申请人:JSR Corporation
公开号:EP1302507A2
公开(公告)日:2003-04-16
A thermoplastic elastomer composition having excellent heat aging characteristics, weather resistance, low-temperature physical properties, oil resistance and flexibility, and moldings using the same, such as hoses, are disclosed. The thermoplastic elastomer composition is obtained by dynamically heat treating a mixture containing (A) an olefin resin, (B) an unsaturated group-containing acrylic rubber, and (D) an inorganic filler in the presence of (E) a crosslinking agent, the component (B) comprising (B1) from 55 to 94.99% by weight of a structural unit derived from an acrylic acid alkyl ester monomer and/or an acrylic acid alkoxyalkyl ester monomer, (B2) from 0.01 to 20% by weight of a structural unit derived from a monomer having a carbon-carbon double bond in a side chain thereof, (B3) from 5 to 30% by weight of a structural unit derived from an unsaturated acrylonitrile monomer, and (B4) from 0 to 30% by weight of a structural unit derived from a monomer copolymerizable therewith, provided that the sum of (B1), (B2), (B3) and (B4) is 100% by weight.
本发明公开了一种热塑性弹性体组合物,该组合物具有优异的热老化特性、耐候性、低温物理性能、耐油性和柔韧性,并公开了使用该组合物的模塑件,如软管。该热塑性弹性体组合物是通过动态热处理含有(A)烯烃树脂、(B)含不饱和基团的丙烯酸橡胶和(D)无机填料的混合物,在(E)交联剂的存在下获得的,组分(B)包括(B1)以重量计从丙烯酸烷基酯单体和/或丙烯酸烷氧基烷基酯单体衍生出的结构单元的 55% 至 94.99%,(B2)以重量计从丙烯酸烷基酯单体和/或丙烯酸烷氧基烷基酯单体衍生出的结构单元的 0.(B3)5-30%(按重量计)由不饱和丙烯腈单体衍生的结构单元,以及(B4)0-30%(按重量计)由可与之共聚的单体衍生的结构单元,条件是(B1)、(B2)、(B3)和(B4)之和为 100%(按重量计)。