p-Brom-phenyldiazen | 22719-25-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-Brom-phenyldiazen
• 英文别名: Diazene, (4-bromophenyl)-；(4-bromophenyl)diazene
• CAS: 22719-25-1
• 化学式: C₆H₅BrN₂
• 分子量: 185.023
• InChiKey: BNIBNRHSDMYMJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  36.2
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• MACROCYCLIC INHIBITORS OF FLAVIVIRIDAE VIRUSES
  申请人：Gilead Sciences, Inc.

  公开号：US20170190737A1

  公开（公告）日：2017-07-06

  Provided are compounds of Formula I: and pharmaceutically acceptable salts and esters thereof. The compounds, compositions, and methods provided are useful for the treatment of virus infections, particularly hepatitis C infections.

  提供的是公式I的化合物： 及其药用可接受的盐和酯。这些化合物、组合物和方法对于治疗病毒感染特别是有用的，尤其是丙型肝炎感染。
• [EN] NEW PROCESS FOR PREPARING ARYLBORANES BY ARYLATION OF ORGANOBORON COMPOUNDS<br/>[FR] NOUVEAU PROCÉDÉ POUR LA PRÉPARATION D'ARYLBORANES PAR ARYLATION DE COMPOSÉS ORGANOBORÉS
  申请人：UNIV BORDEAUX 1

  公开号：WO2014009169A1

  公开（公告）日：2014-01-16

  The present invention relates to a new process for the preparation of an arylborane compound, by arylation of a B-H bond, which comprises a step (1) of contacting an arenediazonium salt or a heteroarenediazonium salt with an organoboron compound containing at least one B-H bond, in a reaction medium containing a solvent, in the absence of base, in the absence or in the presence of an activating agent, for the preparation of an arylborane compound, and a possible step (2) of recovery and purification of said arylborane compound obtained at the step (1), said arylborane being in particular an aminoarylborane, and a possible step (3) of refunctionalisation of said arylborane obtained at step (1) or (2) for the preparation of aryl boronic derivatives or arylborates.

  本发明涉及一种制备芳基硼烷化合物的新工艺，通过芳基硼-氢键的芳基化，包括以下步骤：(1)将芳基重氮盐或杂环芳基重氮盐与至少含有一个硼-氢键的有机硼化合物在反应介质中接触，所述反应介质包含溶剂，在无碱的情况下，在缺乏或存在活化剂的情况下，用于制备芳基硼烷化合物，并可能进行(2)步骤以回收和纯化在步骤(1)中得到的所述芳基硼烷化合物，所述芳基硼烷化合物特别是氨基芳基硼烷，以及可能进行(3)步骤对在步骤(1)或(2)中得到的所述芳基硼烷进行重官能化，用于制备芳基硼酸衍生物或芳基硼酸酯。
• PROCESS FOR DERIVATIZING CARBON NANOTUBES WITH DIAZONIUM SPECIES AND COMPOSITIONS THEREOF
  申请人：Tour James M.

  公开号：US20090301896A1

  公开（公告）日：2009-12-10

  Methods for the chemical modification of carbon nanotubes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter (ca. 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications, and sensor devices. The methods of derivatization include electrochemical induced reactions, thermally induced reactions, and photochemically induced reactions. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes.

  碳纳米管的化学修饰方法包括使用重氮化物对多壁和单壁碳纳米管进行衍生化，包括直径小于0.7纳米的单壁碳纳米管。该方法允许将各种有机化合物化学附着到碳纳米管的侧面和端部。这些化学修饰的纳米管在聚合物复合材料、分子电子应用和传感器设备中有应用。衍生化的方法包括电化学诱导反应、热诱导反应和光化学诱导反应。此外，当用适当的化学基团修饰时，衍生化的纳米管与聚合物基质化学相容，使得纳米管的性质（如力学强度或电导率）能够转移到复合材料整体的性质上。此外，当用适当的化学基团修饰时，这些基团可以聚合形成包含碳纳米管的聚合物。
• New process for preparing arylboranes by arylation of organoboron compounds
  申请人：UNIVERSITE DE BORDEAUX

  公开号：EP2684887B1

  公开（公告）日：2015-06-17
• DEVICE FOR DETECTING GASES AND/OR VOLATILE ORGANIC COMPOUNDS (VOC)
  申请人：Commissariat à l'Énergie Atomique et aux Énergies Alternatives

  公开号：EP2480880B1

  公开（公告）日：2014-03-19