(E)-4-[2-(pyridin-4-yl)vinyl]-1,10-phenanthroline | 1235588-75-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: (E)-4-[2-(pyridin-4-yl)vinyl]-1,10-phenanthroline
• 英文别名: 4-[(E)-2-pyridin-4-ylethenyl]-1,10-phenanthroline
• CAS: 1235588-75-6
• 化学式: C₁₉H₁₃N₃
• 分子量: 283.332
• InChiKey: XKFKCMMQFHNWNZ-ONEGZZNKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-吡啶甲醛 、 4-甲基-1,10-邻二氮杂菲 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.5h， 以46%的产率得到(E)-4-[2-(pyridin-4-yl)vinyl]-1,10-phenanthroline
  参考文献：
  名称：

  Linear vs Exponential Formation of Molecular-Based Assemblies

  摘要：

  Here we present the critical role of the molecular structure and reaction parameters on the nature of thin-film growth, using a versatile two-step assembly method with organic and metal organic chromophores cross-linked with palladium. It was found that the polypyridyl complexes exhibit exponential growth, whereas, under identical conditions, the organic systems exhibit linear behavior. The internal film morphology plays a pivotal role in the storage and usage of the palladium, where a more porous structure results in exponential growth. Interestingly, through proper tuning of the reaction conditions, the growth of the molecular assemblies can be controlled, resulting in a changeover from exponential to linear growth. These findings unequivocally demonstrate the importance of both the internal film structure and deposition conditions on the assembly of molecular-based films.

  DOI：

  10.1021/ja104203v

文献信息

• Linear vs Exponential Formation of Molecular-Based Assemblies
  作者：Joyanta Choudhury、Revital Kaminker、Leila Motiei、Graham de Ruiter、Michael Morozov、Fabio Lupo、Antonino Gulino、Milko E. van der Boom

  DOI：10.1021/ja104203v

  日期：2010.7.14

  Here we present the critical role of the molecular structure and reaction parameters on the nature of thin-film growth, using a versatile two-step assembly method with organic and metal organic chromophores cross-linked with palladium. It was found that the polypyridyl complexes exhibit exponential growth, whereas, under identical conditions, the organic systems exhibit linear behavior. The internal film morphology plays a pivotal role in the storage and usage of the palladium, where a more porous structure results in exponential growth. Interestingly, through proper tuning of the reaction conditions, the growth of the molecular assemblies can be controlled, resulting in a changeover from exponential to linear growth. These findings unequivocally demonstrate the importance of both the internal film structure and deposition conditions on the assembly of molecular-based films.