1-(9-anthryl)-2-propanol | 129948-80-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-(9-anthryl)-2-propanol
• 英文别名: α-methyl-9-anthraceneethanol；9-(2-hydroxypropyl)anthracene；1-anthracen-9-ylpropan-2-ol
• CAS: 129948-80-7
• 化学式: C₁₇H₁₆O
• 分子量: 236.313
• InChiKey: HOXSNGWXDDVWQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(9-anthryl)-2-propanol 在 戴斯-马丁氧化剂 作用下， 以 二氯甲烷 为溶剂， 以89%的产率得到9-anthrylacetone
  参考文献：
  名称：

  Synthesis and photochemical properties of 1,3-di-9-anthryl-2-propanol, 1,3-di-9-anthrylacetone, and related propano-linked anthracenes

  摘要：

  DOI：

  10.1021/jo00274a040
• 作为产物：
  描述：

  ω-(anthracene-9-yl)ethanal 、 甲基碘化镁 以 乙醚 为溶剂， 反应 6.0h， 以above gave 1.05 g (89%) of 1-(9-anthryl)-2-propanol as pale yellow needle的产率得到1-(9-anthryl)-2-propanol
  参考文献：
  名称：

  9-anthrylalkyl compounds

  摘要：

  新的9-蒽基烷基化合物具有通式##STR1##其中R为氢或烷基，但不超过一个R为烷基；R.sub.1为氢，低烷基，卤素或硝基；n为1至7的整数，但在--CHR--(CHR).sub.n --中碳原子的总数不超过8；X为卤素，偶氮基或琥珀酰亚胺基。新化合物是从9-蒽基醇中制备的，其与化合物X-CO-X（其中X为卤素），然后在需要时与给出偶氮基或琥珀酰亚胺基的化合物反应。该化合物用作衍生化试剂，用于分离和检测目的。制备上述定义的一个R为烷基的9-蒽基烷基化合物的中间体是具有--CHR--(CHR).sub.n --OH基团的9-蒽基醇，其中一个R为烷基。

  公开号：

  US05015755A1

文献信息

• PHOTOBASE GENERATOR
  申请人：Kuramoto Ayako

  公开号：US20110233048A1

  公开（公告）日：2011-09-29

  There is intended to provide the novel compounds which generate a base easily when irradiated with long wavelength light (active energy rays), a photobase generator containing the compounds and a photobase generation method, and the present invention relates to the compounds represented by the general formula [1], a photobase generator containing the compounds and a photobase generation method: (wherein, Ar represents any of groups with specific structures selected from the group consisting of an anthracenyl group, an anthraquinonyl group and a pyrenyl group; R 1 and R 2 each independently represent a hydrogen atom or a linear, branched or cyclic alkyl group having 1 to 10 carbon atoms, or represent ones which can form an alicyclic ring containing nitrogen atom(s) or an aromatic ring containing nitrogen atom(s) together with a nitrogen atom to which they are bound, which the rings having 3 to 8 carbon atoms which may have a substituent, R 3 and R 4 each independently represent a hydrogen atom, a linear, branched or acyclic alkyl group having 1 to 10 carbon atoms).

  本发明旨在提供当受长波长光（活性能量射线）照射时易于产生碱的新化合物，包含这些化合物的光碱发生器以及光碱生成方法，本发明涉及由通式[1]表示的化合物，包含这些化合物的光碱发生器以及光碱生成方法：（其中，Ar代表从蒽基团、蒽醌基团和芘基团中选择的具有特定结构的任何基团；R1和R2各自独立地代表氢原子或具有1至10个碳原子的直链、支链或环烷基基团，或表示能够与它们结合的氮原子形成含氮原子的脂环烷基环或含氮原子的芳香环，这些环具有3至8个碳原子，可能有取代基；R3和R4各自独立地代表氢原子，具有1至10个碳原子的直链、支链或非环烷基基团）。
• Stereoselective Diels−Alder Reactions of Chiral Anthracenes
  作者：Amitav Sanyal、John K. Snyder

  DOI：10.1021/ol006206m

  日期：2000.8.1

  Various chiral (9-anthryl)carbinol templates undergo Diels-Alder cycloadditions with a variety of symmetric and nonsymmetric dienophiles with excellent pi-facial selectivity and regioselectivity, under both thermal and Lewis acid catalyzed conditions.

  各种手性（9-蒽）甲醇模板在热和Lewis酸催化条件下均经历Diels-Alder环加成反应，并带有多种对称和非对称的亲二烯体，具有优异的表面选择性和区域选择性。
• 9-anthrylalkyl compounds
  申请人：Eka Nobel AB

  公开号：US05015755A1

  公开（公告）日：1991-05-14

  New 9-anthrylalkyl compounds having the general formula ##STR1## wherein R is hydrogen or an alkyl group, whereby, however, not more than one of the groups R is an alkyl group; R.sub.1 is hydrogen, lower alkyl, halogen or nitro; n is an integer of from 1 to 7, whereby, however, the total number of carbon atoms in the group --CHR--(CHR).sub.n -- does not exceed 8; and X is halogen, an azide group or a succinimidyl group. The new compounds are prepared from 9-anthrylalcohols which are reacted with a compound X--CO--X wherein X is a halogen, and then optionally with compounds giving azide or succinimidyl group. The compounds are used as derivatization reagents for separation and detection purposes. Intermediates for preparation of the above defined 9-anthrylalkyl compounds wherein one R is an alkyl group are 9-anthrylalcohols with the group --CHR--(CHR).sub.n --OH, wherein one R is an alkyl group.

  新的9-蒽基烷基化合物具有通式##STR1##其中R为氢或烷基，但不超过一个R为烷基；R.sub.1为氢，低烷基，卤素或硝基；n为1至7的整数，但在--CHR--(CHR).sub.n --中碳原子的总数不超过8；X为卤素，偶氮基或琥珀酰亚胺基。新化合物是从9-蒽基醇中制备的，其与化合物X-CO-X（其中X为卤素），然后在需要时与给出偶氮基或琥珀酰亚胺基的化合物反应。该化合物用作衍生化试剂，用于分离和检测目的。制备上述定义的一个R为烷基的9-蒽基烷基化合物的中间体是具有--CHR--(CHR).sub.n --OH基团的9-蒽基醇，其中一个R为烷基。
• Use of 9-anthrylalkyl compounds as derivatization reagents for
  申请人：Eka Nobel AB

  公开号：US05128120A1

  公开（公告）日：1992-07-07

  New 9-anthrylalkyl compounds having the general formula ##STR1## wherein R is hydrogen or an alkyl group, whereby, however, not more than one of the groups R is an alkyl group; R.sub.1 is hydrogen, lower alkyl, halogen or nitro; n is an integer of from 1 to 7, whereby, however, the total number of carbon atoms in the group --CHR--(CHR).sub.n -- does not exceed 8; and X is halogen, an azide group or a succinimidyl group. The new compounds are prepared from 9-anthrylalcohols which are reacted with a compound X--CO--X wherein X is a halogen, and then optionally with compounds giving azide or succinimidyl group. The compounds are used as derivatization reagents for separation and detection purposes. Intermediates for preparation of the above defined 9-anthrylalkyl compounds wherein one R is an alkyl group are 9-anthrylalcohols with the group --CHR--(CHR).sub.n --OH, wherein one R is an alkyl group.

  新的9-蒽基烷基化合物具有一般式## STR1## 其中R为氢或烷基，但不超过一个R是烷基；R.sub.1为氢，低烷基，卤素或硝基；n为1至7的整数，但是，--CHR--(CHR).sub.n --中的碳原子总数不超过8；X为卤素，偶氮基或琥珀酰亚胺基。新化合物是由9-蒽醇与化合物X-CO-X反应制备而成，其中X为卤素，然后可以选择性地与给出偶氮基或琥珀酰亚胺基的化合物反应。该化合物用作衍生化试剂，用于分离和检测目的。制备上述定义的9-蒽基烷基化合物其中一个R为烷基的中间体是带有--CHR--(CHR).sub.n --OH基团的9-蒽醇，其中一个R为烷基。
• 9-Anthrylalkyl compounds, their preparation and their use
  申请人：Eka Nobel Aktiebolag

  公开号：EP0365495A2

  公开（公告）日：1990-04-25

  New 9-anthrylalkyl compounds having the general formula wherein R is hydrogen or an alkyl group, whereby, however, not more than one of the groups R is an alkyl group; R₁ is hydrogen, lower alkyl, halogen or nitro; n is an integer of from 1 to 7, whereby ,however, the total number of carbon atoms in the group -CHR-(CHR)n- does not exceed 8; and X is halogen, an azide group or a succinimidyl group. The new compounds are prepared from 9-anthrylalcohols which are reacted with a compound X-CO-X wherein X is a halogen, and then optionally with compounds giving azide or succinimidyl group. The compounds are used as derivatiza­tion reagents for separation and detection purposes. Intermediates for preparation of the above defined 9-anthrylalkyl compounds wherein one R is an alkyl group are 9-anthrylalcohols with the group -CHR-(CHR)n-OH, wherein one R is an alkyl group.

  通式如下的新型 9-蒽烷基化合物 其中，R 是氢或烷基，但是，R 中不超过一个基团是烷基；R₁ 是氢、低级烷基、卤素或硝基；n 是 1 到 7 的整数，但是，基团 -CHR-(CHR)n- 中的碳原子总数不超过 8；X 是卤素、叠氮基团或琥珀酰亚胺基团。 新化合物由 9-蒽醇制备而成，9-蒽醇先与化合物 X-CO-X 反应，其中 X 为卤素，然后再与含有叠氮基团或琥珀酰亚胺基团的化合物反应。这些化合物可用作衍生试剂，用于分离和检测。 制备上述定义的 9-蒽烷基化合物（其中一个 R 是烷基）的中间体是基团为 -CHR-(CHR)n-OH（其中一个 R 是烷基）的 9-蒽醇。