2,4,6-tris-trifluoromethyl-styrene | 485-01-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-tris-trifluoromethyl-styrene
• 英文别名: 2,4,6-Tris-trifluormethyl-styrol；2,4,6-Tris(trifluoromethyl)styrene；2-ethenyl-1,3,5-tris(trifluoromethyl)benzene
• CAS: 485-01-8
• 化学式: C₁₁H₅F₉
• 分子量: 308.146
• InChiKey: HTRLKEJGRJZZPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  2,4,6-Tris(trifluoromethyl)-α-methylbenzyl alcohol 在 phosphorus pentoxide 、 对苯二酚 、 苯 作用下， 生成 2,4,6-tris-trifluoromethyl-styrene
  参考文献：
  名称：

  2,4,6-Tris-(trifluoromethyl)-styrene¹

  摘要：

  DOI：

  10.1021/ja01168a058

文献信息

• RESIN PARTICLE AND METHOD FOR PRODUCING THE SAME
  申请人：Mizumori Masahide

  公开号：US20110020741A1

  公开（公告）日：2011-01-27

  A resin particle having a sufficiently narrow particle size distribution obtainable by using a supercritical fluid, and a production method for obtaining a resin particle having a sufficiently narrow particle size distribution by using a supercritical fluid are provided. The present invention provides a resin particle (C) having a microparticle (A) fixed to or formed as a film on a surface of a resin particle (B) containing a resin (b), wherein the degree of swelling of the microparticle (A) by liquid or supercritical carbon dioxide (X) at a temperature lower than the glass transition temperature or the melting point of the microparticle (A) is 16% or less, and the microparticle (A) is at least one kind selected from the group consisting of a crystalline resin (a1), a noncrystalline resin (a2), and an inorganic compound (a3).

  本发明提供了一种通过使用超临界流体获得具有足够窄的粒径分布的树脂颗粒的方法，以及通过使用超临界流体获得具有足够窄的粒径分布的树脂颗粒的生产方法。本发明提供了一种树脂颗粒（C），其具有微粒子（A）固定到或形成为膜的表面上的树脂颗粒（B），其中微粒子（A）在低于微粒子（A）的玻璃转变温度或熔点的温度下，被液体或超临界二氧化碳（X）溶胀的程度为16％或更少，并且微粒子（A）至少选自由包括结晶树脂（a1）、非晶树脂（a2）和无机化合物（a3）的群组。
• Heat-resistant resin composition
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0348906A1

  公开（公告）日：1990-01-03

  A resin composition comprising (A) at least one heat-resistant resin, (B) at least one thermoplastic resin, (C) an antimony oxide, (D) at least one bromine-­containing reaction product selected from the group consisting of (1) a compound having a molecular weight of from 1,200 to 6,000 and a bromine content of from 5.0 to 60% by weight which is obtained by reacting a bromine-containing epoxy compound and 1,3,5-­tribromophenol, and (2) a compound obtained by reacting a bromine-containing epoxy compound having an epoxy equivalent of from 450 to 7,000 and a bromine content of from 5.0 to 52% by weight and an acrylonitrile-butadiene copolymer having a carboxyl group at the both terminals thereof and a molecular weight of from 1,000 to 10,000, and (E) at least one silicon-containing compound selected from the group consisting of (1) silicone oil, (2) a ladder silicone resin, and (3) an alkoxysilane having a mercapto group, a vinyl group or a methacryloyl group, is disclosed. The resin composition is excellent in heat resistance, impact resistance, flame retardancy, and molding properties.

  一种树脂组合物，包括(A) 至少一种耐热树脂，(B) 至少一种热塑性树脂，(C) 氧化锑，(D) 至少一种含溴反应产物，该反应产物选自以下组别：(1) 一种化合物，其分子量为 1,200 至 6,000 之间，溴含量为 5.0至60%(重量)的化合物，它是由含溴环氧化合物和1,3,5-三溴苯酚反应得到的；和(2)由含溴环氧化合物和含溴环氧化合物反应得到的化合物，含溴环氧化合物的环氧当量为450至7,000，溴含量为5.(E) 至少一种含硅化合物，选自(1)硅油，(2)阶梯硅树脂和(3)具有巯基、乙烯基或甲基丙烯酰基的烷氧基硅烷组成的组。该树脂组合物具有优异的耐热性、抗冲击性、阻燃性和成型性能。
• Method of making fluoropolymers
  申请人：UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL

  公开号：EP1172383A2

  公开（公告）日：2002-01-16

  A process for making a fluoropolymer is disclosed. The process comprises solubilizing a fluoromonomer in solvent comprising a carbon dioxide fluid, and then polymerizing the fluoromonomer to produce a the fluoropolymer. A preferred solvent for carrying out the process is supercritical carbon dioxide; preferred fluoromonomers for carrying out the process are fluoroacrylate monomers such as 1,1-dihydroperfluorooctyl acrylate. The polymerization step is preferably carried out in the presence of an initiator such as azobisisobutyronitrile.

  本发明公开了一种制造含氟聚合物的工艺。该工艺包括在含有二氧化碳流体的溶剂中溶解含氟单体，然后聚合含氟单体以生产含氟聚合物。用于实施该工艺的优选溶剂是超临界二氧化碳；用于实施该工艺的优选含氟单体是丙烯酸氟酯单体，如丙烯酸 1,1-二氢全氟辛酯。聚合步骤最好在偶氮二异丁腈等引发剂存在下进行。
• Method of separating fluoropolymer from a solution therof and carbon dioxide
  申请人：The University of North Carolina at Chapel Hill

  公开号：EP1416002A2

  公开（公告）日：2004-05-06

  There is disclosed a method of making fluoropolymers by separating a solution of fluoropolymer and carbon dioxide, said method comprising: providing a solution consisting essentially of carbon dioxide and a fluoropolymer; and passing the solution through an orifice to separate the fluoropolymer from the solution and form a fluoropolymer layer on a substrate.

  本发明公开了一种通过分离含氟聚合物和二氧化碳溶液来制造含氟聚合物的方法，所述方法包括 提供主要由二氧化碳和含氟聚合物组成的溶液；以及 使溶液通过孔口，将含氟聚合物从溶液中分离出来，并在基底上形成含氟聚合物层。
• RESIN COMPOSITION
  申请人：Asahi Kasei E-materials Corporation

  公开号：EP2246377A1

  公开（公告）日：2010-11-03

  The present invention provides a resin composition containing a resin (a1) containing a siloxane bond and having a number-average molecular weight of 500 or more and 300,000 or less, and a resin (a2) containing no siloxane bond and having a number-average molecular weight of 1,000 or more and 300,000 or less.

  本发明提供了一种树脂组合物，其中包含一种含有硅氧烷键且数均分子量在 500 或以上、300,000 或以下的树脂（a1），以及一种不含硅氧烷键且数均分子量在 1,000 或以上、300,000 或以下的树脂（a2）。