N,N-di(4-ethylphenyl)-(1,1'-biphenyl)-4-amine | 131783-28-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-di(4-ethylphenyl)-(1,1'-biphenyl)-4-amine
• 英文别名: N,N-Bis(4-ethylphenyl)[1,1'-biphenyl]-4-amine；4-ethyl-N-(4-ethylphenyl)-N-(4-phenylphenyl)aniline
• CAS: 131783-28-3
• 化学式: C₂₈H₂₇N
• 分子量: 377.529
• InChiKey: HNTJYLLNISIJIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  硝基联苯 在 palladium on activated charcoal copper bronze 、 三(3,6-二氧杂庚基)胺 、 potassium carbonate 、 一水合肼 作用下， 以 乙醇 、 邻二氯苯 为溶剂， 生成 N,N-di(4-ethylphenyl)-(1,1'-biphenyl)-4-amine
  参考文献：
  名称：

  Photoinduced Intramolecular Charge Transfer in Diphenylamino-Substituted Triphenylbenzene, Biphenyl, and Fluorene

  摘要：

  The photophysical properties of a diphenyl amino-substituted triphenylbenzene, (pEFTP), biphenyl (pEFBP), and fluorene (pEFF) derivative are compared. The similarity of the photophysical properties and their solvent dependence for the triphenylbenzene and the biphenyl model compound indicate the formation of a polar excited state, localized in one branch of pEFTP. Further comparison with the fluorene model compound suggests an excited state relaxation process of the biphenyl moiety in solvents of medium and high polarity toward a more planar geometry. The depopulation of the excited state is explained in the framework of the model developed to rationalize the photophysics of substituted biphenyl.

  DOI：

  10.1021/jp970666o

文献信息

• CAPPED STRUCTURE ORGANIC FILM COMPOSITIONS
  申请人：Cöté Adrien P.

  公开号：US20120029236A1

  公开（公告）日：2012-02-02

  A capped structured organic film comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.

  一种带有盖子的结构有机薄膜，包括多个片段和多个链接剂，排列成共价有机框架。其中，这种结构有机薄膜可以是多片段厚度的结构有机薄膜。
• STRUCTURED ORGANIC FILMS
  申请人：HEUFT Matthew A.

  公开号：US20100227998A1

  公开（公告）日：2010-09-09

  A structured organic film comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.

  一种有机结构膜，由多个片段和多个连接剂组成，排列成共价有机框架，其中这种有机结构膜可以是多个片段厚的有机结构膜。
• Organic Mixed-Valence Systems: Electrochemical and Optical Studies of Intervalence Transition in Partly Oxidized Aromatic Polyamines
  作者：Jacques Bonvoisin、Jean-Pierre Launay、Mark Van der Auweraer、Frans Carl De Schryver

  DOI：10.1021/j100070a018

  日期：1994.5

  The aromatic polyamine molecule denoted p-EFTP containing three equivalent tertiary amine groups is studied by electrochemistry and UV-vis-near-IR spectroscopy. Cyclic voltammetry and coulometry show a unique, reversible, oxidation wave corresponding to a three-electron process. Near-IR spectroscopy unambiguously reveals the presence of intervalence transitions in the mixed-valence forms of the molecule under study. A novel analysis allows the extraction of comproportionation constants from the dependence of intervalence absorption bands vs average oxidation state. From the corrected spectra of the mixed-valence forms, it is then possible to evaluate the effective electronic couplings of both mixed-valence forms and to compare this with a theoretical estimation.
• HIGH MOBILITY PERIODIC STRUCTURED ORGANIC FILMS
  申请人：CÔTÉ Adrien P.

  公开号：US20120232308A1

  公开（公告）日：2012-09-13

  An high mobility structured organic film comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.
• PERIODIC STRUCTURED ORGANIC FILMS
  申请人：XEROX CORPORATION

  公开号：US20170022338A1

  公开（公告）日：2017-01-26

  An ordered structured organic film comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.