苯乙烯基氨基甲酸乙酯 | 107479-82-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯乙烯基氨基甲酸乙酯
• 英文名称: styrylcarbamic acid ethyl ester
• 英文别名: (E)-ethyl styrylcarbamate；styryl-carbamic acid ethyl ester；Styryl-carbamidsaeure-aethylester；(β-Phenyl-aethyliden)-carbamidsaeure-aethylester；ethyl 2-phenylvinylcarbamate；ethyl N-[(E)-2-phenylethenyl]carbamate
• CAS: 107479-82-3
• 化学式: C₁₁H₁₃NO₂
• 分子量: 191.23
• InChiKey: LRKSWHHOAKLHRX-CMDGGOBGSA-N

物化性质

• 熔点：
  70 °C
• 沸点：
  294.5±23.0 °C(Predicted)
• 密度：
  1.088±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  苯乙烯基氨基甲酸乙酯 在 三乙基硅烷 作用下， 以 三氟乙酸 为溶剂， 反应 0.5h， 以92%的产率得到n-苯乙基氨基甲酸乙酯
  参考文献：
  名称：

  Regioselective cationic reduction of 2-aryl-1-N-(ethoxycarbonyl)enamines to 2-arylethylamine carbamates

  摘要：

  2-Aryl-1-N-carboalkoxyenamines (enamides) are selectively reduced to the corresponding 2-arylethylamine carbamates by Et3SiH in the presence of CF3COOH in excellent yields. The reduction proceeds by addition of hydride at C-1 and the rate-limiting step involves proton transfer from CF3COOH. This reduction is useful for preparation of isotopically labeled arylethylamines. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)01780-4
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 作用下， 生成 苯乙烯基氨基甲酸乙酯
  参考文献：
  名称：

  Thiele; Pickard, Justus Liebigs Annalen der Chemie, 1899, vol. 309, p. 193

  摘要：

  DOI：

文献信息

• An efficient one-pot synthesis of N,N′-disubstituted ureas and carbamates from N-acylbenzotriazoles
  作者：Anoop S. Singh、Dhananjay Kumar、Nidhi Mishra、Vinod K. Tiwari

  DOI：10.1039/c6ra14131e

  日期：——

  A facile and high-yielding one-pot synthesis of carbamates and N,N'-disubstituted symmetrical ureas from N-acylbenzotriazoles has been devised. It is believed that, the intermediate acyl-azide undergo Curtius rearrangement and under different...

  已经设计了由N-酰基苯并三唑容易且高产率的一锅合成氨基甲酸酯和N，N′-二取代的对称脲。据信，中间的酰基叠氮化物经历了Curtius重排并且在不同的条件下...
• Preparation and Allylation of Enamides and Enecarbamates Generated via Iron(0) Reduction of Oximes and Derivatives
  作者：Steven Weinreb、Cuixiang Sun

  DOI：10.1055/s-2006-942513

  日期：2006.11

  Reductive acylation of oximes and oxime carbonates can be effected with iron powder in the presence of an acid chloride or a chloroformate to produce enamides or enecarbamates.

  用铁粉在酸氯化物或氯甲酸酯存在下进行亚胺和亚胺碳酸酯的还原酰化，可生产出烯酰胺或烯碳酸酯。
• Process for the synthesis of isocyanates and of isocyanate derivatives
  申请人：Societe Nationale des Poudres et Explosifs

  公开号：US04709087A1

  公开（公告）日：1987-11-24

  The present invention relates to a process for the synthesis of isocyanates and of isocyanate derivatives. Isocyanates are obtained by reacting an organic halide with a metal cyanate in an organic medium in the presence of a catalyst consisting of a complex of nickel with at least one organic ligand, in which complex the nickel is in the zero oxidation state. A carbamate or a urea, respectively, are obtained by a subsequent reaction with a hydroxy compound or a primary or secondary amine. Isocyanates and their derivatives are used especially either as refined synthesis agents for the production of pesticides and medications, or as monomers or comonomers for the preparation of many macromolecular compounds.

  本发明涉及一种合成异氰酸酯和异氰酸酯衍生物的方法。通过在有机媒介物中，在至少一个有机配体的镍配合物催化剂的存在下，将有机卤化物与金属氰酸盐反应，可以获得异氰酸酯。随后，通过与羟基化合物或一次或二次胺的反应，可以获得碳酸酯或脲。异氰酸酯及其衍生物特别用于作为精制合成剂用于制造杀虫剂和药物，或者用作制备许多大分子化合物的单体或共聚单体。
• Radical polymerizable unsaturated resin compound and method of manufacture of a block copolymer used therein
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0418913A2

  公开（公告）日：1991-03-27

  The invention relates to a radical polymerizable unsaturated resin compound applied to a molded material which can provide a molded product with superior surface smoothness without shrinkage at the time of curing by means of a block copolymer, and a method of manufacture of a block copolymer which is used as a block copolymer curing low-profile additive for this. The radical polymerizable unsaturated resin compound of the invention can be used to advantage in SMC and BMC using unsaturated polyester resin and can provide a molded product with superior surface smoothness, paintability, physical strength, and pigmentability.

  本发明涉及一种应用于模塑材料的可自由基聚合的不饱和树脂化合物，该化合物通过嵌段共聚物固化时可提供表面光滑度优异且无收缩的模塑产品，还涉及一种用作嵌段共聚物固化低调添加剂的嵌段共聚物的制造方法。本发明的可自由基聚合的不饱和树脂化合物可在使用不饱和聚酯树脂的 SMC 和 BMC 中发挥优势，并可提供表面光滑度、可涂覆性、物理强度和可着色性优异的模塑产品。
• N,O-Bis-(ethoxycarbonyl)hydroxylamine: a convenient reagent for the Lossen transformation
  作者：R Anilkumar、Sosale Chandrasekhar、Malayalam Sridhar

  DOI：10.1016/s0040-4039(00)00808-x

  日期：2000.7

  The titled compound effects the Lessen rearrangement on aromatic carboxylic acids, via activation by DCC or formation of the acid chlorides, to furnish the corresponding amines in excellent yields, in an essentially 'one-pot' procedure. (C) 2000 Elsevier Science Ltd. All rights reserved.