{4-[1-(3,3,8,8,10,10-Hexamethyl-1,5-dioxa-9-aza-spiro[5.5]undec-9-yloxy)-ethyl]-phenyl}-phenyl-methanone | 437994-72-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {4-[1-(3,3,8,8,10,10-Hexamethyl-1,5-dioxa-9-aza-spiro[5.5]undec-9-yloxy)-ethyl]-phenyl}-phenyl-methanone
• 英文别名: [4-[1-[(3,3,8,8,10,10-Hexamethyl-1,5-dioxa-9-azaspiro[5.5]undecan-9-yl)oxy]ethyl]phenyl]-phenylmethanone
• CAS: 437994-72-4
• 化学式: C₂₉H₃₉NO₄
• 分子量: 465.633
• InChiKey: KAJHLDUWFLCXSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  34
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  48
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  sodium metabisulfite 、 copper(II)chlorid 、 3,3,8,8,10,10-hexamethyl-1,5-dioxa-9-aza-spiro[5.5]undecan-9-oxyl 、 4-乙基苯甲酮 生成 {4-[1-(3,3,8,8,10,10-Hexamethyl-1,5-dioxa-9-aza-spiro[5.5]undec-9-yloxy)-ethyl]-phenyl}-phenyl-methanone
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
  申请人：——

  公开号：US20040049043A1

  公开（公告）日：2004-03-11

  The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polaylkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

  本发明涉及选择的含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶化合物，形成开链或环状的酮缩结构，一种聚合物组合物，包括a)至少一种乙烯基不饱和单体和b)含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶自由基引发剂化合物。本发明的进一步方面包括聚合乙烯基不饱和单体的方法以及使用含有环氧基或羰基基团的N-烷氧基-4,4-二氧-聚烯烃-哌啶自由基引发剂进行自由基聚合的方法。
• N-alkoxy-4, 4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
  申请人：Fuso Francesco

  公开号：US20070173570A1

  公开（公告）日：2007-07-26

  The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

  本发明涉及选择的含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶化合物，形成开链或环状的环缩酮结构，以及包括a) 至少一种乙烯基不饱和单体和b) 含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶亚硝酰化合物的可聚合组合物。本发明的其他方面包括聚合乙烯基不饱和单体的方法以及使用含有环氧基或酮基的N-烷氧基-4,4-二氧基-聚烷基哌啶亚硝酰化合物进行自由基聚合的方法。
• N-ALKOXY-4,4-DIOXY-POLYALKYL-PIPERIDINE COMPOUNDS, WITH GLYCIDYL OR ALKYLCARBONYL GROUPS AS FUNCTIONAL INITIATORS FOR CONTROLLED RADICAL POLYMERIZATION
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1341763B1

  公开（公告）日：2004-06-16
• US7235663B2
  申请人：——

  公开号：US7235663B2

  公开（公告）日：2007-06-26
• US7868171B2
  申请人：——

  公开号：US7868171B2

  公开（公告）日：2011-01-11