1H-benzo[de]cinnoline | 28022-68-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 1H-benzo[de]cinnoline
• 英文别名: Diazaphenalene；2,3-diazatricyclo[7.3.1.05,13]trideca-1(12),3,5,7,9(13),10-hexaene
• CAS: 28022-68-6
• 化学式: C₁₁H₈N₂
• 分子量: 168.198
• InChiKey: JCWKQYJXSKIGEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-甲酰基-8-硝基萘 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 6.0h， 以62%的产率得到1H-benzo[de]cinnoline
  参考文献：
  名称：

  10.1007/s11178-008-1022-y

  摘要：

  DOI：

  10.1007/s11178-008-1022-y

文献信息

• COMPOUND AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAID COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2520576A1

  公开（公告）日：2012-11-07

  The present invention provides a novel compound having an excellent property to inject a hole into a device such as an organic EL device. More specifically, the present invention provides a compound comprising a residue obtained by removing at least one hydrogen atom from a structure represented by the following formula (1): wherein each R1 represents a hydrogen atom, an alkyl group, or the like, each of such groups optionally having a substituent; the R1s may be the same or different; each R2 represents a hydrogen atom, an alkyl group, or the like, each of such groups optionally having a substituent; the R2s may be the same or different; each R4 represents a hydrogen atom, an alkyl group, or the like, each of such groups optionally having a substituent; the R4s may be the same or different; each R15 represents an alkyl group or the like, each of such groups optionally having a substituent; where there are a plurality of R15, they may be the same or different; each e represents an integer of from 0 to 6; and the e's may be the same or different.

  本发明提供了一种新型化合物，具有优良的性能，可以向有机EL器件等设备注入孔。更具体地，本发明提供了一种化合物，其包括通过从以下式（1）所表示的结构中去除至少一个氢原子而获得的残基：其中每个R1代表氢原子、烷基基团或类似物，这些基团中的每一个可以选择地具有取代基；R1可以相同也可以不同；每个R2代表氢原子、烷基基团或类似物，这些基团中的每一个可以选择地具有取代基；R2可以相同也可以不同；每个R4代表氢原子、烷基基团或类似物，这些基团中的每一个可以选择地具有取代基；R4可以相同也可以不同；每个R15代表烷基基团或类似物，这些基团中的每一个可以选择地具有取代基；如果有多个R15，则它们可以相同也可以不同；每个e表示从0到6的整数；e可以相同也可以不同。
• Polymer compound and polymer light emitting device
  申请人：Yamamoto Takakazu

  公开号：US20120200808A1

  公开（公告）日：2012-08-09

  To provide a polymer compound which is useful as a light emitting material or charge transport material having a boron atom. A polymer compound comprising a structure represented by a formula (1) as described below: wherein R 1 , R 2 , and R 3 each independently represents a hydrogen atom or a substituent.

  提供一种聚合物化合物，可用作具有硼原子的发光材料或电荷传输材料。包括以下公式（1）所表示的结构的聚合物化合物：其中R1、R2和R3分别独立表示氢原子或取代基。
• Polymeric light emitting substance and polymer light emitting device using the same
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20020193532A1

  公开（公告）日：2002-12-19

  A polymeric light emitting substance having a polystyrene reduced number-average molecular weight of from 10 3 to 10 8 wherein this light emitting substance has in the main chain or side chain a metal complex structure showing light emission from the triplet excited state, and said substance can form a light emitting layer by industrially simple application methods such as a spin coat method, inkjet method, printing method and the like.

  具有聚苯乙烯减少数量平均分子量为103到108的高分子发光物质，其中该发光物质在主链或侧链中具有显示从三重激发态发射光的金属配合物结构，并且该物质可以通过工业简单的应用方法（如旋涂法、喷墨法、印刷法等）形成发光层。
• Polymer and polymeric luminescent element comprising the same
  申请人：Tamao Kohei

  公开号：US20050170202A1

  公开（公告）日：2005-08-04

  A polymer characterized by comprising repeating units represented by the following formula (1) and having a number-average molecular weight, in terms of polystyrene, of 10 3 to 10 8 . (In the formula, R 1 represents hydrogen, alkyl, alkoxy, alkylthio, aryl, aryloxy, arylthio, arylalkyl, arylalkoxy, arylalkylthio, arylalkenyl, arylalkynyl, amino, substituted amino, silyl, substituted silyl, silyloxy, substituted silyloxy, monovalent heterocyclic group, or halogeno; and rings D and E each represents an optionally substituted aromatic ring.)

  一种聚合物，其特征在于包含由以下式（1）表示的重复单元，并且在以聚苯乙烯为单位的数量平均分子量为103至108之间。（在公式中，R1表示氢，烷基，烷氧基，烷硫基，芳基，芳氧基，芳硫基，芳基烷基，芳基烷氧基，芳基烷硫基，芳基烯基，芳基炔基，氨基，取代氨基，硅烷基，取代硅烷基，硅氧基，取代硅氧基，单价杂环基或卤素；环D和E各代表可选的取代芳环。）
• Polymeric fluorescent substance and polymer light-emitting device using the same
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20020122899A1

  公开（公告）日：2002-09-05

  A polymeric fluorescent substance exhibiting fluorescence in the solid state, having a polystyrene reduced number-average molecular weight of 1'10 3 to 1×10 8 , and comprising one or more repeating units of formula (1) and one or more repeating units of formula (8), —Ar 1 —(CR 1 ═CR 2 ) n (1) —Ar 2 —(CR 36 ═CR 37 ) n —  (8) wherein Ar 1 represents a specific arylene or a divalent heterocyclic compound group, and Ar 2 represent an arylene or a divalent heterocyclic compound group other than Ar 1 . By using the polymeric fluorescent substance, a high performance polymer LED can easily be obtained.

  一种聚合荧光物质，在固态下表现出荧光，其聚苯乙烯的减少平均分子量为1'103至1×108，并包含一个或多个由公式（1）和一个或多个由公式（8）重复单元构成的重复单元，-Ar1-（CR1═CR2）n（1）-Ar2-（CR36═CR37）n-（8），其中Ar1表示特定的芳基或双价杂环化合物基团，而Ar2表示除Ar1以外的芳基或双价杂环化合物基团。通过使用这种聚合荧光物质，可以轻松获得高性能的聚合物LED。