1,2,3,4,5,6,7,8-octafluoro-9,10-bis(mesitylethynyl)anthracene | 1067426-46-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,2,3,4,5,6,7,8-octafluoro-9,10-bis(mesitylethynyl)anthracene
• 英文别名: 1,2,3,4,5,6,7,8-Octafluoro-9,10-bis(mesitylethynyl)anthracene；1,2,3,4,5,6,7,8-octafluoro-9,10-bis[2-(2,4,6-trimethylphenyl)ethynyl]anthracene
• CAS: 1067426-46-3
• 化学式: C₃₆H₂₂F₈
• 分子量: 606.558
• InChiKey: YYIVDNHHWCQYCH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  44
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  9，10-二氯-1，2，3，4，5，6，7，8-八氟蒽 、 2,4,6-三级甲基苯乙炔 在 bis-triphenylphosphine-palladium(II) chloride copper(l) iodide 、 三乙胺 、 三苯基膦 作用下， 反应 24.0h， 以73%的产率得到1,2,3,4,5,6,7,8-octafluoro-9,10-bis(mesitylethynyl)anthracene
  参考文献：
  名称：

  通过钯催化的交叉偶联的9,10-二取代的八氟蒽衍生物。

  摘要：

  9,10-二氯八氟蒽（1）在钯催化的交叉偶联条件下与芳基硼酸和末端炔烃反应，分别制得9,10-二氟六氟蒽（2a-e）和9,10-二炔五氟蒽（6a，b）。光谱和循环伏安法表明，八氟-9,10-二（噻吩-2-基）蒽（2d）表现出给体-受体特性，相对于真空的LUMO能级为-3.27 eV。通过用NBS溴化2d，可以高收率获得官能化的5-溴噻吩-2-基衍生物（2e）。八氟-9,10-双[（（三甲基甲硅烷基）乙炔基]蒽（6a）的X射线晶体分析表明，固态结构模仿了柱状液晶的堆积，八氟蒽芯之间的π堆积距离为3.39 A 。此外，八氟-9

  DOI：

  10.1021/jo8017268

文献信息

• Flexible fabric antenna system comprising conductive polymers and method of making same
  申请人：University of Connecticut

  公开号：US11043728B2

  公开（公告）日：2021-06-22

  Disclosed herein are flexible metal-free antenna systems using fabric coated with electrically conductive polymers.

  本文公开了使用涂有导电聚合物的织物的柔性无金属天线系统。
• CONDUCTIVE POLYMER ELECTRODES, WIRING ELEMENTS, AND USE THEREOF IN HEALTH AND SPORTS MONITORING
  申请人：University of Connecticut

  公开号：US20180014780A1

  公开（公告）日：2018-01-18

  Disclosed herein are conductive polymer electrodes and wiring elements for use as the conductive element in health monitoring applications, and more specifically to conductive polymer fabric electrodes or conductive polymer fabric wiring elements for use as the conductive element in pads for health monitoring applications and other wearable monitoring systems.
• FLEXIBLE FABRIC ANTENNA SYSTEM COMPRISING CONDUCTIVE POLYMERS AND METHOD OF MAKING SAME
  申请人：University of Connecticut

  公开号：US20190326656A1

  公开（公告）日：2019-10-24

  Disclosed herein are flexible metal-free antenna systems using fabric coated with electrically conductive polymers.
• A SUBSTRATE WITH A POLAR ELASTOMER DIELECTRIC AND A METHOD OF COATING A SUBSTRATE WITH A POLAR ELASTOMER DIELECTRIC
  申请人：CORNING INCORPORATED

  公开号：US20200115584A1

  公开（公告）日：2020-04-16

  A polar elastomer dielectric layer is formed on a substrate by dynamically dispensing a solution containing the polar elastomer on the substrate and curing it at an elevated temperature. The polar elastomer can include poly(vinylidene fluoride-co-hexa-fluoropropylene) (e-PVDF-HFP). They dynamic dispensing process can include spinning the substrate at a first speed, depositing the polar elastomer solution on the substrate, and spinning the substrate at a second speed.
• DEVICE AND METHOD FOR NEUROSTIMULATION
  申请人：RAMOT AT TEL-AVIV UNIVERSITY LTD.

  公开号：US20200316370A1

  公开（公告）日：2020-10-08

  An efficient nanoscale semiconducting optoelectronic system, containing a P/N acceptor donor organic hetrojunction which is optimized for neuronal stimulation—an organic electrolytic photocapacitor. The devices comprise a thin (80 nm) trilayer of metal and p-n semiconducting organic nanocrystals. When illuminated in physiological solution, these metal-semiconductor devices charge up, transducing light pulses into localized displacement currents that are strong enough to electrically stimulate neurons with safe light intensities.