Benzyliden-trimethyl-phosphoran | 32688-33-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzyliden-trimethyl-phosphoran
• 英文别名: Phosphorane, trimethyl(phenylmethylene)-；benzylidene(trimethyl)-λ5-phosphane
• CAS: 32688-33-8
• 化学式: C₁₀H₁₅P
• 分子量: 166.203
• InChiKey: LNOQMWYOQUISED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  {(neopentylidene)(2,6-diisopropylphenylimido)((OC(CH3)(CF3)2)2) molybdenum} 、 Benzyliden-trimethyl-phosphoran 以 氘代苯 为溶剂， 生成 、
  参考文献：
  名称：

  Reaction of Phosphoranes with Mo(N-2,6-i-Pr₂C₆H₃)(CHCMe₃)[OCMe(CF₃)₂]₂:  Synthesis and Reactivity of an Anionic Imido Alkylidyne Complex

  摘要：

  The reaction of Ph3P=CH2 with Mo(NAr)(CHCMe3)[OCMe(CF3)(2)](2) (Ar = 2,6-i-Pr2C6H3) produces the anionic alkylidyne complex {Ph3PMe} {Mo(NAr)(CCMe3)[OCMe(CF3)(2)](2)}. An X-ray structure determination of the complex reveals a bent Mo-N-C angle for the imido group, as expected when a metal-carbon triple bond is present. The anion has been shown to react with electrophiles predominantly at the imido nitrogen.

  DOI：

  10.1021/om060501e

文献信息

• Reaction of Phosphoranes with Mo(N-2,6-<i>i</i>-Pr₂C₆H₃)(CHCMe₃)[OCMe(CF₃)₂]₂:  Synthesis and Reactivity of an Anionic Imido Alkylidyne Complex
  作者：Zachary J. Tonzetich、Richard R. Schrock、Peter Müller

  DOI：10.1021/om060501e

  日期：2006.8.1

  The reaction of Ph3P=CH2 with Mo(NAr)(CHCMe3)[OCMe(CF3)(2)](2) (Ar = 2,6-i-Pr2C6H3) produces the anionic alkylidyne complex Ph3PMe} Mo(NAr)(CCMe3)[OCMe(CF3)(2)](2)}. An X-ray structure determination of the complex reveals a bent Mo-N-C angle for the imido group, as expected when a metal-carbon triple bond is present. The anion has been shown to react with electrophiles predominantly at the imido nitrogen.