7-[(4-氯苯基)羰基]-3-甲基-7-氮杂-3-氮鎓杂二环[3.3.1]壬烷(2Z)-3-羧基丙-2-烯酸酯 | 90332-87-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 7-[(4-氯苯基)羰基]-3-甲基-7-氮杂-3-氮鎓杂二环[3.3.1]壬烷(2Z)-3-羧基丙-2-烯酸酯
• 英文名称: 4-Methyl-6-(1-methylethyl)-1,3-benzenediamine
• 英文别名: 4-methyl-6-propan-2-ylbenzene-1,3-diamine
• CAS: 90332-87-9
• 化学式: C₁₀H₁₆N₂
• 分子量: 164.25
• InChiKey: CVSIGCPGGOVWDT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,4-二氨基甲苯 、 三聚丙烯 生成 7-[(4-氯苯基)羰基]-3-甲基-7-氮杂-3-氮鎓杂二环[3.3.1]壬烷(2Z)-3-羧基丙-2-烯酸酯
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• ALDIMINE AND COMPOSITION CONTAINING ALDIMINE
  申请人：BURCKHARDT Urs

  公开号：US20110253309A1

  公开（公告）日：2011-10-20

  Aldimines of Formula (I), which can be used as latent curing agents in curing compositions, for example, in moisture-curing polyurethane compositions that have isocyanate groups. The aldimines are compounds that can be liquid at room temperature, can have a hardly noticeable aldehyde odor before, during and after hydrolysis, and can have a long shelf life. An aldehyde in polyurethane compositions that is released during hydrolysis has only a slight softening effect and can exhibit very little tendency to migrate or exude.

  式(I)的醛缩胺可以用作固化组合物中的潜在固化剂，例如在具有异氰酸酯基团的湿气固化聚氨酯组合物中。这些醛缩胺化合物可以在室温下为液体，水解前、期间和后几乎没有醛类气味，并且可以具有很长的货架寿命。在水解期间释放的聚氨酯组合物中的醛仅具有轻微的软化效果，并且可以表现出极少的迁移或渗出倾向。
• Mono-tertiary-alkylated toluenediamine and derivatives
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0177916A1

  公开（公告）日：1986-04-16

  This invention relates to a class of tertiary-alkyltoluenediamines having alkyl groups ortho to an amine group. More particularly the aromatic diamines are represented by the formulas: wherein R1, R2 and R3 are C1-3 alkyl groups or R2 and R3 are combined to form a C5-6 membered ring. The above described alkylated aromatic diamines have been found to be well suited for use as a chain extender in forming polyurethane/urea elastomer systems and the mono tert-butyltoluenediamine isomers have been found to be non- mutagenic in the Ames test.

  本发明涉及一类叔烷基甲苯二胺，其烷基正交于一个胺基。 更具体地说，芳香族二胺由以下公式表示：其中 R1、R2 和 R3 为 C1-3 烷基，或 R2 和 R3 组合形成一个 C5-6 分子环。 上述烷基化芳香族二胺已被发现非常适合用作聚氨酯/尿素弹性体系统的扩链剂，并且单叔丁基甲苯二胺异构体在艾姆斯试验中被发现无诱变性。
• Alkenylated toluenediamines for use in preparing polyurethane/urea systems
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0235825A2

  公开（公告）日：1987-09-09

  This invention relates to a class of alkenylated toluenediamines having at least one alkenyl group ortho to an amine group. More particularly the toluenediamines are represented by the formula: wherein R1, R2, R3, R4 and Rs are hydrogen. C1-3 aliphatic, phenyl, halogen or alkoxy radicals, or R2 and R4 or Rs are bridged via an alkylene radical -(CH2)y- wherein y=2 to 5, and x is one or two provided that in said formula at least one of R1, R2, R3, R4 or R5 is C1 or greater. The above described alkenylated toluenediamines have been found to be well suited as antioxidants and as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少有一个烯基与胺基正交的烯化甲苯二胺。更具体地说，这些甲苯二胺由式表示： 其中 R1、R2、R3、R4 和 Rs 为氢。C1-3脂肪族、苯基、卤素或烷氧基，或 R2 和 R4 或 Rs 通过亚烷基-(CH2)y-桥接，其中 y=2 至 5，且 x 为 1 或 2，条件是在所述式中，R1、R2、R3、R4 或 R5 中至少有一个是 C1 或更大。 已发现上述烯基化甲苯二胺非常适合作为抗氧化剂和三官能和四官能链延伸剂，用于形成聚氨酯/尿素弹性体体系，并为后固化和聚合提供悬垂不饱和度。
• Alkylation of aromatic amines in the presence of acidic, crystalline molecular sieves
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0226781A1

  公开（公告）日：1987-07-01

  This invention relates to a process for producing ring alkylated aromatic amines. In the process an aromatic amine is reacted with an olefin using an acidic crystalline molecular sieve as a catalyst. Under the conditions of the process the catalyst is extremely active and with amines that are capable of alkylation at the ortho and para positions, high selectivity to the ortho alkylated isomer can be achieved.

  本发明涉及一种生产环状烷基化芳香胺的工艺。 在该工艺中，使用酸性结晶分子筛作为催化剂，使芳香胺与烯烃发生反应。 在该工艺的条件下，催化剂极为活跃，对于能够在正位和对位发生烷基化反应的胺，可以实现对正位烷基化异构体的高选择性。
• Diamino-beta-alkylstyrenes for use in preparing polyurethane/urea systems
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0272650A1

  公开（公告）日：1988-06-29

  This invention relates to a class of alkenylated toluenediamines and phenylenediamines having at least one alkenyl group ortho to an amine group. More particularly the aryldiamines are represented by the formula: wherein R is hydrogen or C₁-C₃ aliphatic, R₁ is hydrogen, R₂ is C₂-C₄, and R₁ and R₂ form an alkylene radical (CH₂)y wherein y=3 or 4, and x is one or two. The above described alkenylated aryldiamine, hereafter referred to as diamino-β-alkyl styrenes, have been found to be well suited as antioxidants and as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少有一个烯基与一个胺基正交的烯化甲苯二胺和苯二胺。更具体地说，芳基二胺由式表示： 其中 R 是氢或 C₁-C₃ 脂肪族，R₁ 是氢，R₂ 是 C₂-C₄，R₁ 和 R₂ 形成亚烷基 (CH₂)y 其中 y=3 或 4，x 是 1 或 2。 已发现上述烯基芳基二胺（以下称为二氨基-β-烷基苯乙烯）非常适合用作抗氧化剂和三官能和四官能链延伸剂，以形成聚氨酯/尿素弹性体体系，并为后固化和聚合提供悬垂不饱和度。