N-t-butyl-p-vinylbenzylamine | 143673-98-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-t-butyl-p-vinylbenzylamine
• 英文别名: 2-Methyl-N-(4-vinylbenzyl)propan-2-amine；N-[(4-ethenylphenyl)methyl]-2-methylpropan-2-amine
• CAS: 143673-98-7
• 化学式: C₁₃H₁₉N
• 分子量: 189.301
• InChiKey: WXGNRGBDUYIKGV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  magnesium,ethenylbenzene,chloride 在 sodium tetrahydroborate 、 molecular sieve 作用下， 以 甲醇 、 苯 为溶剂， 反应 3.25h， 生成 N-t-butyl-p-vinylbenzylamine
  参考文献：
  名称：

  聚(p-[α-(Nt-丁基硝酰基)]苯乙烯)的合成及其与二氧化氮的反应

  摘要：

  聚(p-[α-(Nt-丁基硝酰基)]苯乙烯) (polyPBN) 已通过使用对氯苯乙烯作为原料制备。研究了 polyPBN 与二氧化氮 (NO2) 的反应及其自由基捕获效率。polyPBN 的 NO2 加合物的稳定性和回收 polyPBN 的操作简单性表明 polyPBN 适用于去除大气中的 NO2。

  DOI：

  10.1246/cl.1992.1189

文献信息

• The Synthesis of Poly[<i>N</i>-(<i>p</i>-vinylbenzylidene)-<i>t</i>-butylamine<i>N</i>-oxide] and Characterizations of Reaction with Nitrogen Dioxide
  作者：Jingzhu Ren、Kazuhisa Sakakibara、Minoru Hirota

  DOI：10.1246/bcsj.66.1897

  日期：1993.7

  Polymer-supported spin trap, poly[N-(p-vinylbenzylidene)-t-butylamine N-oxide] (polyPBN), was prepared by using p-chlorostyrene as a starting material, followed by Grignard reaction, condensation with t-butylamine, reduction, polymerization, and oxidation. The adsorption ability of NO2 by polyPBN was investigated in a closed-circulation system. PolyPBN maintains its original NO2 adsorbing ability in the mixed gas of nitrogen and nitrogen dioxide saturated with water vapor even after repeated (5 times) use. However, when the gaseous phase is freed from water, polyPBN exhibits less efficiency to adsorb NO2 and its adsorbing ability decreases gradually with the repeated use.

  以对氯苯乙烯为起始材料，经过格氏反应、与叔丁胺缩合、还原、聚合和氧化制备了聚合物支撑的自旋阱--聚[N-（对乙烯基亚苄基）-叔丁胺 N-氧化物]（polyPBN）。研究人员在封闭循环系统中考察了 PolyPBN 对 NO2 的吸附能力。在氮气和饱和水蒸气的二氧化氮混合气体中，即使反复使用（5 次），PolyPBN 仍能保持其原有的二氧化氮吸附能力。然而，当气相中不含水分时，PolyPBN 对 NO2 的吸附效率较低，并且随着重复使用，其吸附能力逐渐下降。
• VERNETZTER KUNSTSTOFFWERKSTOFF MIT INTRINSISCH ANTIMIKROBIELLER WIRKUNG AUF BASIS VON VINYLESTERN UND VINYLESTERURETHANEN
  申请人：Fachhochschule Münster

  公开号：EP2951243A1

  公开（公告）日：2015-12-09
• VERNETZTER KUNSTSTOFFWERKSTOFF MIT INTRINSISCH ANTIMIKROBIELLER WIRKUNG AUF BASIS UNGESÄTTIGTER POLYESTER
  申请人：Fachhochschule Münster

  公开号：EP2951245A1

  公开（公告）日：2015-12-09
• CROSS-LINKED PLASTIC MATERIAL WITH AN INTRINSIC ANTIMICROBIAL EFFECT BASED ON UNSATURATED POLYESTERS
  申请人：FACHHOCHSCHULE MÜNSTER

  公开号：US20150361259A1

  公开（公告）日：2015-12-17

  The present invention relates to a radically curable chemical composition in the form of a resin for the production of materials with an intrinsically antimicrobial effect, as well as a process for the production of such resins and materials, as well as the use of an amino-functionalized styrene derivative as reactive diluents. The cross-linked plastic formed upon curing has an intrinsically antimicrobial effect without the use of additional biocides.
• CROSS-LINKED PLASTIC MATERIAL WITH AN INTRINSIC ANTIMICROBIAL EFFECT BASED ON VINYL ESTERS AND VINYL ESTER URETHANES
  申请人：FACHHOCHSCHULE MÜNSTER

  公开号：US20150361277A1

  公开（公告）日：2015-12-17

  The present invention is directed to a radically curable chemical composition in form of a resin for the production of materials having an intrinsic antimicrobial effect, to the applications of these materials, to a method for the preparation of these resins and materials, and to the use of an amino-functionalized styrene derivative as a reactive diluent. The cross-linked plastic materials formed after curing have an intrinsic antimicrobial effect without the use of additional biocides.