dimethyl 4-(benzo[d]thiazol-2-yl)phenylboronate | 1145669-96-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: dimethyl 4-(benzo[d]thiazol-2-yl)phenylboronate
• 英文别名: [4-(1,3-Benzothiazol-2-yl)phenyl]-dimethoxyborane；[4-(1,3-benzothiazol-2-yl)phenyl]-dimethoxyborane
• CAS: 1145669-96-0
• 化学式: C₁₅H₁₄BNO₂S
• 分子量: 283.159
• InChiKey: GWHCTEOJXHQCSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.95
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  59.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4,9-二溴萘并[2,3-c][1,2,5]噻二唑 、 dimethyl 4-(benzo[d]thiazol-2-yl)phenylboronate 在 potassium carbonate 、 三苯基膦 、 palladium dichloride 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 8.0h， 以62%的产率得到4,9-bis(4-(benzo[d]thiazol-2-yl)phenyl)naphtho[2,3-c][1,2,5]thiadiazole
  参考文献：
  名称：

  An Ambipolar Transporting Naphtho[2,3-c][1,2,5]thiadiazole Derivative with High Electron and Hole Mobilities

  摘要：

  An ambipolar transporting naphtho[2,3-c][1,2,5]thiadiazole derivative with both high electron and hole mobilities has been synthesized via Suzuki cross-coupling. The electron and hole mobilities are 1.7 x 10(-3) cm(2)/(V.s) and 1.9 x 10(-3) cm(2)/(V.s) at an electric field of 4.5 x 10(5) V/cm, respectively, as measured by using time-of-flight technique.

  DOI：

  10.1021/ol900431a
• 作为产物：
  描述：

  甲醇 、 (4-(benzo[d]thiazol-2-yl)phenyl)boronic acid 以 四氢呋喃 为溶剂， 反应 4.0h， 生成 dimethyl 4-(benzo[d]thiazol-2-yl)phenylboronate
  参考文献：
  名称：

  An Ambipolar Transporting Naphtho[2,3-c][1,2,5]thiadiazole Derivative with High Electron and Hole Mobilities

  摘要：

  An ambipolar transporting naphtho[2,3-c][1,2,5]thiadiazole derivative with both high electron and hole mobilities has been synthesized via Suzuki cross-coupling. The electron and hole mobilities are 1.7 x 10(-3) cm(2)/(V.s) and 1.9 x 10(-3) cm(2)/(V.s) at an electric field of 4.5 x 10(5) V/cm, respectively, as measured by using time-of-flight technique.

  DOI：

  10.1021/ol900431a

文献信息

• An Ambipolar Transporting Naphtho[2,3-<i>c</i>][1,2,5]thiadiazole Derivative with High Electron and Hole Mobilities
  作者：Yongduo Sun、Lian Duan、Peng Wei、Juan Qiao、Guifang Dong、Liduo Wang、Yong Qiu

  DOI：10.1021/ol900431a

  日期：2009.5.21

  An ambipolar transporting naphtho[2,3-c][1,2,5]thiadiazole derivative with both high electron and hole mobilities has been synthesized via Suzuki cross-coupling. The electron and hole mobilities are 1.7 x 10(-3) cm(2)/(V.s) and 1.9 x 10(-3) cm(2)/(V.s) at an electric field of 4.5 x 10(5) V/cm, respectively, as measured by using time-of-flight technique.