2-Methyl-4'-ethyldiphenylmethan | 17241-79-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Methyl-4'-ethyldiphenylmethan
• 英文别名: 1-Ethyl-4-[(2-methylphenyl)methyl]benzene
• CAS: 17241-79-1
• 化学式: C₁₆H₁₈
• 分子量: 210.319
• InChiKey: NOYSYTDYBTVOSE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-(4-乙基苯基)-3-苯基丙烷-2-酮 在 Sodium tetraborate decahydrate 、 硼酸三钠 作用下， 以 水 为溶剂， 反应 0.5h， 生成 2-(4-ethylphenyl)-1-p-tolylethanone 、 1-ethyl-4-(4-methylbenzyl)benzene 、 1-乙基-4-(2-苯基乙基)苯 、 2-Methyl-4'-ethyldiphenylmethan
  参考文献：
  名称：

  Making a Difference on Excited-State Chemistry by Controlling Free Space within a Nanocapsule:  Photochemistry of 1-(4-Alkylphenyl)-3-phenylpropan-2-ones

  摘要：

  The free space within a reaction cavity plays a determining role during the excited-state reaction of 1-(4-alkylphenyl)-3-phenylpropan-2-ones included within a capsule formed by two molecules of a deep cavity cavitand. By controlling the free space within the reaction cavity through remote alkyl substitution on the reactant ketone it is possible to control the yield of the rearrangement product shown above.

  DOI：

  10.1021/ol0713990

文献信息

• Making a Difference on Excited-State Chemistry by Controlling Free Space within a Nanocapsule:  Photochemistry of 1-(4-Alkylphenyl)-3-phenylpropan-2-ones
  作者：Arun Kumar Sundaresan、V. Ramamurthy

  DOI：10.1021/ol0713990

  日期：2007.8.1

  The free space within a reaction cavity plays a determining role during the excited-state reaction of 1-(4-alkylphenyl)-3-phenylpropan-2-ones included within a capsule formed by two molecules of a deep cavity cavitand. By controlling the free space within the reaction cavity through remote alkyl substitution on the reactant ketone it is possible to control the yield of the rearrangement product shown above.