N1-(4-bromophenyl)-N4,N4-diphenylbenzene-1,4-diamine | 1307229-93-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N1-(4-bromophenyl)-N4,N4-diphenylbenzene-1,4-diamine
• 英文别名: 1-N-(4-bromophenyl)-4-N,4-N-diphenylbenzene-1,4-diamine
• CAS: 1307229-93-1
• 化学式: C₂₄H₁₉BrN₂
• 分子量: 415.332
• InChiKey: INYRSYWRFXICHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  15.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-氨基三苯胺 、 对溴碘苯 在 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 以 邻二氯苯 为溶剂， 反应 3.5h， 以23.4%的产率得到N1-(4-bromophenyl)-N4,N4-diphenylbenzene-1,4-diamine
  参考文献：
  名称：

  Redox Potential Inversion by Ionic Hydrogen Bonding between Phenylenediamines and Pyridines

  摘要：

  In electrochemical oxidations, the second oxidation potential of phenylenediamines (PD) varies because of hydrogen-bonding formation for PD+center dot with pyridines. A linear relationship was obtained for the potential shift as a function of pK(a) of the protonated pyridines and potential inversion could be observed. The oxidized PD+center dot could also form hydrogen bonding with alcohols and the shift of potential exhibits a different pattern.

  DOI：

  10.1021/ol2007764

文献信息

• Polymer compound and polymer light-emitting device using the same
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20030165713A1

  公开（公告）日：2003-09-04

  A polymer compound comprising a repeating unit represented by formula (1) and a repeating unit represented by formula (2), 1 —Ar 6 —  (2) wherein, Ar 1 , Ar 2 and Ar 6 each independently represent an arylene group, a divalent heterocyclic compound group, etc.; Ar 3 is an arylene group, arylene vinylene group, or a divalent heterocyclic compound group; Ar 4 and Ar 5 are each independently an aryl group or a monovalent heterocyclic compound group. The polymer compound has excellent characteristics of strong fluorescence and large charge transporting property.

  一种聚合物化合物，由式（1）代表的重复单元和式（2）代表的重复单元组成、 1 -Ar 6 - (2) 其中，Ar 1 、Ar 2 和 Ar 6 各自独立地代表芳烯基团、二价杂环化合物基团等；Ar 3 是芳烯基团、芳基乙烯基团或二价杂环化合物基团；Ar 4 和 Ar 5 各自独立地为芳基或单价杂环化合物基团。该聚合物化合物具有强荧光和大电荷传输性能的优良特性。
• Redox Potential Inversion by Ionic Hydrogen Bonding between Phenylenediamines and Pyridines
  作者：Yi-Chun Chung、Yi-Jung Tu、Shih-Hua Lu、Wan-Chi Hsu、Kuo Yuan Chiu、Yuhlong Oliver Su

  DOI：10.1021/ol2007764

  日期：2011.6.3

  In electrochemical oxidations, the second oxidation potential of phenylenediamines (PD) varies because of hydrogen-bonding formation for PD+center dot with pyridines. A linear relationship was obtained for the potential shift as a function of pK(a) of the protonated pyridines and potential inversion could be observed. The oxidized PD+center dot could also form hydrogen bonding with alcohols and the shift of potential exhibits a different pattern.