arsane;zirconium

• 分子结构分类: 无机化合物 - 各种无机化合物 - 无机砷化合物
• 英文名称: arsane;zirconium
• 化学式: AsZr
• 分子量: 166.146
• InChiKey: WMPJIYURWKMQIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.19
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  arsane;zirconium 、 钴 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Kleinke; Franzen, Zeitschrift für anorganische und allgemeine Chemie, 1998, vol. 624, # 1, p. 51 - 56

  摘要：

  DOI：
• 作为产物：
  描述：

  砷化氢 、 锆 以 neat (no solvent, solid phase) 为溶剂， 生成 arsane;zirconium
  参考文献：
  名称：

  Willerstoem, J.-O., Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 1984, vol. 38, p. 91 - 94

  摘要：

  DOI：

文献信息

• New Layered Zirconium Tellurides:  Zr_0.30ZrTe₂, Zr_0.29Zr₂Te₂As, and NaZr₂Te₂As
  作者：Chwanchin Wang、Cahit Eylem、Timothy Hughbanks

  DOI：10.1021/ic9709077

  日期：1998.2.1

  synthesis and crystal structure determinations of Zr(0.30)ZrTe(2) and M(x)Zr(2)Te(2)As (M = Zr, Na) compounds are reported. The structure of Zr(0.30)ZrTe(2) was refined in the hexagonal space group P6(3)mc (No. 186, Z = 2) with lattice parameters a = 3.9840(3) Å and c = 13.366(3) Å; Zr(0.29)Zr(2)Te(2)As was refined in the rhombohedral space group R&thremacr;m (No. 166, Z = 3) with lattice parameters

  报告了Zr（0.30）ZrTe（2）和M（x）Zr（2）Te（2）As（M = Zr，Na）化合物的合成和晶体结构测定。Zr（0.30）ZrTe（2）的结构在六边形空间群P6（3）mc（No. 186，Z = 2）中得到了改进，其晶格参数为a = 3.9840（3）Å和c = 13.366（3）Å ; Zr（0.29）Zr（2）Te（2）As在菱面体空间群R＆thremacr; m（No. 166，Z = 3）中进行了精炼，晶格参数a = 3.9329（4）Å和c = 29.564（5）Å 。Zr（0.30）ZrTe（2）和Zr（0.29）Zr（2）Te（2）As分别与Zr（2）Se（3）和Ta（2）S（2）C具有紧密的结构相似性，且分别为通过堆叠具有[Zr（0.30）-Te-Zr-Te]和[Zr（0.29）-Te-Zr-As-Zr-Te]序列的六边形层来构建。四探针电阻率测量（77-300
• The lead-zirconium system: binary phases and a series of interstitial compounds of the host Zr5Pb3
  作者：Young-Uk Kwon、John D. Corbett

  DOI：10.1016/0925-8388(93)90402-9

  日期：1993.1

  The Pb-Zr system contains the phases Zr(approximately 5.8)Pb (Cr3Si-type), Zr5Pb3 (Mn5Si3) and Zr5Pb4 (Ti5Ga4). Zr5Pb4 as a substoichiometric region above approximately 800-degrees-C, extending to about Zr5Pb3.65 at 1000-degrees-C. Reactive powder sintering in sealed Ta containers at 1000-1350-degrees-C is the most effective route for the synthesis of pure phases of both the binaries and the interstitial derivatives Zr5Pb3Z. Twenty examples of the latter were obtained with Z = Al, Si, P, S, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Ag, Cd, In, Sn, Sb, Te, (Pb), (second period Z were not investigated). Single crystals for Z = Al, Cd, Zn, Pb0.87, Pb0.94 were obtained by metal flux or vapor phase transport reactions, and the last three were quantified by X-ray crystallography. Volume trends as a function of group and period follow metal/covalent radii trends for Z fairly well.
• Crystal structure predictions: the crystal and electronic structure of Zr1−δV1+δAs
  作者：Enkhtsetseg Dashjav、Chi-Shen Lee、Holger Kleinke

  DOI：10.1016/s0022-4596(02)00030-0

  日期：2002.11

  Zr1 - deltaV1 + deltaAs is accessible via arc-melting of different mixtures of ZrAs, VAs, Zr, and V. It crystallizes in the tetragonal La2Sb type, with a phase range of -0.43(4) less than or equal to delta less than or equal to 0.15(1). The lattice dimensions (a = 382.4(1) pm, c = 1486.8(6) pm for Zr1.43(4)V0.57As; and a = 375.77(7) pm, c = 1400.2(3) pm for Zr0.85(1)V1.15As) strongly depend on delta because of the different sizes of the Zr and V atoms. The ZrVAs structure comprises sheets of (empty) M-6 octahedra, whose triangular faces are capped by the main group atoms Q. The sheets are interconnected via M-Q bonds to a truly three-dimensional structure. Like in the isostructural ZrTiAs, the smaller 3d M atom prefers the site in the densely packed square planes. In addition to the dominating M-As bonds, the structure comprises strong M-M bonding. Independent of the exact Zr:V ratio, Zr1 - deltaV1 + deltaAs is calculated to have three-dimensional metallic properties. (C) 2002 Elsevier Science (USA). All rights reserved.
• Kleinke Holger, Journal of Alloys and Compounds, <hi>1997</hi>, vol. 252, p. L29 - L31
  作者：Kleinke Holger

  DOI：——

  日期：——
• Kleinke; Franzen, Zeitschrift für anorganische und allgemeine Chemie, 1998, vol. 624, # 1, p. 51 - 56
  作者：Kleinke、Franzen

  DOI：——

  日期：——