bis(furan-2-yl)methyl terephthalate | 26347-56-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(furan-2-yl)methyl terephthalate
• 英文别名: terephthalic acid difurfuryl ester；1,4-Benzenedicarboxylic acid, bis(2-furanylmethyl) ester；bis(furan-2-ylmethyl) benzene-1,4-dicarboxylate
• CAS: 26347-56-8
• 化学式: C₁₈H₁₄O₆
• 分子量: 326.306
• InChiKey: CTVDHUAIUAABFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  78.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  bis(furan-2-yl)methyl terephthalate 以67%的产率得到
  参考文献：
  名称：

  BERLIN A. A.; LIOGONKIJ B. I.; ZAPADINSKIJ B. I.; KAZANTSEVA E. A.; STANK+, IZV. AN CCCP. CEP. XIM., 1977, HO 4, 867-874

  摘要：

  DOI：
• 作为产物：
  描述：

  糠醇 以90%的产率得到
  参考文献：
  名称：

  IVANOV A. A.; PRIMELLES E.; DELGADO R., CENTRO. REV. CIENT. UNIV. CENT. LAS. VILLAS, 1975, 3, NO 1, 19-30,

  摘要：

  DOI：

文献信息

• Synthesis and in situ core reorganization of smart polymers
  作者：Xiubo Jiang、Wen Zhu、Yechao Yan、Yongming Chen、Fu Xi

  DOI：10.1016/j.reactfunctpolym.2011.04.009

  日期：2011.8

  A smart poly(ethylene oxide) polymer containing two thermally reversible groups located at the chain center (F2-PEO) was synthesized by a maleimide-furan (MF) [4 + 2] Diels-Alder (DA) reaction between one bis[(furan-2-yl)methyl] terephthalate (F2) and two maleimide-terminated poly(ethylene glycol) methyl ethers (MI-PEOs). MF adducts underwent retro-DA (rDA) addition at a higher temperature, and the maleimide-anthracene (MA) addition reaction could occur simultaneously. Therefore, when F2-PEO and bis((anthracen-10-yl)methyl) succinate (AN2) were refluxed in toluene for 48 h, the cores of F2-PEOs were replaced with the MA adducts in situ to give new polymers AN2-PEOs. Moreover, when F2-PEOs were mixed with the molecules containing four anthracene units (AN4), the rDA reaction of the MF adducts and the MA addition reactions occurred simultaneously, generating four-arm star PEOs. The core reorganization of polymers has been confirmed by SEC, UV, H-1 NMR, and MALDI-TOF mass spectra. (C) 2011 Elsevier Ltd. All rights reserved.
• IVANOV A. A.; PRIMELLES E.; DELGADO R., CENTRO. REV. CIENT. UNIV. CENT. LAS. VILLAS, 1975, 3, NO 1, 19-30,
  作者：IVANOV A. A.、 PRIMELLES E.、 DELGADO R.

  DOI：——

  日期：——
• BERLIN A. A.; LIOGONKIJ B. I.; ZAPADINSKIJ B. I.; KAZANTSEVA E. A.; STANK+, IZV. AN CCCP. CEP. XIM., 1977, HO 4, 867-874
  作者：BERLIN A. A.、 LIOGONKIJ B. I.、 ZAPADINSKIJ B. I.、 KAZANTSEVA E. A.、 STANK+

  DOI：——

  日期：——