2,2'-[5,6-(1,10-phenanthroline)bis(oxy)]-bis(N,N-dibenzylacetamide) | 752994-27-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2,2'-[5,6-(1,10-phenanthroline)bis(oxy)]-bis(N,N-dibenzylacetamide)
• 英文别名: 1,10-phenanthroline-5,6-bis(N,N-dibenzyl-1'-oxopropylamide)；N,N-dibenzyl-2-[[6-[2-(dibenzylamino)-2-oxoethoxy]-1,10-phenanthrolin-5-yl]oxy]acetamide
• CAS: 752994-27-7
• 化学式: C₄₄H₃₈N₄O₄
• 分子量: 686.81
• InChiKey: IWWAPLQYQUBATN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  52
• 可旋转键数：
  14
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  84.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  lanthanum(III) nitrate hexahydrate 、 2,2'-[5,6-(1,10-phenanthroline)bis(oxy)]-bis(N,N-dibenzylacetamide) 以 乙酸乙酯 为溶剂， 以80%的产率得到[La4(NO3)10(1,10-phenanthroline-5,6-bis(N,N-dibenzyl-1'-oxopropylamide)3](NO3)2
  参考文献：
  名称：

  Terminal group effects on the fluorescence spectra of Eu(III) nitrate complexes with a family of amide-based 1,10-phenanthroline derivatives

  摘要：

  Four ligands 1,10-phenanthroline-5,6-bis(N,N-dibenzyl-l'-oxopropylamide) (L-a) 1,10-phenanthroline-5,6-bis(N-methyl-N-benzyl-l'oxopropylamide) (L-b) 1,10-phenanthroline-5,6-bis(N-benzyl-l'-oxopropylamide) (L-c) and 1,10-phenanthroline-5,6-bis(N,N-diethyl-l'oxopropylamide) (L-d), and their lanthanide(III) (La and Eu) complexes were synthesized. The complexes were characterized by elemental analysis, IR, fluorescence spectroscopy and conductivity. The lanthanide atoms are coordinated by O atoms from C=O, Ar-O-C and N atoms from phen With the difference of the ligands, the fluorescent intensities of the Eu(Ill) complexes vary regularly in the THF solution. Some factors that influence the fluorescent intensity were discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.03.010
• 作为产物：
  描述：

  2-氯-N,N-二(苯基甲基)-乙酰胺 、 1,10-phenanthroline-5,6-diol hydrochloride 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以85%的产率得到2,2'-[5,6-(1,10-phenanthroline)bis(oxy)]-bis(N,N-dibenzylacetamide)
  参考文献：
  名称：

  新型euro和ter多核配合物与酰胺基1,10-菲咯啉衍生物的合成，红外光谱和荧光光谱。

  摘要：

  合成了酰胺基的1,10-菲咯啉（phen）衍生物及其与euro（III）和b（III）离子的配合物。通过元素分析，红外光谱和电导率对配合物进行表征。O和ter离子由C = O的O原子，Ar-OC和phen的N原子配位。研究了配合物在THF，二恶烷，MeCN和DMF中的荧光性质。在紫外光的激发下，这些络合物表现出characteristic和ter离子的特征荧光。讨论了影响荧光强度的溶剂因素。

  DOI：

  10.1016/j.saa.2003.09.009

文献信息

• Synthesis and infrared and fluorescence spectra of new europium and terbium polynuclear complexes with an amide-based 1,10-phenanthroline derivative
  作者：Yu-Liang Zhang、Wei-Sheng Liu、Wei Dou、Wen-Wu Qin

  DOI：10.1016/j.saa.2003.09.009

  日期：2004.7

  amide-based 1,10-phenanthroline (phen) derivative and its complexes with europium(III) and terbium(III) ions were synthesized. The complexes were characterized by elemental analysis, infrared spectra and conductivity. The europium and terbium ions were coordinated by O atoms of C=O, Ar-O-C and N atoms of phen. The fluorescence properties of the complexes in THF, dioxane, MeCN and DMF were investigated. Under

  合成了酰胺基的1,10-菲咯啉（phen）衍生物及其与euro（III）和b（III）离子的配合物。通过元素分析，红外光谱和电导率对配合物进行表征。O和ter离子由C = O的O原子，Ar-OC和phen的N原子配位。研究了配合物在THF，二恶烷，MeCN和DMF中的荧光性质。在紫外光的激发下，这些络合物表现出characteristic和ter离子的特征荧光。讨论了影响荧光强度的溶剂因素。
• Terminal group effects on the fluorescence spectra of Eu(III) nitrate complexes with a family of amide-based 1,10-phenanthroline derivatives
  作者：Su-Wen Chen、Yu-Liang Zhang、Wei Dou、Ya-Wen Wang、Wei-Sheng Liu

  DOI：10.1016/j.saa.2005.03.010

  日期：2005.12

  Four ligands 1,10-phenanthroline-5,6-bis(N,N-dibenzyl-l'-oxopropylamide) (L-a) 1,10-phenanthroline-5,6-bis(N-methyl-N-benzyl-l'oxopropylamide) (L-b) 1,10-phenanthroline-5,6-bis(N-benzyl-l'-oxopropylamide) (L-c) and 1,10-phenanthroline-5,6-bis(N,N-diethyl-l'oxopropylamide) (L-d), and their lanthanide(III) (La and Eu) complexes were synthesized. The complexes were characterized by elemental analysis, IR, fluorescence spectroscopy and conductivity. The lanthanide atoms are coordinated by O atoms from C=O, Ar-O-C and N atoms from phen With the difference of the ligands, the fluorescent intensities of the Eu(Ill) complexes vary regularly in the THF solution. Some factors that influence the fluorescent intensity were discussed. (c) 2005 Elsevier B.V. All rights reserved.