N,N-二苯基-2(9,9-二甲基芴)胺 | 148077-51-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N-二苯基-2(9,9-二甲基芴)胺
• 中文别名: 9,9-二甲基-N,N-二苯基-芴-2-胺
• 英文名称: N-(9,9-dimethylfluoren-2-yl)-N,N-diphenylamine
• 英文别名: 9,9-dimethyl-N,N-diphenyl-9H-fluorene-2-amine；N,N-diphenyl-9,9-dimethyl-9H-fluorene-2-amine；(9,9-dimethyl-9H-fluoren-2-yl)-diphenylamine；9,9-dimethyl-N,N-diphenyl-9H-fluoren-2-amine；N,N-diphenyl-9,9-dimethyl-9H-fluoren-2-amine；2-(N,N-diphenyl)amino-9,9-dimethylfluorene；7-(N,N-diphenylamino)-9,9-dimethylfluoren；9,9-dimethyl-N,N-diphenylfluoren-2-amine
• CAS: 148077-51-4
• 化学式: C₂₇H₂₃N
• 分子量: 361.486
• InChiKey: LLAXDWLRVWTADE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-二苯基-2(9,9-二甲基芴)胺 、 在 溶剂黄146 作用下， 反应 12.0h， 生成
  参考文献：
  名称：

  一种有机发光材料及有机电致发光器件

  摘要：

  本发明涉及一种有机发光材料，所述的有机发光材料具有如下通式(Ⅰ)所示的结构：所述有机发光材料用作所述有机电致发光器件的空穴传输材料。本发明公开的有机发光材料具有多元化稠杂环芳胺连接的母体结构，原子间的键能高，具有良好的热稳定性，并有利于分子间的固态堆积，空穴的跃迁能力强，用作空穴传输层材料使用能有效降低器件电压，提高材料的寿命。所述有机发光材料为多元化稠杂环的衍生物，在空穴传输层中应用，与相邻层级间具有合适的能级水平，有利于空穴的注入和迁移，能够有效降低启亮电压，同时较高的空穴迁移速率，能够在器件中实现良好的发光效率。

  公开号：

  CN111574383B

文献信息

• SOLVENT-FREE CROSS-COUPLING REACTION, AND PRODUCTION METHOD USING SAID REACTION
  申请人：NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY

  公开号：US20210387994A1

  公开（公告）日：2021-12-16

  Disclosed is a cross-coupling reaction method which forms a chemical bond selected from C—N, C—B, C—C, C—O and C—S bonds, the method comprising: preparing an aromatic compound (1) having a leaving group; preparing a compound (2) capable of undergoing a cross-coupling reaction selected from an aromatic amino compound (2-1), a diboronic acid ester or the like (2-2), an aromatic boronic acid or the like (2-3), an aromatic compound (2-4) having a hydroxyl group and an aromatic compound (2-5) having a thiol group; and performing a cross-coupling reaction of the compound (1) with the compound (2) in the presence of a palladium catalyst, a base and a compound (4) having a carbon-carbon double bond or a carbon-carbon triple bond, in the absence of a solvent.

  揭示了一种交叉偶联反应方法，形成所选的C—N、C—B、C—C、C—O和C—S键中的化学键，该方法包括：准备具有离去基团的芳香化合物（1）；准备能够发生交叉偶联反应的化合物（2），所选自芳香胺化合物（2-1）、二硼酸酯或类似物（2-2）、芳香硼酸或类似物（2-3）、具有羟基的芳香化合物（2-4）和具有硫醇基的芳香化合物（2-5）；在钯催化剂、碱和具有碳-碳双键或碳-碳三键的化合物（4）的存在下，在无溶剂的情况下，对化合物（1）与化合物（2）进行交叉偶联反应。
• ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY DEVICE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20170084845A1

  公开（公告）日：2017-03-23

  An organic optoelectronic device includes an anode and a cathode facing each other, an emission layer between the anode and the cathode, a hole transport layer between the anode and the emission layer, and a hole transport auxiliary layer between the hole transport layer and the emission layer, wherein the emission layer includes at least one first compound represented by Chemical Formula 1; and at least one second compound represented by Chemical Formula 2, and the hole transport auxiliary layer includes at least one third compound represented by Chemical Formula 3. A display device including the organic optoelectronic device is provided Chemical Formulae 1 to 3 are the same as the detailed description.

  一种有机光电器件包括彼此面对的阳极和阴极，阳极和阴极之间的发射层，阳极和发射层之间的空穴传输层，以及空穴传输层和发射层之间的空穴传输辅助层，其中发射层包括至少一个由化学式1表示的第一化合物；以及至少一个由化学式2表示的第二化合物，空穴传输辅助层包括至少一个由化学式3表示的第三化合物。提供了包括该有机光电器件的显示器件。化学式1至3与详细描述相同。
• AMINE-BASED COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20160365521A1

  公开（公告）日：2016-12-15

  According to one or more embodiments, an organic light-emitting device may include: a first electrode; a second electrode facing the first electrode, and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer includes an amine-based compound represented by Formula 1:

  根据一个或多个实施例，有机发光器件可能包括：第一电极；面向第一电极的第二电极；以及位于第一电极和第二电极之间的有机层，该有机层包括一个发射层，其中有机层包括由化学式1表示的胺基化合物。
• [EN] ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] COMPOSÉ ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT
  申请人：ROHM & HAAS ELECT MATERIALS KOREA LTD

  公开号：WO2019004587A1

  公开（公告）日：2019-01-03

  The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. By using the organic electroluminescent compound of the present disclosure, an organic electroluminescent device having low driving voltage, high luminous efficiency, and/or long lifespan properties can be provided.

  本公开涉及一种有机电致发光化合物和包含该化合物的有机电致发光器件。通过使用本公开的有机电致发光化合物，可以提供具有低驱动电压、高发光效率和/或长寿命特性的有机电致发光器件。
• Electrophotographic photosensitive member, and electrophotgraphic apparatus and process cartridge which make use of the same
  申请人：Canon Kabushiki Kaisha

  公开号：EP1947515A2

  公开（公告）日：2008-07-23

  This invention relates to an electrophotographic photosensitive member having a support and a photosensitive layer. In the electrophotographic photosensitive member having a support and a photosensitive layer, which electrophotographic photosensitive member makes use of, as writing light, a semiconductor laser light ray having a wavelength of from 380 to 500 nm, the photosensitive layer contains a bisazo pigment represented by the following Formula (1): wherein A1, A2 and A3 may be the same or different, and each independently represent a saturated or unsaturated aliphatic hydrocarbon group which may have a substituent, an aromatic hydrocarbon ring group which may have a substituent, a heterocyclic ring group which may have a substituent, or a carbonyl group; R1 and R2 may be the same or different, and each independently represent an alkyl.group which may have a substituent, an aryl group which may have a substituent, or a halogen atom; R3, R4, R5 and R6 may be the same or different, and each independently represent a hydrogen atom, an alkyl group which may have a substituent, an aryl group which may have a substituent, a heterocyclic ring group which may have a substituent, or an aralkyl group which may have a substituent, provided that R3 and R4, and R5 and R6, may each form a cyclic amino group via the nitrogen atom in the formula; Z1 and Z2 each independently represent an oxygen atom or a sulfur atom; m1 and m2 each represent an integer of 0 to 4; and n1, n2 and n3 each independently represent. 0 or 1.

  本发明涉及一种具有支架和感光层的电子照相感光元件。 在这种具有支架和感光层的电子照相感光构件中，该电子照相感光构件利用波长为 380 至 500 纳米的半导体激光光线作为书写光，感光层含有由下式（1）表示的双氮颜料： 其中 A1、A2 和 A3 可以相同或不同，各自独立地代表饱和或不饱和脂肪烃基团（可以有取代基）、芳香烃环基团（可以有取代基）、杂环环基团（可以有取代基）或羰基；R1 和 R2 可以相同或不同，各自独立地代表烷基。R3、R4、R5 和 R6 可以相同或不同，且各自独立地代表氢原子、可 以具有取代基的烷基、可以具有取代基的芳基、可以具有取代基的杂环基团或可以 具有取代基的芳烷基，条件是 R3 和 R4 以及 R5 和 R6 可以各自通过式中的氮原子形 成环状氨基；Z1和Z2各自独立地代表氧原子或硫原子； m1和m2各自独立地代表0至4的整数； n1、n2和n3各自独立地代表。0 或 1。