triphenylmethyl [(tris(pentafluorophenyl)boran)2 amide] | 402572-71-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenylmethyl [(tris(pentafluorophenyl)boran)2 amide]
• 英文别名: Diphenylmethylbenzene;tris(2,3,4,5,6-pentafluorophenyl)-[tris(2,3,4,5,6-pentafluorophenyl)boranuidylazaniumyl]boranuide
• CAS: 402572-71-8
• 化学式: C₁₉H₁₅*C₃₆H₂B₂F₃₀N
• 分子量: 1283.32
• InChiKey: NWBAVRBZMDWJAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.76
• 重原子数：
  88
• 可旋转键数：
  11
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  16.6
• 氢给体数：
  1
• 氢受体数：
  32

反应信息

• 作为反应物：
  描述：

  、 triphenylmethyl [(tris(pentafluorophenyl)boran)2 amide] 、 三甲基铝 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  [H₂N{B(C₆F₅)₃}₂]^-:  A New, Remarkably Stable Diborate Anion for Metallocene Polymerization Catalysts

  摘要：

  The reaction between NaNH2 and B(C6F5)3 affords the amidodiborate anion [H2N{B(C6F5)(3)}(2)](-), the structure of which shows multiple intramolecular NH...F hydrogen bonding. Reaction with HCl affords [H(OEt2)(2)][H2N{B(C6F5)(3)}(2)], while treatment of zirconocene dimethyls with [CPh3][H2N{B(C6F5)(3)}(2)] gives highly active alkene polymerization catalysts.

  DOI：

  10.1021/om010942s
• 作为产物：
  描述：

  、 三苯基氯甲烷 以 二氯甲烷 为溶剂， 以50%的产率得到triphenylmethyl [(tris(pentafluorophenyl)boran)2 amide]
  参考文献：
  名称：

  [H₂N{B(C₆F₅)₃}₂]^-:  A New, Remarkably Stable Diborate Anion for Metallocene Polymerization Catalysts

  摘要：

  The reaction between NaNH2 and B(C6F5)3 affords the amidodiborate anion [H2N{B(C6F5)(3)}(2)](-), the structure of which shows multiple intramolecular NH...F hydrogen bonding. Reaction with HCl affords [H(OEt2)(2)][H2N{B(C6F5)(3)}(2)], while treatment of zirconocene dimethyls with [CPh3][H2N{B(C6F5)(3)}(2)] gives highly active alkene polymerization catalysts.

  DOI：

  10.1021/om010942s

文献信息

• [H₂N{B(C₆F₅)₃}₂]^-:  A New, Remarkably Stable Diborate Anion for Metallocene Polymerization Catalysts
  作者：Simon J. Lancaster、Antonio Rodriguez、Agustin Lara-Sanchez、Mark D. Hannant、Dennis A. Walker、David H. Hughes、Manfred Bochmann

  DOI：10.1021/om010942s

  日期：2002.2.1

  The reaction between NaNH2 and B(C6F5)3 affords the amidodiborate anion [H2NB(C6F5)(3)}(2)](-), the structure of which shows multiple intramolecular NH...F hydrogen bonding. Reaction with HCl affords [H(OEt2)(2)][H2NB(C6F5)(3)}(2)], while treatment of zirconocene dimethyls with [CPh3][H2NB(C6F5)(3)}(2)] gives highly active alkene polymerization catalysts.