5,6-di(n-heptyl)benzo[2,1-b:3,4-b']bis[1]benzothiophene | 1181678-12-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 5,6-di(n-heptyl)benzo[2,1-b:3,4-b']bis[1]benzothiophene
• 英文别名: 11,12-Diheptyl-3,20-dithiapentacyclo[11.7.0.02,10.04,9.014,19]icosa-1(13),2(10),4,6,8,11,14,16,18-nonaene
• CAS: 1181678-12-5
• 化学式: C₃₂H₃₈S₂
• 分子量: 486.786
• InChiKey: MONIBPFYTRXGPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.6
• 重原子数：
  34
• 可旋转键数：
  12
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  8-十六炔 、 3,3'-diiodo-2,2'-bibenzo[b]thiophene 在 palladium diacetate N-甲基二环己基胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.5h， 以87%的产率得到5,6-di(n-heptyl)benzo[2,1-b:3,4-b']bis[1]benzothiophene
  参考文献：
  名称：

  EP2251342

  摘要：

  公开号：

文献信息

• FUSED RING COMPOUND, METHOD FOR PRODUCING THE SAME, POLYMER, ORGANIC THIN FILM CONTAINING THE COMPOUND AND/OR THE POLYMER, AND ORGANIC THIN FILM DEVICE AND ORGANIC THIN FILM TRANSISTOR EACH COMPRISING THE ORGANIC THIN FILM
  申请人：Osaka University

  公开号：EP2251342A1

  公开（公告）日：2010-11-17

  An object of the present invention is to provide a fused ring compound which can show sufficient charge transport properties and also has excellent solubility in a solvent. The fused ring compound of the present invention is represented by the following formula (1): wherein R11 and R12 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group having 3 or more carbon atoms in the alkyl moiety thereof, an aryl group which may have a substituent, a monovalent heterocyclic group which may have a substituent, or a cyano group, wherein at least one of R11 and R12 is not a hydrogen atom; R13 and R14 each independently represent a monovalent group and m and n are an integer of 0 to 2; Y11, Y12, Y13 and Y14 are a predetermined divalent group containing S, O, N, Se, Te or a double bond; Y11 and Y12 are selected so that a ring containing the groups forms a five-membered ring; and Y13 and Y14 are selected so that a ring containing the groups forms a five or six-membered ring.

  本发明的目的是提供一种融合环化合物，它能显示出足够的电荷传输特性，并且在溶剂中具有极佳的溶解性。本发明的熔环化合物由下式（1）表示： 其中 R11 和 R12 各自独立地代表氢原子、烷基、烷氧基、烷硫基、烷氨基、在其烷基中具有 3 个或更多碳原子的烷氧羰基、可具有取代基的芳基、可具有取代基的单价杂环基团或氰基，其中 R11 和 R12 中至少有一个不是氢原子；R13和R14各自独立地代表一个一价基团，m和n是0至2的整数；Y11、Y12、Y13和Y14是含有S、O、N、Se、Te或双键的预定二价基团；Y11和Y12的选择使含有这些基团的环形成一个五元环；Y13和Y14的选择使含有这些基团的环形成一个五元或六元环。
• FUSED RING COMPOUND, METHOD FOR PRODUCING THE SAME, POLYMER, ORGANIC THIN FILM CONTAINING THE COMPOUND AND/OR POLYMER, AND ORGANIC THIN FILM DEVICE AND ORGANIC THIN FILM TRANSISTOR EACH COMPRISING THE ORGANIC THIN FILM
  申请人：Miura Masahiro

  公开号：US20110065895A1

  公开（公告）日：2011-03-17

  An object of the present invention is to provide a fused ring compound which can show sufficient charge transport properties and also has excellent solubility in a solvent. The fused ring compound of the present invention is represented by the following formula (1): wherein R 11 and R 12 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group having 3 or more carbon atoms in the alkyl moiety thereof, an aryl group which may have a substituent, a monovalent heterocyclic group which may have a substituent, or a cyano group, wherein at least one of R 11 and R 12 is not a hydrogen atom; R 13 and R 14 each independently represent a monovalent group and m and n are an integer of 0 to 2; Y 11 , Y 12 , Y 13 and Y 14 are a predetermined divalent group containing S, O, N, Se, Te or a double bond; Y 11 and Y 12 are selected so that a ring containing the groups forms a five-membered ring; and Y 13 and Y 14 are selected so that a ring containing the groups forms a five or six-membered ring.
• US8344095B2
  申请人：——

  公开号：US8344095B2

  公开（公告）日：2013-01-01
• EP2251342
  申请人：——

  公开号：——

  公开（公告）日：——