5,5-Difluoro-1,3-bis(3-hexylthiophen-2-yl)cyclopenta[c]thiophene-4,6-dione | 1160067-07-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 5,5-Difluoro-1,3-bis(3-hexylthiophen-2-yl)cyclopenta[c]thiophene-4,6-dione
• CAS: 1160067-07-1
• 化学式: C₂₇H₃₀F₂O₂S₃
• 分子量: 520.729
• InChiKey: MSPKWRKOCQFKAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.5
• 重原子数：
  34
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  119
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  5,5-Difluoro-1,3-bis(3-hexylthiophen-2-yl)cyclopenta[c]thiophene-4,6-dione 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以91%的产率得到1,3-Bis(5-bromo-3-hexylthiophen-2-yl)-5,5-difluorocyclopenta[c]thiophene-4,6-dione
  参考文献：
  名称：

  EP2223918

  摘要：

  公开号：
• 作为产物：
  描述：

  1,3-dibromo-5,5-difluoro-4H-cyclopenta[c]thiophene-4,6(5H)-dione 、 2-溴-3-己基噻吩 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以41%的产率得到5,5-Difluoro-1,3-bis(3-hexylthiophen-2-yl)cyclopenta[c]thiophene-4,6-dione
  参考文献：
  名称：

  EP2223918

  摘要：

  公开号：

文献信息

• Nitrogen-containing fused-ring compound, polymer comprising a nitrogen-containing fused-ring repeating unit, organic thin film, and organic thin film element
  申请人：SUMITOMO CHEMICAL CO., LTD.

  公开号：EP2520572A1

  公开（公告）日：2012-11-07

  The present invention provides nitrogen-containing fused-ring compounds represented by the following formula (α-I): in formula (α-I), R21 and R22 each independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Z21 and Z22 each independently represent any one of the groups represented by the following formulas (α-i)-(α-ix); wherein R23, R24, R25 and R26 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and R23 and R24 may bond together to form a ring, the left side and the right side of the group represented by formula (α-viii) may be interchanged.

  本发明提供了由下式（α-I）表示的含氮熔环化合物： 式(α-I)中，R21和R22各自独立地代表氢原子、卤素原子或任选取代的一价基团，Z21和Z22各自独立地代表下式(α-i)-(α-ix)所代表的基团中的任一个； 其中 R23、R24、R25 和 R26 各自独立地代表氢原子、卤素原子或单价基团，且 R23 和 R24 可键合在一起形成环，式 (α-viii) 所代表基团的左侧和右侧可互换。
• CONJUGATED COMPOUND, NITROGENATED CONDENSED-RING COMPOUND, NITROGENATED CONDENSED-RING POLYMER, ORGANIC THIN FILM, AND ORGANIC THIN FILM ELEMENT
  申请人：Aso Yoshio

  公开号：US20100301314A1

  公开（公告）日：2010-12-02

  According to the first invention group there are provided conjugated compounds having two or more groups represented by the following formula (I) or the following formula (II): wherein one of Ar and Ar′ represents a C6 or greater divalent aromatic hydrocarbon group and the other represents a C4 or greater divalent heterocyclic group, wherein the groups each may have a substituent, with the proviso that the groups as a whole contain no fluorine atoms, R 1 and R 2 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and Ar″ represents a trivalent aromatic hydrocarbon or trivalent heterocyclic group; when the conjugated compound has two or more groups represented by formula (I), the portion excluding these groups contain no fluorine atoms. According to the second group of the present invention there are provided nitrogen-containing fused-ring compounds represented by the following formula (α-I): in formula (α-I), R 21 and R 22 each independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Z 21 and Z 22 each independently represent any one of the groups represented by the following formulas (α-i)-(α-ix); wherein R 23 , R 24 , R 25 and R 26 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and R 23 and R 24 may bond together to form a ring, the left side and the right side of the group represented by formula (α-viii) may be interchanged.
• US8378338B2
  申请人：——

  公开号：US8378338B2

  公开（公告）日：2013-02-19
• EP2223918
  申请人：——

  公开号：——

  公开（公告）日：——