5-(thien-2-ylsulfanyl)-valeric acid | 452081-78-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 5-(thien-2-ylsulfanyl)-valeric acid
• 英文别名: 5-(2-thienylsulfanyl) valeric acid；5-[(Thiophen-2-yl)sulfanyl]pentanoic acid；5-thiophen-2-ylsulfanylpentanoic acid
• CAS: 452081-78-6
• 化学式: C₉H₁₂O₂S₂
• 分子量: 216.325
• InChiKey: AZFIAJNWMKWMFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  90.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5-溴戊酸乙酯 生成 2-噻吩硫醇 、 5-(thien-2-ylsulfanyl)-valeric acid
  参考文献：
  名称：

  Polyhydroxyalkanoate and method of producing the same, and omega-(2-thienylsulfanyl)alkanoic acid and method of producing the same

  摘要：

  公开号：

  EP1236754B1

文献信息

• Polyhydroxyalkanoate and method of producing same, and w-(2-thienylsulfanyl) alkanoic acid and method of producing same
  申请人：——

  公开号：US20020164726A1

  公开（公告）日：2002-11-07

  PHA containing a novel 3-hydroxy-thioalkanoic acid unit having a highly reactive thienyl group in a side chain thereof, and a method of producing the same are provided. Specifically, 5-(2-thienylsulfanyl) valeric acid represented by Chemical Formula [4] below and 6-(2-thienylsulfanyl) hexanoic acid represented by Chemical Formula [5] below are provided. Further, a method of producing PHA, comprising the step of collecting PHA from cells of a microorganism cultured in a medium containing the valeric acid or hexanoic acid, and a novel PHA represented by Chemical Formula [1] below are provided. 1 (n denotes an integer of 1 to 9)

  本发明提供了一种含有高度反应性噻吩基侧链的新型3-羟基硫代脂肪酸单元的PHA，以及其制备方法。具体地，提供了化学式[4]所表示的5-(2-噻吩基硫代基)戊酸和化学式[5]所表示的6-(2-噻吩基硫代基)己酸。此外，还提供了一种从在含有戊酸或己酸的培养基中培养的微生物细胞中收集PHA的方法，以及化学式[1]所表示的新型PHA。(其中n是1到9的整数)
• Polyhydroxyalkonoate and method of producing same, and w-(2-thienylsulfanyl) alkanoic acid and method of producing same
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20040062811A1

  公开（公告）日：2004-04-01

  PHA containing a novel 3-hydroxy-thioalkanoic acid unit having a highly reactive thienyl group in a side chain thereof, and a method of producing the same are provided. Specifically, 5-(2-thienylsulfanyl) valeric acid represented by Chemical Formula [4] below and 6-(2-thienylsulfanyl) hexanoic acid represented by Chemical Formula [5] below are provided. Further, a method of producing PHA, comprising the step of collecting PHA from cells of a microorganism cultured in a medium containing the valeric acid or hexanoic acid, and a novel PHA represented by Chemical Formula [1] below are provided. 1 (n denotes an integer of 1 to 9)

  本发明提供了含有具有高度反应性噻吩基侧链的新型3-羟基硫代烷酸单元的PHA，以及其制备方法。具体而言，提供了化学式[4]所代表的5-(2-噻吩基硫基)戊酸和化学式[5]所代表的6-(2-噻吩基硫基)己酸。此外，还提供了一种从在含有戊酸或己酸的培养基中培养的微生物细胞中收集PHA的方法，以及化学式[1]所代表的新型PHA。(其中n为1到9的整数)
• Polyhydroxyalkonoate and method of producing same, and ω-(2-thienylsulfanyl) alkanoic acid and method of producing same
  申请人：Kenmoku Takashi

  公开号：US06861496B2

  公开（公告）日：2005-03-01

  PHA containing a novel 3-hydroxy-thioalkanoic acid unit having a highly reactive thienyl group in a side chain thereof, and a method of producing the same are provided. Specifically, 5-(2-thienylsulfanyl) valeric acid represented by Chemical Formula [4] below and 6-(2-thienylsulfanyl) hexanoic acid represented by Chemical Formula [5] below are provided. Further, a method of producing PHA, comprising the step of collecting PHA from cells of a microorganism cultured in a medium containing the valeric acid or hexanoic acid, and a novel PHA represented by Chemical Formula [1] below are provided. (n denotes an integer of 1 to 9)

  本发明提供了一种包含具有高度反应性噻吩基侧链的新型3-羟基硫代烷酸单元的PHA，以及其制备方法。具体地，提供了化学式[4]所表示的5-(2-噻吩基硫基)戊酸和化学式[5]所表示的6-(2-噻吩基硫基)己酸。此外，提供了一种从在含有戊酸或己酸的培养基中培养的微生物细胞中收集PHA的方法，以及化学式[1]所表示的新型PHA。其中，n为1至9的整数。
• Polyhydroxyalkanoate and method of producing same, and &ohgr;-(2-thienylsulfanyl) alkanoic acid and method of producing same
  申请人：Canon Kabushiki Kaisha

  公开号：US06686439B2

  公开（公告）日：2004-02-03

  PHA containing a novel 3-hydroxy-thioalkanoic acid unit having a highly reactive thienyl group in a side chain thereof, and a method of producing the same are provided. Specifically, 5-(2-thienyl-sulfanyl)valeric acid represented by Chemical Formula [4] below and 6-(2-thienylsulfanyl)hexanoic acid represented by Chemical Formula [5] below are provided. Further, a method of producing PHA, comprising the step of collecting PHA from cells of a microorganism cultured in a medium containing the valeric acid or hexanoic acid, and a novel PHA represented by Chemical Formula [1] below are provided. (n denotes an integer of 1 to 9)

  本发明提供了含有高度反应性噻吩基侧链的新型3-羟基硫代脂肪酸单元的PHA，以及其制备方法。具体地，提供了化学式[4]所表示的5-(2-噻吩基硫基)戊酸和化学式[5]所表示的6-(2-噻吩基硫基)己酸。此外，还提供了一种从在含有戊酸或己酸的培养基中培养的微生物细胞中收集PHA的方法，以及化学式[1]所表示的新型PHA。（其中n为1到9的整数）
• Polyhydroxyalkanoate and method of producing same, and omega-(2-thienylsulfanyl) alkanoic acid and method of producing same
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP1236754A2

  公开（公告）日：2002-09-04

  PHA containing a novel 3-hydroxy-thioalkanoic acid unit having a highly reactive thienyl group in a side chain thereof, and a method of producing the same are provided. Specifically, 5-(2-thienylsulfanyl) valeric acid represented by Chemical Formula [4] below and 6-(2-thienylsulfanyl) hexanoic acid represented by Chemical Formula [5] below are provided. Further, a method of producing PHA, comprising the step of collecting PHA from cells of a microorganism cultured in a medium containing the valeric acid or hexanoic acid, and a novel PHA represented by Chemical Formula [1] below are provided. (n denotes an integer of 1 to 9)

  本发明提供了含有新型 3-羟基硫代烷酸单元的 PHA（其侧链中含有高活性噻吩基）及其生产方法。具体而言，提供了以下化学式[4]代表的 5-(2-噻吩基硫基)戊酸和以下化学式[5]代表的 6-(2-噻吩基硫基)己酸。此外，还提供了一种生产 PHA 的方法，该方法包括从在含有戊酸或己酸的培养基中培养的微生物细胞中收集 PHA 的步骤，以及由以下化学式[1]代表的新型 PHA。 (n表示1至9的整数)