2,6,2',6',2'',6''-hexa-tert-butyl-4,4',4''-[1,3,5]triazine-2,4,6-triyltrimethyl-tris-phenol | 41243-96-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6,2',6',2'',6''-hexa-tert-butyl-4,4',4''-[1,3,5]triazine-2,4,6-triyltrimethyl-tris-phenol
• 英文别名: 4-[[4,6-Bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazin-2-yl]methyl]-2,6-ditert-butylphenol
• CAS: 41243-96-3
• 化学式: C₄₈H₆₉N₃O₃
• 分子量: 736.094
• InChiKey: KSVUNYDRKINFCO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.8
• 重原子数：
  54
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  99.4
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3,5-di(tert-butyl)-4-hydroxyphenylacetic ethyl acid imino ester hydrochloride 、 ethyl iminoester of 4-hydroxy-3,5-di-tert-butylphenylacetic acid 反应 25.0h， 以84%的产率得到2,6,2',6',2'',6''-hexa-tert-butyl-4,4',4''-[1,3,5]triazine-2,4,6-triyltrimethyl-tris-phenol
  参考文献：
  名称：

  Symm-三嗪衍生物的合成和性质。4.含有空间受阻酚片段的2,4,6-三取代的间位三嗪的合成

  摘要：

  DOI：

  10.1007/bf00515432

文献信息

• Polyphenylene ether resin composition of improved heat stability and shaped articles thereof
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0036278A1

  公开（公告）日：1981-09-23

  A polyphenylene ether resin composition having improved heat stability, comprises a matrix of polyphenylene ether resin and dispersed therein, as stabilizer, a phosphonous acid or esterthereof of the formula wherein R1 represents an alkyl group, an aryl group which may be substituted by an alkyl group, an aralkyl group which may be substituted by an alkyl group, or a group of the formula (a) in which R. groups are identical or different alkyl groups, and R, and R, are identical or different and each represents a hydrogen atom, an alkyl group, an aryl group which may be substituted by an alkyl group, or an aralkyl group which may be substituted by an alkyl group, provided that when R, represents the group of formula (a), R, and R3 represent identical or different 2,4-dialkylphenyl groups.

  一种具有更好热稳定性的聚苯醚树脂组合物，包括聚苯醚树脂基体和分散在其中的 作为稳定剂的磷酸或其酯，其式如下 其中 R1 代表烷基、可被烷基取代的芳基、可被烷基取代的芳烷基或式（a）的基团 其中 R.基团是相同或不同的烷基，且 R，和 R，是相同或不同的，且各自代表氢原子、烷基、可被烷基取代的芳基或可被烷基取代的芳烷基，但当 R 代表式（a）的基团时，R，和 R3 代表相同或不同的 2，4-二烷基苯基。
• Polyphenylene ether resin compositions and shaped articles thereof
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0038183A1

  公开（公告）日：1981-10-21

  A polyphenylene ether resin composition comprises a polyphenylene ether resin matrix and dispersed therein as heat stabilizer a phosphonic acid or derivative thereof of the formula wherein R1 represents an unsubstituted or substituted phenyl or naphthyl group, or a linear or branched alkyl group of 1 to 18 carbon atoms, or a group of the formula (a) R2 and R3 are the same or different and each represents hydrogen atom, a metal, an unsubstituted or substituted phenyl group, or an alkyl group of 1 to 10 carbon atoms and R4 is a divalent hydrocarbon group of 2 to 10 carbon atoms.

  一种聚苯醚树脂组合物，包括聚苯醚树脂基体和分散在其中的作为热稳定剂的 式中的膦酸或其衍生物 其中 R1 代表未取代或取代的苯基或萘基，或 1 至 18 个碳原子的直链或支链烷基， 或式(a)的基团 R2 和 R3 相同或不同，各自代表氢原子、金属、未取代或取代的苯基或 1 至 10 个碳原子的烷基，R4 是 2 至 10 个碳原子的二价烃基。
• Improved process for synthesis of hindered amine stabilizers for polymeric materials
  申请人：The B.F. GOODRICH Company

  公开号：EP0062322A1

  公开（公告）日：1982-10-13

  Process for the synthesis of hindered polysubstituted α-amino acetamides by reaction of a secondary amine with an α-halo acetamide in a basic organic reaction medium and in the presence of a phase transfer catalyst. The product thus obtained can comprise a multifunctional compound having one or more hindered amino moieties. These compounds are highly effective as UV stabilizers in a variety of plastics, especially the alpha monoolefins.

  在碱性有机反应介质中，在相转移催化剂存在下，通过仲胺与α-卤代乙酰胺反应合成受阻多取代α-氨基乙酰胺的工艺。由此得到的产物可以是具有一个或多个受阻氨基的多功能化合物。这些化合物在各种塑料，特别是α-单烯烃中作为紫外线稳定剂非常有效。
• Polyphenylene ether resin composition
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0099230A1

  公开（公告）日：1984-01-25

  A polyphenylene ether resin composition comprising (1) a polyphenylene ether resin, (2) an oxanilide represented by the following formula wherein R' and R6 are identical or different and each represents a hydrogen atom. an alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 15 carbon atoms. R2 and R are identical or different and each represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 10 carbon atoms. R3 and R6 are identical or different and each represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms and R4 and R5 are identical or different and each represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or a dialkylaminoalkyl group with the alkyl moiety having 1 to 6 carbon atoms, and (3) an organic phosphite.

  一种聚苯醚树脂组合物，包括 (1) 聚苯醚树脂、 (2) 下式所代表的草酰苯胺 其中 R' 和 R6 相同或不同，各自代表氢原子、具有 1 至 8 个碳原子的烷基或具有 1 至 15 个碳原子的烷氧基。R2 和 R 相同或不同，各自代表氢原子、具有 1 至 8 个碳原子的烷基或具有 1 至 10 个碳原子的烷氧基。R3 和 R6 相同或不同，各自代表一个氢原子或一个具有 1 至 8 个碳原子的烷基；R4 和 R5 相同或不同，各自代表一个氢原子、一个具有 1 至 6 个碳原子的烷基或一个具有 1 至 6 个碳原子的烷基的二烷基氨基烷基；以及 (3) 有机亚磷酸酯。 (3) 有机亚磷酸酯。
• FLAME RETARDANT POLYETHYLENE TEREPHTHALATE RESIN COMPOSITION
  申请人：Win Tech Polymer Ltd.

  公开号：EP1405879A1

  公开（公告）日：2004-04-07

  A flame-retardant polyethylene terephthalate-series resin composition comprises, relative to 100 parts by weight of (A) a polyethylene terephthalate-series resin, (B) 5 to 60 parts by weight of a bromine-containing flame retardant in which 5% by weight reduction from the initial weight thereof is given at a temperature of not less than 360°C under heating the flame retardant at a heating rate of 10°C/min. in a nitrogen stream; (C) 0.01 to 20 parts by weight of a crystallization accelerator; (D) 0.01 to 20 parts by weight of a colorant; and (E) 0.01 to 5 parts by weight of an antioxidant. The resin composition is excellent in resistance to heat/humidity, and has a color difference represented by a ΔE value of not more than 15 under heating the composition at 210°C for 24 hours. The resin composition may comprise an antimony-containing flame-retardant synergist and/or an inorganic filler. The resin composition ensures effective inhibition of discoloration, and strikes a balance between mechanical properties and heat fading resistance.

  一种阻燃聚对苯二甲酸乙二醇酯系列树脂组合物，相对于 100 份重量的(A)聚对苯二甲酸乙二醇酯系列树脂，(B)5 至 60 份重量的含溴阻燃剂，其中在不低于 360℃的温度下，在氮气流中以 10℃/分钟的升温速度加热阻燃剂，阻燃剂的重量比初始重量减少 5%；(C)0.01 至 20 份重量的结晶促进剂；(D)0.01 至 20 份重量的着色剂；以及(E)0.01 至 5 份重量的着色剂。(C) 0.01 至 20 份（按重量计）结晶促进剂； (D) 0.01 至 20 份（按重量计）着色剂；以及 (E) 0.01 至 5 份（按重量计）抗氧化剂。该树脂组合物具有优异的耐热/耐湿性，在 210°C 下加热 24 小时后，其色差以 ΔE 值表示不超过 15。树脂组合物可包括含锑阻燃增效剂和/或无机填料。 该树脂组合物可确保有效抑制褪色，并在机械性能和耐热褪色性之间取得平衡。