1,1'-diallyl-4,4'-dihydroxy-1H,1H'-[3,3']biquinolinyl-2,2'-dione | 1150542-16-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1,1'-diallyl-4,4'-dihydroxy-1H,1H'-[3,3']biquinolinyl-2,2'-dione
• 英文别名: 1,1'-Diallyl-4,4'-dihydroxy-1h,1' h-[3,3']biquinolinyl-2,2'-dione；4-hydroxy-3-(4-hydroxy-2-oxo-1-prop-2-enylquinolin-3-yl)-1-prop-2-enylquinolin-2-one
• CAS: 1150542-16-7
• 化学式: C₂₄H₂₀N₂O₄
• 分子量: 400.434
• InChiKey: KVIRSXVCJFHKIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  81.1
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  methyl 2-(N-allyl-4-methoxy-4-oxobutanamido)benzoate 在 sodium 作用下， 以 甲苯 为溶剂， 以0.84 mg的产率得到1,1'-diallyl-4,4'-dihydroxy-1H,1H'-[3,3']biquinolinyl-2,2'-dione
  参考文献：
  名称：

  4-羟基-2-喹诺酮类化合物146. 1,1'-二烯丙基-4,4'-二羟基-1H，1'H- [3,3'] biquinolinyl-2,2'-二酮的合成和结构

  摘要：

  The methyl ester of N-allyl-2-methoxycarbonylsuccinanilic acid is partially converted to 1,1'-diallyl-4,4'-dihydroxy-1H,1'H-[3,3']biquinolinyl-2,2'-dione in refluxing toluene in the presence of metallic sodium. A possible mechanism for the occurrence of these chemical processes is discussed.

  DOI：

  10.1007/s10593-008-0116-3

文献信息

• 4-Hydroxy-2-quinolones 146. Synthesis and structure of 1,1′-diallyl-4,4′-dihydroxy-1H,1′ H-[3,3′]biquinolinyl-2,2′-dione
  作者：I. V. Ukrainets、A. A. Tkach、S. V. Shishkina

  DOI：10.1007/s10593-008-0116-3

  日期：2008.7

  The methyl ester of N-allyl-2-methoxycarbonylsuccinanilic acid is partially converted to 1,1'-diallyl-4,4'-dihydroxy-1H,1'H-[3,3']biquinolinyl-2,2'-dione in refluxing toluene in the presence of metallic sodium. A possible mechanism for the occurrence of these chemical processes is discussed.