N'-(2-methoxybenzoyl)hydrazinecarbodithiolate | 1073819-08-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N'-(2-methoxybenzoyl)hydrazinecarbodithiolate
• 英文别名: Benzyl N'-(2-methoxybenzoyl)hydrazinecarbodithioate；benzyl N-[(2-methoxybenzoyl)amino]carbamodithioate
• CAS: 1073819-08-5
• 化学式: C₁₆H₁₆N₂O₂S₂
• 分子量: 332.447
• InChiKey: MCQNOFUUJZOUIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  108
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N'-(2-methoxybenzoyl)hydrazinecarbodithiolate 以 甲醇 、 氯仿 为溶剂， 生成 [Mn(N'-(2-methoxybenzoyl)hydrazinecarbodithiolate(1-))2(o-phen)]*DMSO
  参考文献：
  名称：

  First row transition metal complexes of benzyl N′-(2-methoxybenzoyl)hydrazinecarbodithioate (H2mbhcd): X-ray structures of [Mn(Hmbhcd)2(o-phen)]·DMSO and [Mn2(Hmbhcd)2(2,2′-bpy)2(μ-OAc)2]

  摘要：

  The ligand benzyl N'-(2-methoxybenzoyl)hydrazinecarbodithioate (H(2)mbhcd) (1), having a NOS donor sequence, formed a series of complexes [M(Hmbhcd)(2)](n) {M = Mn(II), Co(II) and Ni(II) (2, 5 and 6)}, [Mn(Hmbhcd)(2)(o-phen)] center dot DMSO (3) and [Mn-2(Hmbhcd)(2)(2,2'-bpy)(2)(mu-OAc)(2)] (4). The complexes 3 and 4 have been obtained as single crystals, containing o-phen/2,2'-bpy as coligands. The compounds 2, 5 and 6 have been characterized with the aid of elemental analyses, IR, UV-Vis, magnetic susceptibility and mass spectrometry. Compound 3 crystallized in the triclinic system with the space group P (1) over bar while 4 crystallized in the monoclinic system with the space group P2(1)/c. The (N,O) donor sites of the uninegative bidentate ligand chelates the Mn(II) center to form a five-membered MnOCN2 ring in both complexes 3 and 4. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.12.061

文献信息

• First row transition metal complexes of benzyl N′-(2-methoxybenzoyl)hydrazinecarbodithioate (H2mbhcd): X-ray structures of [Mn(Hmbhcd)2(o-phen)]·DMSO and [Mn2(Hmbhcd)2(2,2′-bpy)2(μ-OAc)2]
  作者：M. Singh、R.J. Butcher、N.K. Singh

  DOI：10.1016/j.poly.2008.12.061

  日期：2009.5

  The ligand benzyl N'-(2-methoxybenzoyl)hydrazinecarbodithioate (H(2)mbhcd) (1), having a NOS donor sequence, formed a series of complexes [M(Hmbhcd)(2)](n) M = Mn(II), Co(II) and Ni(II) (2, 5 and 6)}, [Mn(Hmbhcd)(2)(o-phen)] center dot DMSO (3) and [Mn-2(Hmbhcd)(2)(2,2'-bpy)(2)(mu-OAc)(2)] (4). The complexes 3 and 4 have been obtained as single crystals, containing o-phen/2,2'-bpy as coligands. The compounds 2, 5 and 6 have been characterized with the aid of elemental analyses, IR, UV-Vis, magnetic susceptibility and mass spectrometry. Compound 3 crystallized in the triclinic system with the space group P (1) over bar while 4 crystallized in the monoclinic system with the space group P2(1)/c. The (N,O) donor sites of the uninegative bidentate ligand chelates the Mn(II) center to form a five-membered MnOCN2 ring in both complexes 3 and 4. (C) 2009 Elsevier Ltd. All rights reserved.