2,4-Ethylbenzyldiisocyanat | 21897-43-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-Ethylbenzyldiisocyanat
• 英文别名: Ethyl-m-phenylendiisocyanat；4-ethyl-m-phenylene diisocyanate；4-Aethyl-m-phenylendiisocyanat；Ethyl-m-phenylenediisocyanate；1-ethyl-2,4-diisocyanatobenzene
• CAS: 21897-43-8
• 化学式: C₁₀H₈N₂O₂
• 分子量: 188.186
• InChiKey: FHGPADAQQRYSEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4-Ethylbenzyldiisocyanat 在 吡啶 作用下， 生成 bis-(4-ethyl-3-isocyanato-phenyl)-[1,3]diazetidine-2,4-dione
  参考文献：
  名称：

  Siefken, Justus Liebigs Annalen der Chemie, 1949, vol. 562, p. 75,1114

  摘要：

  DOI：
• 作为产物：
  描述：

  光气 、 4-乙基苯-1,3-二胺 生成 2,4-Ethylbenzyldiisocyanat
  参考文献：
  名称：

  Siefken, Justus Liebigs Annalen der Chemie, 1949, vol. 562, p. 75,1114

  摘要：

  DOI：

文献信息

• Release sustaining composition and sustained release preparation
  申请人：Hayakawa Kazuhisa

  公开号：US20050147676A1

  公开（公告）日：2005-07-07

  A release sustaining composition comprising a polyalkylene polyol derivative comprising repeating units U-1 derived from a water-soluble polyalkylene polyol and a polyisocyanate and repeating units U-2 derived from a dihydroxy compound and a polyisocyanate in a molar ratio of U-1/U-2 between 0.5/0.5 and 0.99/0.01 and optionally a water-soluble cellulose ether is combined with an active ingredient to make a sustained release preparation.

  一种持续释放组合物，包括由可溶于水的聚烯烃聚醚和聚异氰酸酯衍生的重复单元U-1以及由二羟基化合物和聚异氰酸酯衍生的重复单元U-2，在U-1/U-2的摩尔比在0.5/0.5至0.99/0.01之间，可选地与可溶于水的纤维素醚结合，用于制备持续释放制剂。
• SIZING AGENT FOR CARBON FIBER, CARBON FIBER WITH IMPROVED INTERFACIAL ADHESION, POLYMERIZATION REACTION TYPE CARBON FIBER-REINFORCED POLYMER COMPOSITE MATERIAL USING SAME, AND PRODUCTION METHOD THEREFOR
  申请人：KOREA INSTITUTE OF MACHINERY & MATERIALS

  公开号：US20190284751A1

  公开（公告）日：2019-09-19

  The present invention relates to a sizing agent for carbon fibers, a carbon fiber with improved interfacial adhesion, a polymerization reaction type carbon fiber-reinforced polymer composite material using the same, and a production method therefor and, more specifically, to a sizing agent for carbon fibers, comprising a phenoxy resin and a block isocyanate compound prepared through a reaction of ε-caprolactam with one of two isocyanate groups of a diisocyanate compound, and the production of a carbon fiber with improved interfacial adhesion using the same, a polymerization reaction type carbon fiber-reinforced polymer composite material using the carbon fiber with improved interfacial adhesion, and a production method therefor.

  本发明涉及一种用于碳纤维的分散剂、改善界面黏附的碳纤维、采用该分散剂制备的聚合反应型碳纤维增强聚合物复合材料以及其生产方法，更具体地，涉及一种用于碳纤维的分散剂，包括一种苯氧树脂和一种经由ε-己内酰胺与二异氰酸酯化合物的两个异氰酸基中的一个反应制备的块状异氰酸酯化合物，并使用该分散剂生产改善界面黏附的碳纤维，采用改善界面黏附的碳纤维制备的聚合反应型碳纤维增强聚合物复合材料，以及其生产方法。
• LAMINATE
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20150166751A1

  公开（公告）日：2015-06-18

  The laminate according to the invention is comprised of a base material (A), a silicon-containing layer (B) and a polymer layer (C) obtained from an organic acid metallic salt having a polymerizable group. The silicon-containing layer (B) and the polymer layer (C) are sequentially laminated over at least one surface of the base material (A), the silicon-containing layer (B) includes a high nitrogen concentration region comprised of silicon atoms and nitrogen atoms, silicon atoms and nitrogen atoms and oxygen atoms, or silicon atoms and nitrogen atoms and oxygen atoms and carbon atoms. The high nitrogen concentration region is formed by irradiating energy ray onto a polysilazane film formed over the base material (A) under an oxygen concentration equal to or lower than 5% and/or a relative humidity at room temperature (23° C.) equal to or lower than 30% so as to denature at least a part of the film.

  本发明的层压板由基材料(A)、含硅层(B)和聚合物层(C)组成，聚合物层(C)是从具有聚合基团的有机酸金属盐制备而成。硅含量层(B)和聚合物层(C)被顺序地层压在基材料(A)的至少一个表面上，硅含量层(B)包括高氮浓度区，由硅原子和氮原子、硅原子和氮原子和氧原子，或硅原子和氮原子和氧原子和碳原子组成。高氮浓度区是通过在氧浓度等于或低于5%和/或相对湿度在室温(23°C)等于或低于30%的条件下，对基材料(A)上形成的聚硅氮烷薄膜照射能量射线而形成的，以使膜的至少一部分变性。
• Process for producing arylsulfonylureide compounds
  申请人：Yamamoto Chemicals, Inc.

  公开号：EP0879816A1

  公开（公告）日：1998-11-25

  The arylsulfonylureide compound which is of value as a color developer is provided in high yield and high purity by a simple procedure. The technology of the invention for producing an arylsulfonylureide compound of general formula (1)         (Ar1-SO2NHCONH)n-Ar2     (1) wherein Ar1 represents an aromatic residue; Ar2 represents a bivalent or trivalent aromatic residue; n represents an integer of 2 or 3 comprises reacting an arylsulfonamide alkali metal salt of general formula (2)         Ar1-SO2NH·B     (2) wherein B represents an alkali metal with an aromatic isocyanate compound of general formula (3)         Ar2-(NCO)n     (3) in at least one solvent selected from the class consisting of acetonitrile, acetone, methyl ethyl ketone, diethyl ketone, methyl isobutyl ketone, tetrahydrofuran, ethyl acetate, and butyl acetate and containing 1 to 10 weight % of water in a state of suspension being maintained throughout the reaction and eliminating the alkali metal from the resulting arylsulfonylureide compound alkali metal salt in the same solvent.

  本发明通过一个简单的步骤，提供了高产率和高纯度的具有显色剂价值的芳基磺酰脲化合物。本发明生产通式（1）的芳基磺酰脲化合物的技术 (Ar1-SO2NHCONH)n-Ar2 (1) 其中 Ar1 代表芳香族残基；Ar2 代表二价或三价芳香族残基；n 代表 2 或 3 的整数 包括使通式(2)的芳基磺酰胺碱金属盐反应 Ar1-SO2NH-B (2) 其中 B 代表碱金属与通式（3）的芳香族异氰酸酯化合物反应 Ar2-(NCO)n (3) 在至少一种选自乙腈、丙酮、甲乙酮、二乙基酮、甲基异丁基酮、四氢呋喃、乙酸乙酯和乙酸丁酯的溶剂中，并含有 1 至 10 重量％的水 在整个反应过程中保持悬浮状态，并 在相同的溶剂中消除所得芳基磺酰脲化合物碱金属盐中的碱金属。
• NEAR INFRARED RAY SHIELDING FILM
  申请人：TEIJIN LIMITED

  公开号：EP1452556A1

  公开（公告）日：2004-09-01

  A near infrared screening film which consists of a biaxially oriented film made from a polyester containing a near infrared light absorber having a weight reduction start temperature of at least 280° C and which has a haze value of 5 % or less and a total transmittance for visible lights having a wavelength of 400 to 650 nm of 40 % or more and which is exemplified by having optical properties at visible and near infrared ranges which satisfy the following expressions (1) to (4):1 < T(850) < 201 < T(950) < 20- 10 < T(620) - T(540) < 10- 10 < T(450) - T(540) < 10 wherein T(450), T(540), T(620), T(850) and T(950) are light transmittances at wavelengths of 450 nm, 540 nm, 620 nm, 850 nm and 950 nm, respectively. This film is inexpensive, has high handling ease, a high visible light transmittance and the function of preventing the malfunction of peripheral equipment caused by near infrared lights from the screen of a plasma display, for example, and can be suitably used in the front panel of the plasma display.

  一种近红外屏蔽膜，它是由聚酯制成的双向拉伸薄膜，该聚酯含有近红外光吸收剂，其减重起始温度至少为 280℃，雾度值为 5%或以下，对波长为 400 至 650 纳米的可见光的总透射率为 40%或以上，在可见光和近红外范围内的光学特性满足以下表达式(1)至(4)：1 < T(850) < 201 < T(950) < 20- 10 < T(620) - T(540) < 10- 10 < T(450) - T(540) < 10 其中，T(450)、T(540)、T(620)、T(850) 和 T(950) 分别是波长为 450 纳米、540 纳米、620 纳米、850 纳米和 950 纳米时的透光率。 这种薄膜价格低廉、易于操作、可见光透射率高，还具有防止等离子显示器屏幕上的近红外线光等引起外围设备故障的功能，可适当地用于等离子显示器的前面板。