Diphenyl-(3-trimethylsilanyl-propyl)-phosphane | 69858-27-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Diphenyl-(3-trimethylsilanyl-propyl)-phosphane
• 英文别名: Diphenyl[3-(trimethylsilyl)propyl]phosphane；diphenyl(3-trimethylsilylpropyl)phosphane
• CAS: 69858-27-1
• 化学式: C₁₈H₂₅PSi
• 分子量: 300.456
• InChiKey: XZYKUQHNUMYJNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.85
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Diphenyl-(3-trimethylsilanyl-propyl)-phosphane 、 氢化铝锂 以90%的产率得到
  参考文献：
  名称：

  HOLMES-SMITH, R. D.;OSEI, R. D.;STOBART, S. R., J. CHEM. SOC. PERKIN TRANS., 1983, N 4, 861-866

  摘要：

  DOI：
• 作为产物：
  描述：

  (3-氯丙基)三甲基硅烷 、 二苯基氯化膦 生成 Diphenyl-(3-trimethylsilanyl-propyl)-phosphane
  参考文献：
  名称：

  Capka,M. et al., Collection of Czechoslovak Chemical Communications, 1978, vol. 43, p. 3347 - 3355

  摘要：

  DOI：

文献信息

• Transition metal complex catalysts
  申请人：Exxon Research and Engineering

  公开号：US04668809A1

  公开（公告）日：1987-05-26

  Compositions of matter are disclosed which are highly useful in hydroformylation processes. The compositions are non-charged, non-chelated bis- and tris-(alkyl diaryl phosphine) rhodium carbonyl hydrides. The substituents of the alkyl group includes heteroorganic radicals containing ether, ester, keto and hydroxy oxygen, phosphine oxide and phosphorus ester phosphorus, amine, amide, amine oxide and heterocyclic nitrogen groups. These compositions are highly stable and selective catalysts for the hydroformylation of olefins under certain conditions. The disclosed catalyst systems contain a large excess of phosphine ligand and employ alpha-olefin plus synthesis gas reactant mixtures having a high H.sub.2 /CO ratio at relatively low pressures. They produce moslty aldehydes derived from terminal attack on the alpha-olefin reactant. In the case of low olefins, such as butene-1, the products can be advantageously removed in a continuous manner, as distillate components from a ligand reaction mixture kept at an elevated temperature and continuously fed by an appropriate mixture of the reactants.

  本发明披露了一种在氢甲酰化过程中非常有用的物质组成物。该组成物是非带电、非螯合的双(烷基二芳基膦)、三(烷基二芳基膦)铑羰基氢化物。烷基基团的取代基包括含有醚、酯、酮和羟基氧、膦氧和磷酸酯磷、胺、酰胺、胺氧和杂环氮基的杂有机基团。这些组成物是高度稳定和选择性的催化剂，可在一定条件下用于烯烃的氢甲酰化反应。披露的催化剂体系含有大量的膦配体，并采用具有高H.sub.2/CO比的α-烯烃加合物和合成气反应物混合物，在相对较低的压力下。它们主要产生从α-烯烃反应物的末端攻击中得到的醛。对于低烯烃，例如丁烯-1，可以从保持在高温下并由适当的反应物混合物连续供给的配体反应混合物中以馏分组分的形式优势地去除产物。
• Ligand exchange process for producing alkyl diaryl phosphine rhodium
  申请人：Exxon Research and Engineering Company

  公开号：US04687866A1

  公开（公告）日：1987-08-18

  Compositions of matter are disclosed which are highly useful in hydroformylation processes. The compositions are non-charged, non-chelated bis- and tris-(alkyl diaryl phosphine) rhodium carbonyl hydrides. The substituents of the alkyl group include heteroorganic radicals containing silane, silicone, ether, ester, keto and hydroxy oxygen, phosphine oxide and phosphorus ester phosphorus, amine, amide, amine oxide and heterocyclic nitrogen groups. These compositions are highly stable and selective catalysts for the hydroformylation of olefins under certain conditions. The disclosed catalyst systems contain a large excess of phosphine ligand and employ alpha-olefin plus synthesis gas reactant mixtures having a high H.sub.2 /CO ratio at relatively low pressures. They produce mostly aldehydes derived from terminal attack on the alpha-olefin reactant. In the case of low olefins, such as butene-1, the products can be advantageously removed in a continuous manner, as distillate components from a ligand reaction mixture kept at an elevated temperature and continuously fed by an appropriate mixture of the reactants.

  披露了在水合甲酰化过程中非常有用的物质组成物。这些组成物是非带电、非螯合的双(烷基二芳基膦)和三(烷基二芳基膦)铑羰基氢化物。烷基基团的取代基包括含有硅烷、硅氧烷、醚、酯、酮和羟基氧、膦氧和磷酸酯磷的杂有机基团、胺、酰胺、胺氧和杂环氮基团。这些组成物是高度稳定和选择性催化剂，在一定条件下用于烯烃的水合甲酰化反应。所披露的催化剂体系含有大量的膦配体，并使用具有高H.sub.2/CO比的α-烯烃和合成气反应物混合物，在相对较低的压力下。它们主要产生由α-烯烃反应物的末端攻击产生的醛。对于低烯烃，例如丁烯-1，可以从保持在高温下并由适当的反应物混合物连续供给的配体反应混合物中优势地连续地去除产物，作为馏分组分。
• Selective hydroformylation process using alkyl diaryl phosphine rhodium
  申请人：Exxon Research and Engineering Company

  公开号：US04687874A1

  公开（公告）日：1987-08-18

  Compositions of matter are disclosed which are highly useful in hydroformylation processes. The compositions are non-charged, non-chelated bis- and tris-(alkyl diaryl phosphine) rhodium carbonyl hydrides. The substituents of the alkyl group include heteroorganic radicals containing ether, ester, keto and hydroxy oxygen, phosphine oxide and phosphorus ester phosphorus, amine, amide, amine oxide and heterocyclic nitrogen groups. These compositions are highly stable and selective catalysts for the hydroformylation of olefins under certain conditions. The disclosed catalyst systems contain a large excess of phosphine ligand and employ alpha-olefin plus synthesis gas reactant mixtures having a high H.sub.2 /CO ratio at relatively low pressures. They produce mostly aldehydes derived from terminal attack on the alpha-olefin reactant. In the case of low olefins, such as butene-1, the products can be advantageously removed in a continuous manner, as distillate components from a ligand reaction mixture kept at an elevated temperature and continuously fed by an appropriate mixture of the reactants.

  本发明揭示了一种在加氢甲酰化过程中非常有用的物质组成物。这些组成物是非带电的、非螯合的双(烷基二芳基膦)和三(烷基二芳基膦)钌羰基氢化物。烷基基团的取代基包括含有醚、酯、酮和羟基氧、膦氧和磷酸酯磷、胺、酰胺、胺氧和杂环氮基的杂有机基团。这些组成物是高度稳定和选择性的催化剂，在特定条件下对烯烃的加氢甲酰化反应非常有效。揭示的催化剂系统包含大量过量的膦配体，并使用具有高H.sub.2/CO比的α-烯烃加合物和合成气反应混合物，在相对较低的压力下进行。它们主要产生从α-烯烃反应物的端部攻击中得到的醛类产物。在低烯烃（如丁烯-1）的情况下，可以从保持在升高温度下并通过适当的反应物混合物连续供给的配体反应混合物中作为馏分组分优势地去除产物。
• Heterocycle-substituted alkyl diaryl phosphine rhodium caronyl hydride
  申请人：Exxon Research and Engineering Co.

  公开号：US04595753A1

  公开（公告）日：1986-06-17

  Compositions of matter are disclosed which are highly useful in hydroformylation processes. The compositions are non-charged, non-chelated bis- and tris-(alkyl diaryl phosphine) rhodium carbonyl hydrides. The substituents of the alkyl group include heteroorganic radicals containing silane, silicone, ether, ester, keto and hydroxy oxygen, phosphine oxide and phosphorus ester phosphorus, amine, amide, amine oxide and heterocyclic nitrogen groups. These compositions are highly stable and selective catalysts for the hydroformylation of olefins under certain conditions. The disclosed catalyst systems contain a large excess of phosphine ligand and employ alpha-olefin plus synthesis gas reactant mixtures having a high H.sub.2 /CO ratio at relatively low pressures. They produce mostly aldehydes derived from terminal attack on the alpha-olefin reactant. In the case of low olefins, such as butene-1, the products can be advantageously removed in a continuous manner, as distillate components from a ligand reaction mixture kept at an elevated temperature and continuously fed by an appropriate mixture of the reactants.

  本发明揭示了在羰基化反应中高度有用的物质组成。这些组成物是非带电、非螯合的双和三(烷基二芳基膦)铑羰基氢化物。烷基基团的取代基包括含有硅烷、硅氧烷、醚、酯、酮和羟基氧、膦氧和磷酸酯磷、胺、酰胺、胺氧和杂环氮基的杂有机基团。这些组成物是高度稳定和选择性的催化剂，可在特定条件下用于烯烃的羰基化反应。揭示的催化剂体系含有大量过量的膦配体，并使用具有高H.sub.2/CO比的α-烯烃加合成气反应混合物，在相对较低的压力下进行。它们主要产生从α-烯烃反应物的末端攻击中得到的醛类产物。对于低烯烃，如丁烯-1，可以从保持在升高温度的配体反应混合物中连续地将产物作为馏分组分有利地除去，并通过适当的反应物混合物连续供给。
• Holmes-Smith, Rupert D.; Osei, Rexford D.; Stobart, Stephen R., Journal of the Chemical Society. Perkin transactions I, 1983, p. 861 - 866
  作者：Holmes-Smith, Rupert D.、Osei, Rexford D.、Stobart, Stephen R.

  DOI：——

  日期：——