysical properties and the fluxional behavior of these molecules have been examined. The emission of 1 appeared at 499 nm whereas that of 2 appeared at 389 nm.

  DOI：

  10.1021/ol0356688

文献信息

• Furan-Containing Oligoaryl Cyclophanene
  作者：Jui-Chang Tseng、Shou-Ling Huang、Cheng-Lan Lin、Hsin-Chieh Lin、Bih-Yaw Jin、Chun-Yan Chen、Jen-Kan Yu、Pi-Tai Chou、Tien-Yau Luh

  DOI：10.1021/ol0356688

  日期：2003.11.1

  Furan-containing oligoaryl cyclophanene 1 and the corresponding cyclophane 2 were synthesized from propargylic dithioacetal 3. The electrochemical and photophysical properties and the fluxional behavior of these molecules have been examined. The emission of 1 appeared at 499 nm whereas that of 2 appeared at 389 nm.