m,m'-selenodiphenol | 98040-20-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: m,m'-selenodiphenol
• 英文别名: 3,3'-selanediyl-di-phenol；Bis-(3-hydroxy-phenyl)-selenid；3,3'-Selandiyl-di-phenol；b-Hydroxyphenylselenide；3-(3-hydroxyphenyl)selanylphenol
• CAS: 98040-20-1
• 化学式: C₁₂H₁₀O₂Se
• 分子量: 265.17
• InChiKey: KRFAZLFROCIQAY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.75
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-磺基苯甲酸酐 、 m,m'-selenodiphenol 在 对甲苯磺酸 作用下， 反应 2.5h， 以31.9%的产率得到o-(6-hydroxy-3-oxo-3H-selenoxanthen-9-yl)benzenesulphonic acid
  参考文献：
  名称：

  Novel photosensitizers for the E/Z-isomerization of trienes. Part 1. Syntheses and application

  摘要：

  Uranine and its thioxanthene and selenoxanthene analogues, as well as the disodium salts of o-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzenesulphonic acid and its thioxanthene and selenoxanthene analogues, show different photosensitizer properties in the E/Z-isomerization of trienes. This has been verified by applying them to the technically useful conversion of tachysterol into previtamin D. The syntheses of the novel photosensitizers with thioxanthene and selenoxanthene moieties are also described.

  DOI：

  10.1039/p29910000523
• 作为产物：
  描述：

  bis(3-methoxyphenyl)selane 在 氢碘酸 、 溶剂黄146 作用下， 生成 m,m'-selenodiphenol
  参考文献：
  名称：

  Novel photosensitizers for the E/Z-isomerization of trienes. Part 1. Syntheses and application

  摘要：

  Uranine and its thioxanthene and selenoxanthene analogues, as well as the disodium salts of o-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzenesulphonic acid and its thioxanthene and selenoxanthene analogues, show different photosensitizer properties in the E/Z-isomerization of trienes. This has been verified by applying them to the technically useful conversion of tachysterol into previtamin D. The syntheses of the novel photosensitizers with thioxanthene and selenoxanthene moieties are also described.

  DOI：

  10.1039/p29910000523

文献信息

• Keimatsu; Yokota; Satoda, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1933, vol. 53, p. 993,1029; dtsch. Ref. S. 203, 206
  作者：Keimatsu、Yokota、Satoda

  DOI：——

  日期：——
• PFOERTNER, KARL-HEINZ, J. CHEM. SOC. PERKIN TRANS. PT 2,(1991) N, C. 523-526
  作者：PFOERTNER, KARL-HEINZ

  DOI：——

  日期：——
• Novel photosensitizers for the E/Z-isomerization of trienes. Part 1. Syntheses and application
  作者：Karl-Heinz Pfoertner

  DOI：10.1039/p29910000523

  日期：——

  Uranine and its thioxanthene and selenoxanthene analogues, as well as the disodium salts of o-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzenesulphonic acid and its thioxanthene and selenoxanthene analogues, show different photosensitizer properties in the E/Z-isomerization of trienes. This has been verified by applying them to the technically useful conversion of tachysterol into previtamin D. The syntheses of the novel photosensitizers with thioxanthene and selenoxanthene moieties are also described.